ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2003,Vol.19>> Issue(04)>> 307-310     doi: 10.3866/PKU.WHXB20030405         中文摘要
The Application of Poly (1-aminoanthraquinone) for Positive Electrode Material in Lithium Secondary Battery
Tang Zhi-Yuan;Xu Guo-Xiang
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072
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Poly(1-aminoanthraquinone) is synthesized by chemical method and used as positive electrode in rechargeable lithium battery. Using the techniques of infrared (IR) spectrum, scan electronic microscopy (SEM), granularity, cyclic voltammograms (CVs) and charge-discharge, the function group, microscopic structure, particulate size and the electrochemical performance of the polymer are studied and analyzed. When used in lithium second battery with lithium, the initial discharge capacity of poly(1-aminoanthraquinone) is 218.3 mAh•g-1,it can keep excellent cycle efficiency after 25 charge-discharge cycles. In virtue of its high energy density and good cycling capability, the poly (1-aminoanthraquinone) is a promising positive electrode material for lithium secondary battery.

Keywords: Poly(1-aminoanthraquinone)   Positive electrode material   Charge-discharge   Cycle   Lithium secondary battery  
Received: 2002-07-05 Accepted: 2002-10-07 Publication Date (Web): 2003-04-15
Corresponding Authors: Tang Zhi-Yuan Email:

Cite this article: Tang Zhi-Yuan;Xu Guo-Xiang. The Application of Poly (1-aminoanthraquinone) for Positive Electrode Material in Lithium Secondary Battery[J]. Acta Phys. -Chim. Sin., 2003,19 (04): 307-310.    doi: 10.3866/PKU.WHXB20030405
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88. WU Feng, WANG Meng, SU Yue-Feng, CHEN Shi.Surface Modification of LiCo1/3Ni1/3Mn1/3O2 by TiO2-Coating[J]. Acta Phys. -Chim. Sin., 2009,25(04): 629-634
89. XU Jie; YAO Wan-Hao; YAO Yi-Wen; WANG Zhou-Cheng; YANG Yong.Effect of Fluoroethylene Carbonate Additive on the Performance of Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2009,25(02): 201-206
90. YANG Shun-Yi; WANG Xian-You; WEI Jian-Liang; LI Xiu-Qin; TANG An-Ping.Preparation and Electrochemical Performance of Na-Mn-O Cathode Materials[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1669-1674
91. ZHANG Hui; ZHU Li-Qun; LI Wei-Ping; LIU Hui-Cong.Sonochemical Fabrication and Electrochemical Performance of Electrode Materials Containing Rare Earth Yttrium[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1425-1431
92. AO Jian-Ping; SUN Guo-Zhong; YAN Li; KANG Feng; YANG Liang; HE Qing; ZHOU Zhi-Qiang; LI Feng-Yan; SUN Yun.Properties of One-Step Electrodeposited Cu(In1-x, Gax)Se2 Thin Films[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1073-1079
93. GAN Ning; WANG Lu-Yan; LI Tian-Hua; WANG Feng; JIANG Qian-Li.Preparaton and Electrocatalytic Activities of Nano Pt/Dimercaptosuccinic Amide Copper Modified Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(05): 915-920
94. TU Xiao-Hua; CHU You-Qun; MA Chun-An; MO Yi-Ping; CHEN Zhao-Yang.Electrochemical Behavior of Aluminium Electrode in LiNO3-KNO3 Molten Salt[J]. Acta Phys. -Chim. Sin., 2008,24(04): 665-669
95. CHANG Zhao-Rong; CHEN Zhong-Jun; WU Feng; TANG Hong-Wei; ZHU Zhi-Hong.Synthesis of LiNi1/3Co1/3Mn1/3O2 Cathode Material by Eutectic Molten Salt LiOH-LiNO3[J]. Acta Phys. -Chim. Sin., 2008,24(03): 513-519
96. CHEN Yu-Ting; ZHANG Hai-Yan; ZHANG Guo-Qing; CHEN Yi-Ming; ZHU Qing-Feng.Influence of Addition of Carbon Nanotubes in the Hydrogen Storage Alloy Electrode on the Performance of SC High Power Batteries[J]. Acta Phys. -Chim. Sin., 2008,24(03): 527-532

DU Guo-Dong; NULI Yan-Na; FENG Zhen-Zhen; WANG Jiu-Lin; YANG Jun

.Electrochemical Behavior of High-Voltage LiNi0.5Mn1.5O4-xFx Electrodes at Elevated Storage Temperature[J]. Acta Phys. -Chim. Sin., 2008,24(01): 165-170

98. LI Wei; Tong-Ge-La-Ge; MU Qi-Yong; QI Lu; GUO Jin.Chemical Pattern Recognition Applied to the Analysis of Effect of Technology Factors on the Properties of Li-Mn-O Spinel Oxide[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 10-13
99. ZHANG Chun-Ling; JIANG Wei-Jun; ZHANG Jing; QI Lu.Performance of LiMn1.5Ni0.5-xCuxO4 as 5V Cathode Material for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 31-35
100. HOU Xian-Quan; JIANG Wei-Jun; QI Lu; HAN Li-Juan.Synthesis and Properties of Layered LiNi0.8Co0.2-xMgxO2 Cathode Material[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 40-45
101. CHEN Yong-Chong; XU Xing-Jun; CUI Hong-Zhi; DAI Ke-Hua; SONG Zhao-Shuang; JIANG Wei-Jun; QI Lu.Synthesis Mechanisms and Properties of Cathode Material LiNixMn2-xO4[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 26-30
102. JIANG Wei-Jun; Sai-Xi-Ya-Le-Tu; Wu-Yun-Bi-Li-Ge; QI Lu; SHANG Shi-Bo.Performance of Nonstoichiometric Li1+xCoO2 Cathode Materials[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 56-59

WANG Jian; QI Yu-Jun; LI Yong-Wei; QI Lu

.Discharge Performances of C/LiNi1/3Co1/3Mn1/3O2[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 46-50

104. HAO Yong-Chao; QIAN Liang-Guo; XIAO Ya-Ling.Quality Evaluation of GroupMotive Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 94-99
105. GUO Ying-Jun; LI Qi-Qi-Ge; NING Ying-Kun; QI Lu; TANG Hong-Wu.Performance of Liquid Electrolyte for Lithium-ion Battery at Elevated-temperature[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 1-4
106. DAI Ke-Hua; WANG Yin-Jie; FENG Hua-Jun; XIE Yan-Ting; QI Lu.Preparation Conditions of LiMn0.45Ni0.45Co0.1O2 via Hydroxide Co-precipitation[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1927-1931
107. CHEN Yong-Chong; XU Xing-Jun; CUI Hong-Zhi; DAI Ke-Hua; SONG Zhao-Shuang; JIANG Wei-Jun; QI Lu.Preferred Orientation of Crystals and the Intensity Ratios of XRD Peaks of Cathode Material LiCoO2[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1948-1953
108. HOU Chun-Ping; YUE Min.A Novel Cathode Material Lithium Vanadium Phosphate Synthesized by Liquid-phase Sphericizing Granulation[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1954-1957
109. YAN Na; ZHANG Cun-Zhong; WU Feng; LIU Jing-Jing; CHEN Jun-Zheng.Influence of Electropolymerized Current Density on Polypyrrole Electrode of Lithium Ion Cells[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1747-1752
110. CHU Yan-Qiu; WU Bo; WU Liang; SHUI Qing; FU Zheng-Wen.Electrochromic Properties of Bismuth Oxide Thin Films Prepared by Reactive Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1787-1791
111. ZHAO Yan; LIN Chang-Jian; LI Yan; DU Rong-Gui; WANG Jing-Run.Electrochemical Corrosion Behavior of Copper Clad Laminate in NaCl Solution[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1342-1346
112. WANG Li-Wu; LI Zong-Mu; ZHANG Wen-Hua; XU Fa-Qiang; Wang Jie; YAN Wen-Sheng.Electrochemical Epitaxy and XMCD Study of Co-Ni Alloy Film[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1163-1167
113. WEI Ying-Jin; LI Xu; WANG Chun-Zhong; ZHAN Shi-Ying; CHEN Gang.Preparation and Electrochemical Properties of Cu Doped V2O5[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1090-1094
114. ZHANG Shu-Ping; NI Jiang-Feng; ZHOU Heng-Hui; ZHANG Zhan-Jun.Controllable Synthesis of Regular LiFePO4 Particles via Solvothermal Reaction[J]. Acta Phys. -Chim. Sin., 2007,23(06): 830-834
115. LIU Su-Qin; LI Shi-Cai; HUANG Ke-Long; CHEN Zhao-Hui.Effect of Doping Ti4+ on the Structure and Performances of Li3V2(PO4)3[J]. Acta Phys. -Chim. Sin., 2007,23(04): 537-542
116. FENG Zhen-Zhen;NULI Yan-Na;YANG Jun.Conductive Sulfur-Containing Material/Polyaniline Composite for Cathode Material of Rechargeable Magnesium Batteries[J]. Acta Phys. -Chim. Sin., 2007,23(03): 327-331
117. TIAN Juan;ZHENG Dan;ZHANG Xi-Gui;ZHANG Bao-Hong;XIA Bao-Jia;YANG Hui.Preparation of Pt Nanoparticle Modified Porous Silicon Electrode and Its Electrocatalytic Performance[J]. Acta Phys. -Chim. Sin., 2007,23(01): 68-72
118. HUANG Ke-Long;YANG Sai;LIU Su-Qin;WANG Hai-Bo.Kinetics of Electrode Processes of LiFePO4 in Saturated Lithium Nitrate Solution[J]. Acta Phys. -Chim. Sin., 2007,23(01): 129-133
119. TANG Zhi-Yuan;YU Ming-Yuan;XUE Jian-Jun;GAO Fei;CUI Yan;LI Liang-Dong.Electrochemical Properties and Synthesis of LiNi0.01Co0.01Mn1.98O4 by SAC Route for Lithium Secondary Battery[J]. Acta Phys. -Chim. Sin., 2007,23(01): 134-138
120. ZHUANG Da-Gao;ZHAO Xin-Bing;XIE Jian;TU Jian;ZHU Tie-Jun;CAO Gao-Shao.One-step Solid-state Synthesis and Electrochemical Performance of Nb-doped LiFePO4/C[J]. Acta Phys. -Chim. Sin., 2006,22(07): 840-844
121. MA Chun-An;SHENG Jiang-Feng;WANG Xiao-Juan;ZHANG Cheng;WANG Lian-Bang.Electrochemical Behavior of Nitrobenzene on Pt Micro-disk Electrode in Aprotic Medium[J]. Acta Phys. -Chim. Sin., 2006,22(05): 635-637
122. XU Meng-Qing; ZUO Xiao-Xi; LI Wei-Shan; ZHOU Hao-Jie; LIU Jian-Sheng; YUAN Zhong-Zhi.Effect of Butyl Sultone on the Li-ion Battery Performance and Interface of Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2006,22(03): 335-340
123. XU Liang-Qin; DU Zhan-He; FENG Jia-Min; LÜ Xiao-Li; GAO Qing-Yu.The Behavior of Electrochemical Oxidation of Thiosulfate on Platinum Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1422-1425
124. ZHONG Qi-ling ; ZHANG Xiao-hong; ZHOU Hai-Hui; WEN Zu-biao; YANG Xiong-yuan; HUANG Peng; REN Bin; TIAN Zhong-qun.In-situ SERS of Piperonal and Isosafrole Electrooxidation on Pt Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1182-1185
125. TANG Zhi-yuan; LU Xing-he; ZHANG Na.The Anion-cation Multiple Doping Effect of Spinel Cathode Materials on Electrochemical Speciality[J]. Acta Phys. -Chim. Sin., 2005,21(08): 934-938
126. TAO Bin-Wu;LIU Jian-Hua;LI Song-Mei;ZHAO Liang.Electrochemical Properties of a V2O5/C Composite in Aqueous Solution Used for Zinc Secondary Battery[J]. Acta Phys. -Chim. Sin., 2005,21(03): 338-342
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128. LIU Yan;GUO Xia;GUO Rong.Interaction between N, N-diethylaniline and SDS/n-C5H11OH/H2O Microemulsion[J]. Acta Phys. -Chim. Sin., 2005,21(01): 38-41
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130. Shen Jie;Wo Song-Tao;Cui Xiao-Li;Cai Zhen-Wei;Yang Xi-Liang;Zhang Zhuang-Jian.Photoelectrochemical Characteristics of Nano-Titanium Dioxide Thin Films Prepared by RF Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1191-1195
131. Chang Xiao-Yan;Wang Zhi-Xing;Li Xin-Hai;Kuang Qiong;Peng Wen-Jie;Guo Hua-Jun;Zhang Yun-He.Synthesis and Performance of LiMnPO4 Used as Cathode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1249-1252
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154. Guo Xia;Liu Yan;Guo Rong.The Location of Phenothiazine in SDS/BA/H2O Microemulsion[J]. Acta Phys. -Chim. Sin., 2001,17(11): 982-985
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