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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2003,Vol.19>> Issue(03)>> 208-211     doi: 10.3866/PKU.WHXB20030304         中文摘要
Adsorption Thermodynamics of Macroporous Cross-linked Poly (N-methyl-N-p- vinylbenzylacetamine) Resin for Phenols from Non-aqueous System
Huang Jian-Gou;Xu Man-Cai;Li Hai-Tao;Shi Zuo-Qing;He Bing-Lin
College of Chemistry and Chemical Engineering,Hunan Normal University, Changsha 410081; The State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University, Tianjin 300071
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The title resin was synthesized and the adsorption isotherms of phenol from cyclohexane solution were measured. Values of isosteric adsorption enthalpy, adsorption Gibbs free energy and adsorption entropy were calculated. These values implied a hydrogen-bonding adsorption mechanism. Furthermore, difference of adsorption property for phenol and o-nitrophenol from cyclohexane solution was studied, and the result was in accordance with the hydrogen-bonding mechanism.

Keywords: Macroporous cross-linked poly(N-methyl-N-p-vinylbenzylacetamine) resin   Non-aqueous system   Phenols   Hydrogen-bonding   Adsorption mechanism  
Received: 2002-06-14 Accepted: 2002-08-19 Publication Date (Web): 2003-03-15
Corresponding Authors: Xu Man-Cai Email: xu_mc@yahoo.com.cn


Cite this article: Huang Jian-Gou;Xu Man-Cai;Li Hai-Tao;Shi Zuo-Qing;He Bing-Lin. Adsorption Thermodynamics of Macroporous Cross-linked Poly (N-methyl-N-p- vinylbenzylacetamine) Resin for Phenols from Non-aqueous System[J]. Acta Phys. -Chim. Sin., 2003,19 (03): 208-211.    doi: 10.3866/PKU.WHXB20030304
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