ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2006,Vol.22>> Issue(08)>> 1040-1042     doi: 10.3866/PKU.WHXB20060826         中文摘要
Li-ZnO/La2O3 Catalyst for the Oxidation Coupling of Methane at Low Temperature
HOU Si-Cong;LIU Ling-Tao;KOU Yuan
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences, Green Chemistry Center of Peking University, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
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The oxidative coupling of methane (OCM) at low temperature was examined on Li- ZnO/La2O3 catalyst with w(Li)=2% and w(ZnO)=20%. CH4 conversion of 27.3% with C2 selectivity of 65.2% was obtained at 680 ℃ and the C2 yield reached 21.8% at 700 ℃ under reaction conditions. Raman and XPS results suggested that the low- temperature activity was related to the concentration of adsorbed oxygen species on the catalyst surface and La2O2CO3 was supposed to be responsible for the enhancement of C2 selectivity in OCM.

Keywords: Oxidative coupling of methane   Low temperature   Li- ZnO/La2O3   Adsorbed oxygen species   La2O2CO3  
Received: 2006-06-01 Accepted: 2006-06-22 Publication Date (Web): 2006-07-07
Corresponding Authors: KOU Yuan Email:

Cite this article: HOU Si-Cong;LIU Ling-Tao;KOU Yuan. Li-ZnO/La2O3 Catalyst for the Oxidation Coupling of Methane at Low Temperature[J]. Acta Phys. -Chim. Sin., 2006,22 (08): 1040-1042.    doi: 10.3866/PKU.WHXB20060826
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14. ZHANG Li-Zhi, YANG Hao-Lin, ZHAO Dai-Qing, JIANG Li-Qiao.Influence of Methanol Addition on the Two Stage Combustion of a Dimethyl Ether/Air Mixture[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1560-1566
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17. SHEN Bo-Xiong, LIU Ting.Deactivation of MnOx-CeOx/ACF Catalysts for Low-Temperature NH3-SCR in the Presence of SO2[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3009-3016
18. RAN Jing-Yu, ZHAO Liu-Jie.Thermodynamic Analysis of Low Temperature Methane Wet-Air Reforming in a Microcombustor[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2899-2906
19. XU Hai-Di, QIU Chun-Tian, ZHANG Qiu-Lin, LIN Tao,GONG Mao-Chu, CHEN Yao-Qiang.Influence of Tungsten Oxide on Selective Catalytic Reduction of NOx with NH3 over MnOx -CeO2 /ZrO2-TiO2Monolith Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2449-2454
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22. LIU Rui-Hui, ZHANG Cun-Man, MA Jian-Xin.Al2O3-Modified Fe2O3 Based Gold Catalysts with Good Thermal Stability[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2261-2269
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46. Zhao Wen-Kuan;Fang You-Ling.Synthesis of Photocatalytic Activity TiO2 Thin Films at LowTemperature[J]. Acta Phys. -Chim. Sin., 2002,18(04): 368-371
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48. Chen Hong-Shan, Niu Jian-Zhong, Xia Chun-Gu, Li Shu-Ben.Raman Spectroscopy Characterization of Na-W-Mn/SiO2 Catalyst for Oxidative Coupling of Methane[J]. Acta Phys. -Chim. Sin., 2000,16(06): 543-546
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50. Wei Sai-Zhen,Mao Zu-Sui,Wang Lei,Chen Xiao-Feng,Zheng Yong-Ming.The Fractal Structure Investigation of Pd Film Deposited on Polyvinyl Formal[J]. Acta Phys. -Chim. Sin., 1997,13(03): 218-223
51. Yu Lin,Xu Yi-De,Guo Xie-Xian.A FT-IR Study on the Interaction of CH4 and O2 with the Surface of SrO-La2O3/CaO Catalysts[J]. Acta Phys. -Chim. Sin., 1995,11(10): 902-906
52. Ji Min, Bi Ying-Li, Zhen Kai-Ji, Xu Yu-Hua, Wei Quan.The Study on Structures of CaO-La2O3 Catalysts by Fluorescence Emission of Eu3+[J]. Acta Phys. -Chim. Sin., 1995,11(02): 175-179
53. Xiong Guo-Xing, Xia Xin-Rui, Chen Heng-Rong, Guo Xie-Xian.Synergetic Effect between NaCl and B2O3 in Modified FeOχ Catalysts[J]. Acta Phys. -Chim. Sin., 1994,10(11): 971-977
54. Zhao Zhen, Yuan Song-Yue, Yu Zuo-Long.Role of Lithium in Multicomponent Oxide Catalysts for Oxidative Coupling of Methane[J]. Acta Phys. -Chim. Sin., 1994,10(07): 616-622
55. Luo Xiao-Ming; Han Qiao-Feng; Chen Yi; Han Shi-Ying; Jin Tong-Zheng; Sui Yun-Xia.The Study of Adsorbed Oxygen Species on the Surface of a Series of Na2SnO3 Catalysts by epr Experiments[J]. Acta Phys. -Chim. Sin., 1993,9(06): 746-751
56. Wang Jiang; Zhen Kai-Ji; Wei Quan; Bi Ying-Li.The Surface Properties of LaAlO3 Perovskite Oxides and Their Catalytic Activities[J]. Acta Phys. -Chim. Sin., 1992,8(02): 247-250
57. SUN Hao-Yu, PU Jing-Huan, TANG Gui-Hua.High-performance Thermogalvanic Cell Based on Organic Nanofluids[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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