ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2007,Vol.23>> Issue(01)>> 129-133     doi: 10.3866/PKU.WHXB20070127         中文摘要
Kinetics of Electrode Processes of LiFePO4 in Saturated Lithium Nitrate Solution
College of Chemistry & Chemical Engineering, Central South University, Changsha 410083, P. R. China
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Kinetics of electrode processes of LiFePO4 in saturated LiNO3 solution was investigated by analyses of cyclic voltammetry (CV), charge/discharge test, and potentiostatic intermittent titration (PITT). The results showed that LiFePO4 had good electrochemical reversibility in saturated LiNO3 solution. The first discharge capacity was about 116.2 mAh•g−1, and its charge/discharge efficiency was 92%. The lithium diffusion coefficients, corresponding to anodic peak and cathodic peak in LiFePO4, obtained from CV were 4.3×10−11 cm2•s−1 and 3.8×10−11 cm2•s−1. The lithium diffusion coefficients obtained from PITT varied with potentials, and the lowest value was about 5.5×10−11 cm2•s−1, coinciding with the voltage plateau region in the charge curves.

Keywords: Aqueous lithium-ion battery   LiFePO4   Cyclic voltammetry   Potentiostatic intermittent titration technique   Diffusion coefficient  
Received: 2006-07-31 Accepted: 2006-09-12 Publication Date (Web): 2007-01-08
Corresponding Authors: HUANG Ke-Long Email:

Cite this article: HUANG Ke-Long;YANG Sai;LIU Su-Qin;WANG Hai-Bo. Kinetics of Electrode Processes of LiFePO4 in Saturated Lithium Nitrate Solution[J]. Acta Phys. -Chim. Sin., 2007,23 (01): 129-133.    doi: 10.3866/PKU.WHXB20070127
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