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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2007,Vol.23>> Issue(02)>> 187-191     doi: 10.3866/PKU.WHXB20070210         中文摘要
Sulfonated Poly(phthalazinones) Membranes For Direct Methanol Fuel Cell
DENG Hui-Ning;WANG Yu-Xin
Chemical Engineering Research Center, School of Chemical Engineering and Technology,
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Proton exchange membrane is one of the key parts of direct methanol fuel cell (DMFC). Sulfonated poly(phthalazinones) membranes were prepared and the feasibility of applying these membranes in DMFC was studied. The thermal degradation temperature of sulfonated poly(phthalazinone ether sulfone keton) (SPPESK) membrane was about 100 ℃ lower than that of sulfonated poly(phthalazinone ether keton) (SPPEK) and sulfonated poly(phthalazinone ether sulfone) (SPPES) membranes with similar ion-exchange capacity (IEC). These new membranes showed high proton conductivity and their methanol permeability was lower than that of Nafion membrane. DMFC performance of these new membranes was also investigated. The DMFCs with sulfonated poly(phthalazinones) membranes showed higher open circuit voltage than that using Nafion membrane as electrolyte. However, the DMFC performance of these new membranes was lower than that of Nafion membrane at high current density.

Keywords: Poly(phthalazinones)   Direct methanol fuel cell (DMFC)   Proton exchange membrane (PEM)   Proton conductivity   Methanol permeability  
Received: 2006-08-21 Accepted: 2006-09-11 Publication Date (Web): 2007-01-30
Corresponding Authors: WANG Yu-Xin Email: yxwang@tju.edu.cn


Cite this article: DENG Hui-Ning;WANG Yu-Xin . Sulfonated Poly(phthalazinones) Membranes For Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2007,23 (02): 187-191.    doi: 10.3866/PKU.WHXB20070210
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