Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2006,Vol.22>> Issue(05)>> 596-601     doi: 10.3866/PKU.WHXB20060516         中文摘要
Chemical Composition and Reaction Mechanisms for Secondary Organic Aerosol from Photooxidation of Ethylbenzene
HUANG Ming-Qiang;HAO Li-Qing;ZHOU Liu-Zhou;GU Xue-Jun;WANG Zhen-Ya;FANG Li;ZHANG Wei-Jun
Laboratory of Environment Spectroscopy, Anhui Institute of Optics&Fine Mechanics,Chinese Academy of Sciences, Hefei 230031, P. R. China
Full text: PDF (274KB) Export: BibTeX | EndNote (RIS)
A laboratory study was carried out to investigate the secondary organic aerosol (SOA) products from photooxidation of the aromatic hydrocarbon ethylbenzene. The experiments were conducted by irradiating ethylbenzene/CH3ONO/NOx mixtures in a home-made smog chamber. Size distribution of the secondary organic aerosol particles was detected with an aerodynamic particle sizer spectrometer. The aerosol time-of-flight mass spectrometer (ATOFMS) was used to measure the chemical composition of individual secondary organic aerosol particle in real time. According to a large number of single aerosol mass spectra, the chemical composition of SOA was obtained statistically. The possible reaction mechanisms leading to these products were also discussed.

Keywords: Ethylbenzene   Secondary organic aerosol   Smog chamber   Laser desorption/ ionization   Reaction mechanisms  
Received: 2005-11-24 Accepted: 2006-01-17 Publication Date (Web): 2006-04-28
Corresponding Authors: ZHANG, Wei-Jun Email: wjzhang@aiofm.ac.cn


Cite this article: HUANG Ming-Qiang;HAO Li-Qing;ZHOU Liu-Zhou;GU Xue-Jun;WANG Zhen-Ya;FANG Li;ZHANG Wei-Jun. Chemical Composition and Reaction Mechanisms for Secondary Organic Aerosol from Photooxidation of Ethylbenzene[J]. Acta Phys. -Chim. Sin., 2006,22 (05): 596-601.    doi: 10.3866/PKU.WHXB20060516
1. YANG Zhen, LIU Hai, HE Yuan-Hang.Molecular Dynamics Simulations of Femtosecond Laser Ablation of Energetic Materials[J]. Acta Phys. -Chim. Sin., 2016,32(8): 1977-1982
2. WUAi-Ming, XIA Guo-Feng, SHEN Shui-Yun, YIN Jie-Wei, MAO Ya, BAI Qing-You, XIE Jing-Ying, ZHANG Jun-Liang.Recent Progress in Non-Aqueous Lithium-Air Batteries[J]. Acta Phys. -Chim. Sin., 2016,32(8): 1866-1879
3. LIU Xiao-Long, LI Xiao-Xia, HAN Song, QIAO Xian-Jie, ZHONG Bei-Jing, GUO Li.Initial Reaction Mechanism of RP-3 High Temperature Oxidation Simulated with ReaxFF MD[J]. Acta Phys. -Chim. Sin., 2016,32(6): 1424-1433
4. YANG Zhen, HE Yuan-Hang.Pyrolysis of Octanitrocubane via Molecular Dynamics Simulations[J]. Acta Phys. -Chim. Sin., 2016,32(4): 921-928
5. ZHANG Tian-Lei, YANG Chen, FENG Xu-Kai, WANG Zhu-Qing, WANG Rui, LIU Qiu-Li, ZHANG Peng, WANG Wen-Liang.Theoretical Study on the Atmospheric Reaction of HS with HO2: Mechanism and Rate Constants of the Major Channel[J]. Acta Phys. -Chim. Sin., 2016,32(3): 701-710
6. WANG Quan-De.Skeletal Mechanism Generation for Methyl Butanoate Combustion via Directed Relation Graph Based Methods[J]. Acta Phys. -Chim. Sin., 2016,32(3): 595-604
7. ZHANG Pei-Zhi, YE Mei-Jun, HU Wei-Lian, WU Jun.Kinetics of Acid-Catalyzed Smiles Rearrangement of 2,6-Dimethoxy-2-pyrimidinyloxy-N-arylbenzylamine Derivatives[J]. Acta Phys. -Chim. Sin., 2016,32(2): 422-428
8. ZENG Xiao-Lan, WANG Yan.Mechanism and Regioselectivity of Addition Reactions of CH3OH to Germasilenes[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1699-1707
9. ZHENG Zhao-Lei, LIANG Zhen-Long.Reduced Chemical Kinetic Model of a Gasoline Surrogate Fuel for HCCI Combustion[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1265-1274
10. WANG Wei-Gang, LI Kun, ZHOU Li, GE Mao-Fa, HOU Si-Qi, TONG Sheng-Rui, MU Yu-Jing, JIA Long.Evaluation and Application of Dual-Reactor Chamber for Studying Atmospheric Oxidation Processes and Mechanisms[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1251-1259
11. LI Min-Jie, DIAO Ling, KOU Li, LI Zhong-Gao, LU Wen-Cong.Hydroxyl Radical Reaction with the Guanine-Cytosine Base Pair: A Density Functional Theory Study[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1007-1014
12. REN Qing-Hua, SHEN Xiao-Yan.Reaction Mechanism for the Iron-Catalyzed Biaryl Cross-Coupling of Aryl Grignard Reagents[J]. Acta Phys. -Chim. Sin., 2015,31(5): 852-858
13. ZHENG Dong, YU Wei-Ming, ZHONG Bei-Jing.RP-3 Aviation Kerosene Surrogate Fuel and the Chemical Reaction Kinetic Model[J]. Acta Phys. -Chim. Sin., 2015,31(4): 636-642
14. LI Zhe-Qi, WANG Te-Hua, LI Xiu-Yuan, ZHANG Ya-Qin, JI Min.Preparation and Catalytic Performances of a Three-Dimensionally Ordered Macroporous MgFe0.1Al1.9O4 Catalyst for Ethylbenzene Oxydehydrogenation with CO2[J]. Acta Phys. -Chim. Sin., 2015,31(4): 743-749
15. YU Wei-Ling, ZUO Hui-Wen, LU Chun-Hai, LI Yi, ZHANG Yong-Fan, CHEN Wen-Kai.Nitrous Oxide Decomposition Catalyzed by Au19Pd and Au19Pt Clusters[J]. Acta Phys. -Chim. Sin., 2015,31(3): 425-434
16. XU Qiong, ZHANG Tian-Lei, Lü Wen-Bin, WANG Rui, WANG Zhi-Yin, WANG Wen-Liang, WANG Zhu-Qing.Theoretical Study on the effect of a Single Water Molecule on the H2O2+Cl Gas Reaction[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1061-1070
17. BA Yan-Tao, HOU Ling-Yun, MAO Xiao-Fang, WANG Feng-Shan.Construction and Analysis of a Chemical Kinetic Model for Monomethylhydrazine/Nitrogen Tetroxide Reactions[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1042-1048
18. JIANG Feng, REN Qing-Hua.Reaction Mechanism for the Ni-Catalyzed Reductive Cross-Coupling of Aryl Halides[J]. Acta Phys. -Chim. Sin., 2014,30(5): 821-828
19. ZHANG Hai-Xin, CHEN Shu-Wei, CUI Xing-Yu, PAN Da-Hai, QIN Zhang-Feng, WANG Jian-Guo.Effect of Ce Promoter on Catalytic Performance of V/SiO2 in Oxidative Dehydrogenation of Ethylbenzene with Carbon Dioxide[J]. Acta Phys. -Chim. Sin., 2014,30(2): 351-358
20. XU Kun, FENG Jie, CHU Qi, ZHANG Li-Li, LI Wen-Ying.Density Functional Theory Study of Thiophene Hydrodesulfurization on γ-Mo2N(100) Surface[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2063-2070
21. PANG Bin, XIE Mao-Zhao, JIA Ming, LIU Yao-Dong.Improved Phenomenological Soot Model for Multicomponent Fuel Based on Variations in PAH Characteristics with Fuel Type[J]. Acta Phys. -Chim. Sin., 2013,29(12): 2523-2533
22. ZENG Xiu-Lin, HUANG Shan-Qi-Song, JU Xue-Hai.Density Functional Theory Study of the Gas-Phase Reaction of U+ with CO2[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2308-2312
23. ZHANG Tian-Lei, WANG Wei-Na, LIU Chang, LU Na, CHEN Miao, GUO Sha, WANG Wen-Liang.Computational Study of the Reaction Mechanism and Kinetics of CH3CHC(CH3)COOCH3 Ozonolysis[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2313-2320
24. LI Jia, XU Wen-Li, HU Jing, LING Min, YAO Jian-Hua.Hydrolysis Reaction Mechanismof 2, 4-Dichlorophenoxy Acetic Acid Metabolism[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1923-1930
25. LV Ling-Ling, WANG Xiao-Fang, ZHU Yuan-Cheng, LIU Xin-Wen, YUAN Kun, WANG Yong-Cheng.Spin-Orbit Coupling and Zero-Field Splitting in Dioxygen Activation by Non-Heme Iron(III)[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1673-1680
26. XIE Hu-Jun, MOU Wang-Shu, LIN Fu-Rong, XU Jie-Hui, LEI Qun-Fang, FANG Wen-Jun.Radical Scavenging Activity of Myricetin[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1421-1432
27. CAO Yin-Liang, LI Zhi-Lin, WANG Feng, LIU Jing-Jun, JI Jing, WANG Jian-Jun, ZHANG Liang-Hu, QIN Shi-Yong.Electrochemical Preparation of Ni-Sn Active Cathode and Its Electrocatalytic Hydrogen Evolution Reaction Mechanisms in Alkaline Solution[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1479-1486
28. ZHENG Dong, ZHANG Yun-Peng, ZHONG Bei-Jing.Chemical Kinetic Model for Polycyclic Aromatic Hydrocarbon Formation during Gasoline Surrogate Fuel Combustion[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1154-1160
29. ZHONG Bei-Jing, XIONG Peng-Fei, YANG Fan, YU Ya-Wei.Thermal and Chemical Effects of Hydrogen in Catalytic Ignition of n-Butane/Air Mixture[J]. Acta Phys. -Chim. Sin., 2013,29(05): 897-902
30. YAO Fang-Fang, WU Bao-Shan, ZHOU Li-Ping, GAO Jun-Hu, LI Ying, LI Yong-Wang.Effect of Alcohol Addition on Fischer-Tropsch Synthesis over Cobalt-Based Catalysts[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1063-1072
31. QIU Yi-Xiang, WAN Ming-Da, CHEN Xian-Yang, WANG Shu-Guang.Reaction Mechanisms of Ethylene Hydrogenation Catalyzed by Gold(I) Complexes[J]. Acta Phys. -Chim. Sin., 2013,29(02): 279-286
32. GU Lai-Yuan, GAO Bao-Jiao, FANG Xiao-Lin.Characterization of Immobilized Composite Catalysts of Cationic Metalloporphyrin and Heteropoly Anion in Oxidation of Ethyl Benzene by Molecular Oxygen[J]. Acta Phys. -Chim. Sin., 2013,29(01): 191-198
33. WANG Yan, ZENG Xiao-Lan.1,2- and 1,4-Addition Reactions between Silabenzenes and HX (X=F, OH, NH2)[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2831-2838
34. YANG Shu, YANG Xiao-Mei, XIE Xiao-Guang.Theoretical Study of Gas-Phase Reaction of YS+ (1Σ+, 3Φ) with COS: YS++COS→YS2++CO[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1892-1898
35. ZHANG Ming-Bo, GONG Li-Dong.Evolution of the Molecular Face during the Reaction Process of F-+CH3Cl→CH3F+Cl-[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1120-1126
36. LI Tian-Tian, WANG Chao-Yang, XING Li-Dan, LI Wei-Shan, PENG Bin, XU Meng-Qing, GU Feng-Long, HU She-Jun.Reaction Mechanism of 1,4-Dimethoxy Benzene as an Overcharge Protection Additive[J]. Acta Phys. -Chim. Sin., 2012,28(04): 818-822
37. WANG Li-Geng, YUAN Ting, LI Yuan, SHI Wei, NI Zhe-Ming.Interlayer Reaction of Thiosulfate in a Confined Region of Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2012,28(02): 273-282
38. LI Ai-Chang, LI Gui-Hua, ZHENG Yan, FENG Ling-Ling, ZHENG Yan-Jun.Photocatalytic Property and Reaction Mechanism of (Ni-Mo)/TiO2 Nano Thin Film Evaluated with Congo Red[J]. Acta Phys. -Chim. Sin., 2012,28(02): 457-464
39. ZHU Yuan-Qiang, GUO Jian-Chun, YE Zhong-Bin.AuClx (x=1, 3)-Catalyzed Benzannulation Mechanisms between 2-Propynyl-hypnone and Benzyne[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2043-2050
40. XIONG Peng-Fei, ZHONG Bei-Jing, YANG Fan.Heterogeneous Mechanism of C1-C4 on a Platinum Catalyst[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2200-2208
41. HUANG Ying-Heng, TONG Zhang-Fa, WEI Teng-You, LI Bin.Reaction Kinetics of the Intermediate in Synthesis of LiCoPO4 by Solid-State Reaction[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1325-1334
42. DENG Ping, ZHANG Hai-Dong, JIANG Jun-Hao, JIANG Qi-Hua.Reaction Mechanism for Propylene Carbonate Prepared by KI/NH3 Catalysis from Propylene Oxide and CO2[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1386-1392
43. LI Jing-Hong, ZHOU Dan-Hong, REN Jue.Theoretical Study of Ethylene Dimerization on the Ga/HZSM-5 Zeolite[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1393-1399
44. LI Jun-Nan, PU Min, HE Shu-Heng, HE Jing, EVANS David G..Reaction Mechanism of Acetylene Hydrogenation Catalyzed by Pd8 Cluster[J]. Acta Phys. -Chim. Sin., 2011,27(04): 793-800
45. SONG Lei, YU Feng, WU Li-Xia, ZHOU Xiao-Guo, LIU Shi-Lin.Anionic Production Pathways Involved in the Reaction between OH- and CH2ClF[J]. Acta Phys. -Chim. Sin., 2011,27(04): 801-807
46. ZHANG Qing-Feng, ZHENG Zhao-Lei, HE Zu-Wei, WANG Ying.Reduced Chemical Kinetic Model of Toluene Reference Fuels for HCCI Combustion[J]. Acta Phys. -Chim. Sin., 2011,27(03): 530-538
47. LI Xiao-Yan, LIU Qun, ZHENG Shi-Jun, MENG Ling-Peng.Mechanisms and Kinetics of the HOSO+NO Reaction[J]. Acta Phys. -Chim. Sin., 2011,27(03): 564-570
48. WANG Jia-Yong, BI Si-Wei, ZHAO Jun-Feng.Reaction Mechanisms between (Cl-nacnac)Pt(H) and a Terminal Alkyne[J]. Acta Phys. -Chim. Sin., 2011,27(03): 571-576
49. HU Jian-Ping, WANG Jun, TANG Dian-Yong, FU Qin-Chao, ZHANG Yuan-Qin.Reaction Mechanisms of CO Oxidation Catalyzed by Binary Copper Group Cluster Anions[J]. Acta Phys. -Chim. Sin., 2011,27(02): 329-336
50. HOU Ling-Yun, YANG Jin, MA Xue-Song, LIU Wei.Effects of Species in Vitiation Air on Methane-Fueled Supersonic Combustion[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3150-3156
51. CI Cheng-Gang, DUAN Xue-Mei, LIU Jing-Yao, SUN Chia-Chung.Photodissociation Mechanism of Cyanogen Azide[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2787-2792
52. LU Chun-Li, FU Zai-Hui, LIU Ya-Chun, LIU Feng-Lan, QIN Jin-Wei, HE Xiang-Ling, YIN Du-Lin.Selective Oxidation of Ethylbenzene with Hydrogen Peroxide Catalyzed by 5,7-Dibromo-8-quinolinolato Manganese Complexes[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2705-2710
53. WU Li-Xia, YU Feng, LIU Jing, DAI Jing-Hua, ZHOU Xiao-Guo, LIU Shi-Lin.Ab initioMolecular Dynamics Investigation on the Production Channels for the Reaction of O- with CH3F[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2331-2336
54. LIU Xiao-Ming, NI Zhe-Ming, YAO Ping, XU Qian, MAO Jiang-Hong, WANG Qiao-Qiao.Comparison of Three Reaction Mechanisms for the Water Gas Shift Reaction on Au(111) Surface[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1599-1606
55. ZHAO Yi, DONG Dong-Dong, BI Si-Wei.Mechanism of the Model Reaction between CpRu(PH3)2SH and HNCS[J]. Acta Phys. -Chim. Sin., 2010,26(03): 745-750
56. WANG Huan, ZHAO Shu-Feng, LAN Yang-Chun, LIU Xiao, LU Jia-Xing.Electrochemical Reduction Reaction Mechanism of Cinnamonitrile[J]. Acta Phys. -Chim. Sin., 2010,26(02): 277-282
57. CAI Wan-Fei, WANG Xiao-Hui, LI Lai-Cai, TIAN An-Min.Mechanism for the CuX-Catalyzed (X=I, Br) Intramolecular O-Arylation Reaction of N-(ortho-chlorophenyl)benzamide[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2101-2106
58. WANG Yan-Kun, ZHANG Jian-Min, LAN Meng.Temperature Effects on ZnO Film Electrodeposition[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1998-2004
59. WANG Rui-Xin, JIAO Wei-Zhou, GAO Bao-Jiao.Catalytic Performance of P(4VP-co-St)/SiO2-Supported Co Tetraphenylporphyrins for the Aerobic Oxidation of Phenylethane[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1791-1798
60. WEI Qing, XU Bao-En, SUN Cui-Hong, LI Xiao-Yan, MENG Ling-Peng, REN Lei.Reaction Mechanism and Topological Analysis of Electronic Density for the Reaction of HNCS with Cl[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1623-1628
61. NI Zhe-Ming, MAO Jiang-Hong, PAN Guo-Xiang, XU Qian, LI Xiao-Nian.Mechanism of Palladium-Catalyzed Methanol Decomposition for Hydrogen Production[J]. Acta Phys. -Chim. Sin., 2009,25(05): 876-882
62. WANG Yan; ZENG Xiao-Lan; WANG Ling.Diels-Alder Reactions between Silabenzenes and Dienophiles[J]. Acta Phys. -Chim. Sin., 2009,25(02): 371-376
63. CHEN Xin, LI Ying.Cycloaddition Reaction Mechanism between Dichloromethylene Germylene and Methanethial[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2229-2235
64. GAO Li-Guo; SONG Xiao-Li; CHEN Xiao-Xia; WANG Yong-Cheng.C—S Activation of CS2 by Y+ in Gas Phase[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2083-2088
65. MAO Jiang-Hong; NI Zhe-Ming; PAN Guo-Xiang; XU Qian.Mechanism of the Copper-Catalyzed Water Gas Shift Reaction[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2059-2064
66. WANG Jun-Xia; YU Feng; LIU Jing; LIU Shi-Lin; ZHOU Xiao-Guo.Reaction Mechanism of Hydroxyl Anion with Benzene[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1393-1399
67. XU Bao-En; LI Xiao-Yan; ZENG Yan-Li; MENG Ling-Peng; ZHANG Ping; LIU Zhan-Rong.Reaction Mechanisms and Topological Studies of Electronic Density on the Reaction of CH3SH with CN·Radical[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1245-1251
68. TIAN Yan; HE Tian-Jing; CHEN Dong-Ming; LIU Fan-Chen.Reaction Mechanism and Kinetics for the Reaction of ·OH+CH3CN[J]. Acta Phys. -Chim. Sin., 2008,24(04): 587-594
69. HU Qi-Shan; LIU Jun-Ling; LI Lai-Cai; TIAN An-Min.Reaction Mechanism of the Activation of Ethane via Cobalt AtomCatalysis[J]. Acta Phys. -Chim. Sin., 2007,23(06): 916-920
70. HUANG Ke-Long; LIU Ren-Sheng; YANG You-Ping; LIU Su-Qin; WANG Li-Ping.Shape-controlled Synthesis and Formation Mechanism of Co3O4 by Solvothermal Method[J]. Acta Phys. -Chim. Sin., 2007,23(05): 655-658
71. YANG Li-Juan;MENG Ling-Peng;ZENG Yan-Li;ZHENG Shi-Jun
.Quantum Chemistry and Electron Density Topological Study on the Reaction of CH2NH(s) with O(3P) Atom[J]. Acta Phys. -Chim. Sin., 2007,23(03): 311-316

72. LIU Le-Yan;GENG Zhi-Yuan;ZHAO Cun-Yuan;WANG Yong-Cheng;LI Zhao-Hui .Gas-phase Reaction Mechanism of Allyl anion with N2O[J]. Acta Phys. -Chim. Sin., 2007,23(02): 217-222
73. YUAN Li-Xia;YANG Guo-Ying;SUN De-Sheng;WANG Zun-Yao;CHI Qing-Qing.Theoretical and Experimental Study on the Reaction Mechanism of Br2+Cl2=2BrCl[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1191-1195
74. ZHAO Ying-Guo;ZHOU Xiao-Guo;YU Feng;DAI Jing-Hua;LIU Shi-Lin.Investigation of the Mechanism of the Reaction between Atomic Oxygen Radical Anion and Benzene[J]. Acta Phys. -Chim. Sin., 2006,22(09): 1095-1100
75. LIU Jun-Ling;SHANG Jing; WANG Pei-Yi; LI Lai-Cai1;TIAN An-Min.Theory of the Reaction Mechanismfor CH3CHF Radical and HNCO[J]. Acta Phys. -Chim. Sin., 2006,22(08): 921-925
76. WANG Zhou-Cheng;HUANG Long-Men;TANG Yi;NI Yong-Jin;LIN Chang-Jian.Preparation of Co-YSZ/HAp Nano-composite Coating on Ti Substrate by Electrochemical Method[J]. Acta Phys. -Chim. Sin., 2006,22(05): 590-595
77. LÜ Ling-Ling; WANG Yong-Cheng.Theoretical Studies on the Reaction Mechanism of Au+(1S, 3D) and N2O(1Σ+)[J]. Acta Phys. -Chim. Sin., 2006,22(03): 265-269
78. CHANG Jie; TENG Bo-tao; XIANG Hong-wei; LI Yong-wang; SUN Yu-han.UBI-QEP Analysis for the Mechanism of Fischer-Tropsch Synthesis[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1223-1228
79. GAO Li-guo; WANG Yong-cheng; GENG Zhi-yuan; CHEN Xiao-xia; LÜ Lingling; DAI Guo-liang; WANG Dongmei.Theoretical Study of the Reaction of Sc+ and Ti+ with CS2 in Gas Phase[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1102-1107
80. LIU Hong-yan; WANG Zun-yao; LIU Shu-shen.Theoretical Study on the Reaction Mechanism of Cl2+2HI=2HCl+I2[J]. Acta Phys. -Chim. Sin., 2005,21(09): 961-966
81. WANG Yong; LI Hao-Ran; WU Tao; WANG Cong-Min; HAN Shi-Jun.Reaction Mechanism Study for the Synthesis of Alkylimidazolium-based Halide Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2005,21(05): 517-522
82. ZHOU Jun-Hong;ZENG Yan-Li;MENG Ling-Peng;ZHENG Shi-Jun.Reaction Mechanisms and Topological Studies of Electron Density on the Reaction of ClO and ClO Radical[J]. Acta Phys. -Chim. Sin., 2005,21(02): 166-172
83. Wang Yong-Cheng;Dai Guo-Liang;Geng Zhi-Yuan;Lü Ling-Ling;Wang Dong-Mei.A Density Functional Theory (DFT) Study on the Reaction of Ozone with Ethylene Radicals[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1071-1077
84. Zhao Xin-Sheng.The Mechanisms on the Heterogeneous Reactions in Atmospheric Ozone Depletion[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 936-938
85. Ding Wan-Jian;Fang Wei-Hai;Liu Ruo-Zhuang.Mechanisms of Unimolecular Reactions for Ground-state Pyruvic Acid[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 911-916
86. Xue Ke-Yi;Gao Qing-Yu;Liu Bing;Xu Liang-Qin.Dependence of the H2O2-Na2S2O3 Reaction on pH and [H2O2]0/[Na2S2O3]0[J]. Acta Phys. -Chim. Sin., 2004,20(07): 772-775
87. Su Yu-Zhi;Guo Shi-Heng;Xiao Yi-Zhi;Xiao Min;Yang Qi-Qin.Electrode Kinetics of 2,2’-diaminophenyloxydisulfide[J]. Acta Phys. -Chim. Sin., 2004,20(05): 518-523
88. Yun Hong;Zhang Hui;Chen Jian-Hua;Chen Hong-Bo;Lin Chang-Jian.The Intermediate State and Mechanism of the Steam Reforming of Methanol over CuO-ZnO-ZrO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(05): 524-528
89. Zhai Zhi-Cai;Bai Yun-Shan;Wang Zun-Yao;Wang Lian-Sheng.The Reaction Mechanism of Br2+2HI=2HBr+I2 by Density Functional Theory[J]. Acta Phys. -Chim. Sin., 2004,20(04): 400-404
90. Han Shi-Tong;Xi Hai-Ling;Fu Xian-Zhi;Wang Xu-Xu;Ding Zheng-Xin;Lin Zhi-Cong;Su Wen-Yue.Study on the Photocatalytic Degradation of a Simulate Agent (2-CEES) of Mustard Gas[J]. Acta Phys. -Chim. Sin., 2004,20(03): 296-301
91. Zhong Qi-Ling;Zhang Xiao-Hong;Su Xiao-Qiong;Zhang Lei;Liu Yue-Long;Ren Bin;Tian Zhong-Qun.The Investigation of Electro-oxidation Behavior and In-situ Surface Enhanced Raman Spectrum of Isosafrole on Rough Pt[J]. Acta Phys. -Chim. Sin., 2004,20(01): 94-97
92. Liao Chuan-Ping;Gu Ming-Yuan.Mechanism for the Reduction of Dichromate in the Polymerization of Aniline[J]. Acta Phys. -Chim. Sin., 2003,19(07): 580-583
93. Li Lai-Cai;Tian An-Min.Quantum Study on the Reaction Mechanism of CH3(2A′) Radicals with Ozone Reaction[J]. Acta Phys. -Chim. Sin., 2003,19(07): 626-629
94. Li Yong-Hong;Chen Li-Ping;Xu Wen-Yuan;Hong San-Guo.Reaction Mechanism of the Gas-phase Elimination of 2-bromopropionic Acid[J]. Acta Phys. -Chim. Sin., 2003,19(05): 389-392
95. Li Xiao-Ping;Liu Zhi-Hong;Gao Shi-Yang;Hu Man-Cheng;Xia Shu-Ping;.The Kinetics of Dissolution and Phase Transformation of 2MgO•2 B2O3•MgCl2•14H2O in Water at 87 ℃[J]. Acta Phys. -Chim. Sin., 2003,19(02): 181-184
96. Wang Jin;Chen Hong-Bo;Yun Hong;Lin Jing-Dong;Yi Jun;Zhang Hong-Bin;Liao Dai-Wei.Study on Rh-ZnO/MWNTs Catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2003,19(01): 65-69
97. Chen Di-Zhao;Liang Yi-Zeng;Xu Cheng-Jian.Rank Analysis on Two-dimensional Kinetic Data and Its Related Application[J]. Acta Phys. -Chim. Sin., 2002,18(10): 924-929
98. Liu Zhao-Qiong;Ma Jun;Zhang Zhao-Liang;Yang Xi-Yao.The Mechanism of SO2, NO and CO Reaction over Sn0.5Ti0.5O2 Catalyst[J]. Acta Phys. -Chim. Sin., 2002,18(03): 193-196
99. Xi Jing-Yu;Wang Zhi-Fei;Wang Wei-Ping;Lü Gong-Xuan.In-situ XPS Study for Reaction Mechanism of Methanol Decomposition over Cu-Ni/Zn Catalyst[J]. Acta Phys. -Chim. Sin., 2002,18(01): 82-86
100. Shi Huai-Bin;Shao Chun-Lin;Yu Zeng-Liang.Mechanism of the Reaction between Low Energy N and CH3COCH3 with D2O as Solvent[J]. Acta Phys. -Chim. Sin., 2001,17(11): 986-990
101. Liu Zhi-Jian;Cai Zun-Sheng;Ning Yu;Li Yan-Ni;Wang Gui-Chang;Zhao Xue-Zhuang.BrO-3-SO2-3-H-KMnO4 pH Oscillation Reaction[J]. Acta Phys. -Chim. Sin., 2001,17(08): 676-681
102. Liu Gou-Sheng;Song Xing-Fu;Yu Jian-Guo;Qian Xu-Hong.Theoretical Study on the Reaction Mechanism of H2O2 with N2O[J]. Acta Phys. -Chim. Sin., 2001,17(06): 491-495
103. Peng Qing-Jing;Duan You-Gou;Ouyang Yu-Zhu;Fu Wei-Chang.Regioselective Oxidation of Phenylethane with Air Catalyzed by μ-oxo-bis-manganese Porphyrins[J]. Acta Phys. -Chim. Sin., 2001,17(04): 292-294
104. Wang Zun-Yao;Xiao He-Ming;Li Jin-Shan.Mechanism of the Reactions F+Cl2->ClF +Cl and Cl′F+Cl->Cl′+ClF[J]. Acta Phys. -Chim. Sin., 2001,17(02): 107-110
105. Chen Bo-Zhen, Huang Ming-Bao, Su Hong-Mei, Kong Fan-Ao.Mechanism of the CH2+O2 Reaction[J]. Acta Phys. -Chim. Sin., 2000,16(10): 869-872
106. Cai Xiao-Ping, Fang De-Cai, Fu Xiao-Yuan.Reaction Mechanism of CIONO2 and O(3P)[J]. Acta Phys. -Chim. Sin., 2000,16(08): 689-693
107. Zhao Zhen-Bo, Sun Wen-Dong, Yang Xiang-Guang, Ye Xing-Kai, Wu Yue.Active Components and Mechanism of Isobutane Alkylation with Butenes in the Catalytic System of HPAs+AcOH[J]. Acta Phys. -Chim. Sin., 2000,16(07): 613-620
108. Kuang Ping-Xian, Chen Bo-Zhen, Huang Ming-Bao.Mechanism of the C(3P)H2S Reaction[J]. Acta Phys. -Chim. Sin., 2000,16(05): 389-392
109. Wu Peng, He Shao-Ren.Theoretical Study on the Mechanism of [2+2] Cycloaddition of Ketenimine with Imine[J]. Acta Phys. -Chim. Sin., 2000,16(03): 243-247
110. Zhu Yi-Xiang, Chai Yun-Zhou, Liu Zheng-Yang, Huang Su-Mei, Cheng Xiang-Ming.XRD Characterization of Interaction between Potassium Promoter and Magnetite[J]. Acta Phys. -Chim. Sin., 2000,16(02): 126-132
111. Meng Ling-Peng, Zheng Shi-Jun, Cai Xin-Hua.Theoretical Studies in the Reaction of Atomic O(3P) with CS2[J]. Acta Phys. -Chim. Sin., 1999,15(11): 990-996
112. Liu Dan, Chen Guang-Ju, Liu Ruo-Zhuang, Fu Xiao-Yuan.Exploration of the Mechanism of 2-bromoacetic Acid Gas-phase Elimination Process[J]. Acta Phys. -Chim. Sin., 1999,15(10): 872-876
113. Chen Tong, Li Wen-Zhao, Yu Chun-Ying.Investigation of the Interaction between NiO and Support,γ-Al2O3,for Oxidative Dehydrogenation of Ethane[J]. Acta Phys. -Chim. Sin., 1999,15(07): 613-618
114. Zhou Zhi-Gang, Dai Qian-Huan.Theoretical Study for the Mechanism of Electrophilic Addition to Alkenes Reactions[J]. Acta Phys. -Chim. Sin., 1999,15(06): 500-505
115. Shi Tu-Jin, Li Zong-He, Liu Ruo-Zhuang.Mechanism of Reaction HNCO+OH->H2O+NCO[J]. Acta Phys. -Chim. Sin., 1999,15(03): 247-252
116. Zhu Yi-Xiang, Chen Rong-Qin, Feng Lei, Wang Jun.Mossbuer Spectroscopic Studies of Fe2O3-K2O-Based Catalysts for Ethylbenzene Dehydrogenation[J]. Acta Phys. -Chim. Sin., 1999,15(03): 234-240
117. Feng Hai-Xia, Zhu Zhi-Ang, Wang Chuan-Zhong, Ruan Wen-Juan, Li Ying, Chen Rong-Ti.Kinetics on the Axial Coordination Reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol[J]. Acta Phys. -Chim. Sin., 1999,15(02): 167-172
118. Wang Yan, Fang De-Cai, Fu Xiao-Yuan.Theoretical Studies on the Mechanism of Dimerization Reactions of Thioketene[J]. Acta Phys. -Chim. Sin., 1999,15(01): 35-39
119. Hu Hai-Quan, Liu Cheng-Bu.The Reaction Mechanism of the Biradical CF2 and O3[J]. Acta Phys. -Chim. Sin., 1998,14(12): 1104-1107
120. Xu Si-Chuan, Zhao Xin-Sheng.Investigation of the Reaction of Chlorine Nitrate on lce Surface[J]. Acta Phys. -Chim. Sin., 1998,14(11): 988-994
121. Zhang Guo-Dong.Study on the Reaction Rate and Mechanism of Ni-P Electroless Plating[J]. Acta Phys. -Chim. Sin., 1998,14(05): 429-434
122. Xu Si-Chuan, Zhao Xin-Sheng.Reaction Mechanism of Chlorine Nitrate with HCl on lce Surface[J]. Acta Phys. -Chim. Sin., 1998,14(01): 5-7
123. Qian Ying,Wang Yan,Feng Wen-Lin,Liu Ruo-Zhuang.Theoretical Calculation on the Canonical Rate Constants for the Addition Reaction of 1,3-cyclohexa-diene with Propylene[J]. Acta Phys. -Chim. Sin., 1997,13(12): 1084-1089
124. Song Wei-Ping,Fu Xiao-Yuan,He Shao-Ren.Theoretical Studies on the Mechanism of Chloro-carboxylic Acids Gas-phase Elimination Process[J]. Acta Phys. -Chim. Sin., 1997,13(10): 908-915
125. Wang Zhi-Xiang,Huang Ming-Bao,Liu Ruo-Zhuang.Ab initio Study on the Reaction of CH Radical with O2[J]. Acta Phys. -Chim. Sin., 1997,13(05): 385-388
126. Ruan Wen-Juan,Zhu Zhi-Ang,Lin Hua-Kuan,Chen Zheng-Hua,Chen Hong-Wei,Yang Xiu-Lin.Kinetic Studies on the Formation Reaction of Zinc(II)、Cadmium(II) and Mercury(II) with Porphyrins[J]. Acta Phys. -Chim. Sin., 1997,13(04): 335-343
127. Song Wei,Liang Zhen-Cheng,Qin Yong-Ning.Influence of the Method of Adding Potassium Promoter on Catalyst for Dehydrogenation of Diethylbenzene[J]. Acta Phys. -Chim. Sin., 1997,13(01): 79-82
128. Sheng Ying-Hong,Fang De-Cai,Fu Xiao-Yuan.Theoretical Study on the Mechanism of the Cycloaddition Reactions Between Methyleneketene and 5-methylene-1,3-dioxan-4,6-dione[J]. Acta Phys. -Chim. Sin., 1996,12(06): 496-501
129. Pang Xian-Yong,Feng Wen-Lin,Wang Yan,Zhang Shao-Wen.Theoretical Study on the Singlet-state and the Triplet-state Mechanisms for the Reaction CH3O with NO[J]. Acta Phys. -Chim. Sin., 1996,12(05): 391-395
130. Zhu Zhi-Ang, Yan Xi, Zhang Zhi-Hui, Ma Gang, Lin Hua-Kuan, Chen Rong-Ti.Thermodynamics and Kinetics of Coordination Reaction of Imidazolates with Cobalt(II) Porphyrin[J]. Acta Phys. -Chim. Sin., 1996,12(04): 372-376
131. Kang Qing-Hua,Zhong Shun-He.Mechanism of Laser Stimulated Surface Reaction of Ethanol Oxidative Coupling to 1,4-Butanediol[J]. Acta Phys. -Chim. Sin., 1995,11(06): 498-503
132. Li Qing-Shui, Lin Yu-Qin, Liao Yuan-Yan.Studies on Catalytic Dehydrogenation of Methanol to Formaldehyde[J]. Acta Phys. -Chim. Sin., 1995,11(05): 442-446
133. Xu Zhi-Jin,Yan Ji-Min.Investigation on the Reaction Barriers of He+C60↔(He@C60)[J]. Acta Phys. -Chim. Sin., 1995,11(04): 346-350
134. Zhang Lin-Yang,Zhang Jia-Mu,W.Fuss.The Effect of Light Intensity on the Photoinduced BrC2F4Br+C2F4 Telomerization Reaction[J]. Acta Phys. -Chim. Sin., 1995,11(04): 308-314
135. Ruan Wen-Juan, Zhu Zhi-Ang, Huang Xiao-Qun, Chen Rong-Ti, Jiang Dong-Qing.Kinetic Study on Porphinatoiron(III) Catalyzing Decomposition of β-Carotene[J]. Acta Phys. -Chim. Sin., 1994,10(04): 312-318
136. Ying Li-Ming, Han De-Gang, Yang Hui-Xing.Reaction Kinetics and Mechanism of the Pyrolysis of Isobutane at High Temperature[J]. Acta Phys. -Chim. Sin., 1994,10(03): 223-229
137. Zhu Zhi-Ang; Huang Xiao-Qun; Chen Rong-Ti.Kinetic Study of the Electrophilic Substitution Reaction of Copper ion with Meso-tetrakis (Meta-methylphenyl) Porphyrin Cadmium (II)[J]. Acta Phys. -Chim. Sin., 1993,9(05): 635-641
138. Jiang Xiong.An Investigation on the Cathodic Reduction of Co2+ Ions[J]. Acta Phys. -Chim. Sin., 1993,9(01): 129-133
139. Yang Song-Qing; Jiang Han-Ying.Electrochemical Studies on Pyrite[J]. Acta Phys. -Chim. Sin., 1991,7(06): 735-739
140. Dai Jian-Bo; Bai Ling-Jun; Zhang Yi-Bao; Zang Ya-Ru; Jiang Dong-Qing; Gu Zhuo-Ying; Zhao Xue-Zhuang.Research on the Oxidation of Adrenaline——Kinetics and Mechanism of the Oxidation Reaction and the Radical Intermidate[J]. Acta Phys. -Chim. Sin., 1991,7(03): 260-269
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top