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Acta Physico-Chimica Sinica  2001, Vol. 17 Issue (03): 265-270    DOI: 10.3866/PKU.WHXB20010317
Article     
Coupling Effect for TiO2/SnO2 Compound Semiconductor Photocatalyst
Liu Ping;Zhou Ting-Yun;Lin Hua-Xiang;Fu Xian-Zhi
Research Institute of Photocatalysis,Fuzhou University,Fuzhou 350002
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Abstract  The photocatalyst of TiO2/SnO2 compound semiconductor was prepared by improved solgel method.The coupling mechanism and the factors affecting photoc atalytic efficiency were studied by using XRD,gas chromatography,granularity equ ipment and surface photovoltage spectroscopy.TiO2/SnO2 catalysts were employed f or photocatalytic degradation of formaldehyde.The experimental results showed th at phtocatalytic efficiency of TiO2 catalyst was greatly enhanced by adding SnO2 into TiO2,and the optimum content of SnO2 was about 20 %(mol).According to the particle close packing rule and experimental result,the strong and weak couplin g effect models for TiO2/SnO2 compound semiconductor were proposed.The coupling effect was derived from the close packing structure of the photocatalyst particl es.The critical bourn between enhanced and weaken effect depends on whether the close packing structure is threedimensional or not.The photocatalyst doped wit h SnO2 less than 20 %(mol) presented a threedimensional structure,which impro ved the activity of the photocatalyst due to effective separation of the photoge nerated carriers.The opposite situation was occurred when content of SnO2 was mo re than 20 %(mol).

Key wordsPhotocatalysis      Coupling effect      TiO2/SnO2     
Received: 08 October 2000      Published: 15 March 2001
Corresponding Authors: Fu Xian-Zhi     E-mail: xzfu@fzu.edu.cn
Cite this article:

Liu Ping;Zhou Ting-Yun;Lin Hua-Xiang;Fu Xian-Zhi. Coupling Effect for TiO2/SnO2 Compound Semiconductor Photocatalyst. Acta Physico-Chimica Sinica, 2001, 17(03): 265-270.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB20010317     OR     http://www.whxb.pku.edu.cn/Y2001/V17/I03/265

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