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Acta Physico-Chimica Sinica  2002, Vol. 18 Issue (06): 490-494    DOI: 10.3866/PKU.WHXB20020603
Article     
Change of Adsorption State of Oligodeoxynucleotides on the Silver Electrode Surface with Change of Potential
Shen He-Bai;Zhou Wen-Jun;Yang Hai-Feng;Yu Pei-Tao
Chemistry Department of Life and Environmental Science College, Shanghai Normal University, Shanghai 200234
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Abstract  The oligodeoxynucleotides is anchoraged on the silver electrode surface by means of physical methods. The in situ Electrochemistry-Surface Enhanced Raman Scattering (SERS) Spectrum is used to study the adsorption state of 26-mers oligodeoxynucleotides (ODN) and 13-mers ODN on the electrode surface respectively. The SERS spectra of oligdeoxynucleotides based on the silver electrode have obtained. The results of study of the SERS spectra change of ODN with the change of potential on the silver electrode demonstrate that the oligodeoxynucleotides adsorbed on the silver electrode surface primarily through the special base-Adenine (A).The adsorption state changes with the variation of the potential on the electrode. The shorter ODN changes more quickly and is more sensitive to the change of potential than the longer ODN(see Table 1).

Key wordsOligodeoxynucleotide (ODN)      SERS      Adenine      Adsorption      Silver electrodes     
Received: 16 October 2001      Published: 15 June 2002
Corresponding Authors: Shen He-Bai     E-mail: shenhb@shtu.edu.cn
Cite this article:

Shen He-Bai;Zhou Wen-Jun;Yang Hai-Feng;Yu Pei-Tao. Change of Adsorption State of Oligodeoxynucleotides on the Silver Electrode Surface with Change of Potential. Acta Physico-Chimica Sinica, 2002, 18(06): 490-494.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20020603     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2002/V18/I06/490

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