ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 1998,Vol.14>> Issue(02)>> 178-180     doi: 10.3866/PKU.WHXB19980216         中文摘要
The Dispersed States of Manganese Species on Mn-O/ZrO2 Catalysts and its Influents on the Catalytic Performance
Zhou Ren-Xian, Chen Fang, Jiang Xiao-Yuan, Zheng Xiao-Ming
Institute of Catalysis,Hangzhou University,Hangzhou 310028
Full text: PDF (621KB) HTML Export: BibTeX | EndNote (RIS)

Mn-O/ZrO2 catalysts were prepared by impregnation method and were characterized by XRD, TPR and TPD-MS. The oxidation activity of CO on these catalysts was also studied. The results indicated that the interaction between MnOx and ZrO2 would restrained the phase transformation of ZrO2, and raised the dispersion of MnOx species on ZrO2. The highly-dispersed MnOx on ZrO2 is predominant contributors in catalytic activity of the Mn-O/ZrO2 catalysts.

Keywords: Manganese oxide   ZrO2   Dispersed state   Catalytic performance  
Received: 1997-05-26 Accepted: 1997-09-22 Publication Date (Web): 1998-02-15
Corresponding Authors: Zhou Ren-Xian Email:

Cite this article: Zhou Ren-Xian, Chen Fang, Jiang Xiao-Yuan, Zheng Xiao-Ming. The Dispersed States of Manganese Species on Mn-O/ZrO2 Catalysts and its Influents on the Catalytic Performance[J]. Acta Phys. -Chim. Sin., 1998,14 (02): 178-180.    doi: 10.3866/PKU.WHXB19980216
1. YU Liang, YU Fang-Yong, YUAN Li-Li, CAI Wei-Zi, LIU Jiang, YANG Cheng-Hao, LIU Mei-Lin.Electrical Performance of Ag-Based Ceramic Composite Electrodes and Their Application in Solid Oxide Fuel Cells[J]. Acta Phys. -Chim. Sin., 2016,32(2): 503-509
2. HUANG Wei-Xin, QIAN Kun, WU Zong-Fang, CHEN Shi-Long.Structure-Sensitivity of Au Catalysis[J]. Acta Phys. -Chim. Sin., 2016,32(1): 48-60
3. HAN Yong, XU Qian, JU Huan-Xin, ZHU Jun-Fa.Growth, Electronic Structure and Thermal Stability of Ni on ZrO2(111) Thin Film Surfaces[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2151-2157
4. YU Zai-Lu, XIE Peng-Fei, TANG Xing-Fu, YUE Ying-Hong, HUA Wei-Ming, GAO Zi.Selective Catalytic Reduction of NO with NH3 over MnOx-CeO2-WO3-ZrO2:Effect of Calcination Temperature[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1175-1179
5. WANG Guan-Nan, CHEN Li-Min, GUO Yuan-Yuan, FU Ming-Li, WU Jun-Liang, HUANG Bi-Chun, YE Dai-Qi.Effect of Chromium Doping on the Catalytic Behavior of Cu/ZrO2/CNTs-NH2 for the Synthesis of Methanol from Carbon Dioxide Hydrogenation[J]. Acta Phys. -Chim. Sin., 2014,30(5): 923-931
6. ZHANG Xuan-Xuan, RAN Fen, FAN Hui-Li, KONG Ling-Bin, KANG Long.Hydrothermal Synthesis and Electrochemical Measurements of Interconnected Porous Carbon/MnO2 Composites[J]. Acta Phys. -Chim. Sin., 2014,30(5): 881-890
7. TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua.Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1876-1882
8. ZHANG Hui, MENG Hui-Min.Stability and Failure Behavior of Gas Diffusion Electrodes in Strong Acid Media for Electrolytic Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2013,29(12): 2558-2564
9. LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou.Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1681-1690
10. DING Peng, XU You-Long, SUN Xiao-Fei.Synthesis and Performance of Nano MnO as an Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2013,29(02): 293-297
11. HE Sai-Nan, HU Cai-Yuan, XIAO Ge, ZHENG Hua-Jun.Hydrothermal Synthesis and Amperometric Determination of Hydrogen Peroxide of Highly-Dispersed MnO2 Nanofibers[J]. Acta Phys. -Chim. Sin., 2012,28(03): 630-634
12. ZHUANG Ke, QIU Jing, XU Bo-Lian, FAN Yi-Ning.Promotional Effect of Cerium Oxide on the Catalytic Properties of Ce-Mn-Ti-O Catalysts for Selective Catalytic Reduction of NO[J]. Acta Phys. -Chim. Sin., 2012,28(03): 681-685
13. MAN Mei-Ling, LU Chun-Hai, CHEN Wen-Kai, LI Yi, ZHANG Yong-Fan.Adsorption Properties of CO Molecules on Pt/t-ZrO2(101) Surfaces[J]. Acta Phys. -Chim. Sin., 2012,28(01): 51-57
14. HE Jie, FAN Yi-Ning.Dispersion States and Brønsted Acidity Feature of Nb2O5on t-ZrO2[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2416-2420
15. XUE Rong, YAN Jing-Wang, TIAN Ying, YI Bao-Lian.Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2340-2346
16. LIANG Li-Ping, ZHU Qing, ZHAO Yong-Xiang, LIU Dian-Sheng.Effects of Heat Treatment on the Structure and Properties of the Tungstophosphoric Acid-Modified Zirconia Aerogel Solid Acids[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1933-1940
17. ZHAO Gao-Feng, XIANG Bing, SHEN Xue-Feng, SUN Jian-Min, BAI Yan-Zhi, WANG Yuan-Xu.Structures and Stabilities of Small Zirconium Oxide Clusters[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1095-1102
18. MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui.Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2011,27(04): 893-899
19. ZHU Qing, LIANG Li-Ping, JIA Zhi-Qi, GAO Chun-Guang, ZHAO Yong-Xiang.Polyoxotungstate-Modified Zirconia Aerogel as a Solid Catalyst for Tetrahydrofuran Polymerization[J]. Acta Phys. -Chim. Sin., 2011,27(02): 491-498
20. SHI Yan-Hua, MENG Hui-Min.Electrochemical Behavior of IrO2 Electrodes in the Anodic Electrodeposition of MnO2[J]. Acta Phys. -Chim. Sin., 2011,27(02): 461-467
21. TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
22. CHE Hong-Wei, HAN Shu-Hua, HOU Wan-Guo, LIU Ai-Feng.Novel Synthesis of Mesoporous Nanocrystalline Zirconia[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2177-2181
23. ZHANG Sheng-Hong, ZHANG Hong-Peng, LI Wei-Zhen, ZHANG Wei, HUANG Hua, LIU Hai-Chao.Effects of Zirconia Crystallite Phases on the Structures of MoOx/ZrO2 Catalysts and Their Properties in the Selective Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1879-1886
24. PANG Xu, MA Zheng-Qing, ZUO Lie.Sn Doped MnO2 Electrode Material for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2433-2437
25. SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
26. GAO Qiang; LIU Ya-Fei; HU Zhong-Hua; ZHENG Xiang-Wei; WEN Zu-Biao.Electrochemical Properties of Manganese Oxide Surface-Modified Activated Carbon Electrode Materials[J]. Acta Phys. -Chim. Sin., 2009,25(02): 229-236
27. CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
28. LI Wei-Zhen, LIU Hai-Chao.Solvent Effects on the Solvothermal Synthesis of PureMonoclinic and Tetragonal Zirconia Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2172-2178
29. ZHANG Rui-Min; FAN Guang-Yin; LI Cheng; WANG Ying-Ying; LI Rui-Xiang; CHEN Hua; LI Xian-Jun.Hydrogenation of Quinoline over Ru/ZrO2·xH2O[J]. Acta Phys. -Chim. Sin., 2008,24(06): 965-970
30. SHI Yan-Hua; MENG Hui-Min; SUN Dong-Bai; NI Yong-Le; CHEN Dong.Effect of SbOx+SnO2 Intermediate Layer on the Properties of Ti-based MnO2 Anode[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1553-1559
31. JIA Li-Tao;FANG Ke-Gong;CHEN Jian-Gang;SUN Yu-Han .Effect of Pretreatment Atmosphere on the Structure of the Co-ZrO2 Catalyst Prepared by Precipitation Method[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1404-1408
32. SHEN Yong;WU Quan-Zhou;LI Yu-Guang.Three Dimensional Ordered Macroporous ZrO2 Prepared by Directly Calcining ZrOCl2[J]. Acta Phys. -Chim. Sin., 2006,22(09): 1121-1125
33. LIU Jian;ZHAO Zhen;XU Chun-Ming.The Structures of VOx/ZrO2 and K-VOx/ZrO2 Catalysts and Their Catalytic Performances for Diesel Soot Oxidation[J]. Acta Phys. -Chim. Sin., 2005,21(02): 156-160
34. MA Zhong-Yi;YANG Cheng;DONG Qing-Nian;WEI Wei;LI Wen-Huai;SUN Yu-Han.A Study of CO2/H2 Adsorption on Zirconia Polymorphs[J]. Acta Phys. -Chim. Sin., 2005,21(02): 225-228
35. Ma Zhong-Yi;Xu Run;Yang Cheng;Wei Wei;Li Wen-Huai;Sun Yu-Han.Preparation and Surface Properties of Different Zirconia Polymorphs[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1221-1225
36. Zeng Li;Wang Chun-Ming;Wei Ji-Ying;Zhu Yue-Xiang;Xie You-Chang.Preparation and Characterization of CrOx/ZrO2 with High Thermal Stability and High Specific Surface Area[J]. Acta Phys. -Chim. Sin., 2004,20(03): 251-255
37. Cheng Hu-Min;Ma Yu-Rong;Liao Fu-Hui;Ma Ji-Ming;Qi Li-Min.Synthesis of Mesoporous Zirconia with Hydrothermal Homogeneous Precipitation Method[J]. Acta Phys. -Chim. Sin., 2003,19(04): 326-328
38. Yang Xu-Fei;Li Wei-Bin.Preparation of Zirconia Zanoparticles in Reverse Microemulsion[J]. Acta Phys. -Chim. Sin., 2002,18(01): 5-9
39. Li Ying;Gong Jiang-Hong;Tang Zi-Long;Xie Yu-Sheng.Temperature-Independent Activation Energy for Ionic Conduction of Zirconia Based Solid Electrolytes[J]. Acta Phys. -Chim. Sin., 2001,17(09): 792-796
40. Guo Yuan;Li Yong-Jun;He Mao-Xia;Xia Xi.Observation of Electron-Transfer Inverted Region in γ-MnO2/K3[Fe(CN)6] Solution Interface[J]. Acta Phys. -Chim. Sin., 2001,17(07): 636-640
41. Li Xu-Yuan,Zhang Zi-Ping,Ma Jian-Tai,Zhu Zong-Zhen,Meng Yi-Min.The Catalytic Activity for CO Oxidation and Characterization of Perovskite-type Oxides Catalysts La1+X/2Sr1-x/2Co1-xCuxO3[J]. Acta Phys. -Chim. Sin., 1996,12(06): 502-507
42. Zhou Ren-Xian,Chen Ping,Zheng Xiao-Ming,Chen Lin-Shen.The Lnteraction between Active Phase and Support and the TPR Characteristics on CuO/ZrO2 Catalyst[J]. Acta Phys. -Chim. Sin., 1996,12(05): 464-467
43. Liu Yuan,Zhong Bing,Peng Shao-Yi,Wu Dong,Fan Wen-Hao.The Preparation and Characterization of Ultrafine ZrO2[J]. Acta Phys. -Chim. Sin., 1995,11(09): 781-784
44. Xu Bo-Qing,Yamaguchi Tsutomu.Characterization of Acid-base Property of ZrO2 by Thermal Desorption:III.Dual Adsorption of Phenol and NH3 or CO2[J]. Acta Phys. -Chim. Sin., 1995,11(04): 337-341
45. Gao Zi, Cui Jun.Studies on the Dispersion States of Nickel Salt and Oxide on NaY Zeolites[J]. Acta Phys. -Chim. Sin., 1994,10(11): 992-997
46. Xu Bai-Qing, Yamaguchi Tsutomu, Tanabe Kozo, Liang Juan, Zheng Lu-Bin.Characterization of Acid-base Property of ZrO2 by Thermal Desorption: I. TPD Studies of Acid and Base Probes[J]. Acta Phys. -Chim. Sin., 1994,10(02): 107-113
47. Xu Bai-Qing, Yamaguchi Tsutomu, Tanabe Kozo, Liang Juan, Zheng Lu-Bin.Characterization of Acid-Base Property of ZrO2 by Thermal Desorption: II. Dual Adsorption of NH3 and CO2[J]. Acta Phys. -Chim. Sin., 1994,10(02): 114-120
48. Ji Wei-Jie; Shen Shi-Kong; Li Shu-Ben; Wang Hong-Li.Dispersion State of Ferric Oxide on ZrO2 and its Influence on the Catalytic Performance[J]. Acta Phys. -Chim. Sin., 1993,9(03): 311-318
49. Xu Bai-Qing; Liang Juan; Zheng Lu-Bin; Yamaguchi Tsutomua; Tanabe Kozoa.TPD and IR Studies on the Decomposition of Formic Acid Adsorbed on ZrO2[J]. Acta Phys. -Chim. Sin., 1991,7(06): 712-715
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top