Acta Phys. -Chim. Sin. ›› 1994, Vol. 10 ›› Issue (04): 293-296.doi: 10.3866/PKU.WHXB19940402

• Communication • Previous Articles     Next Articles

Chemiluminescence of the Reaction of He*(23S)/CO2 with CS2

Hu Yi-Hua, Chu Yan-Nan, Ni Jin-Zhi, Li Ying-Chun, LI  Shu-Chao, Cao De-Zhao, Guo Jing-Zhong, Liu Chuan-Pu, Gu Yue-Shu   

  1. Laser Spectroscopy Laboratory, Anhui Institute of Optics and Fine Mechanics, Academia Sinica, Hefei 230031| Department of Chemistry, Shandong Univeristy, Jinan 250100
  • Received:1994-01-10 Revised:1994-02-28 Published:1994-04-15
  • Contact: Chu Yan-Nan

Abstract:

The reaction of He~*(2~3S)/CO_2 with CS_2 has been studied in discharge fiowing-afterglow apparatus. The emission spectra from exited state products CS~+_2(A)、CS (A,a) have been observed. The formation mechbosm proposed is:
CO~+_2(X)+CS_2→CS~+_2(A)+CO_2
CO(a)+CS_2→OCS(X)+CS(A)
CO(a)+CS_2→OCS(X)+CS(a)

Key words: Energy transfer, Chemiluminescence, CS2, Charge-transfer reaction