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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 1994,Vol.10>> Issue(03)>> 247-253     doi: 10.3866/PKU.WHXB19940311         中文摘要
The States of Zinc in ZnZSM-5 Zeolites and their Catalysis
She Li-Qin, Wang Duo-Cai, Li Xuan-Wen, Liu Xing-Yun, Han Ming
Department of Chemistry, Peking University, Beijing 100871; Department of Chemistry, Sichuan Normal College, Nanchong 637002
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NH_3-TPD and pyridine adsorption IR spectroscopy techniques have been used to study the zinc states in ZnHZSM-5 zeolite containing various zine content. The results indicate that, in addition to two desorption peaks for HZSM-5 zeolite located at about 533 and 733 K, two new peaks located at about 573 and 873 K were observed. These new peaks are believed to be associated with two kinds of zinc sites designated by L_1, L_2. The adsorbed ammonia amount of L_2 corresponds to the amount of L_(1616) acid characterized by pyridine adsorption IR spectra for ZnHZSM-5 zeolite with various zinc contents. It is possible that there are two kinds of zinc states in ZnHZSM-5 zeolite. One kind of them is ZnO species with weak acidity, the other is ZnOH~+ species with strong acidity which can promote the activity and has an effect on stability of activity for aromatization of propane.



Keywords: ZnZSM-5   Propane   Aromatization   NH3-TPD   Pyridine adsorption IR spectra   Zeolite  
Received: 1992-07-30 Accepted: 1993-02-16 Publication Date (Web): 1994-03-15
Corresponding Authors: She Li-Qin Email:


Cite this article: She Li-Qin, Wang Duo-Cai, Li Xuan-Wen, Liu Xing-Yun, Han Ming. The States of Zinc in ZnZSM-5 Zeolites and their Catalysis[J]. Acta Phys. -Chim. Sin., 1994,10 (03): 247-253.    doi: 10.3866/PKU.WHXB19940311
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