ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2004,Vol.20>> Issue(11)>> 1292-1296     doi: 10.3866/PKU.WHXB20041102         中文摘要
Preparation and Characterization of TiO2--CdS-MCM-41 Nano-composite
Chen Feng; Zhu Yi-Ping; Ma Hong-Liao; Bo Zi-Long; Zhang Jin-Long
Institute of Fine Chemicals, East China University of Science and Technology; Institute of Petroleum Processing, East China University of Science and Technology, Shanghai 200237
Full text: PDF (1897KB) Export: BibTeX | EndNote (RIS)
γ-thiopropyl tri-methyl silicane and surface pre-adsorption hydrolysis technique were used to accommodate CdS and TiO2 nanoparticles into the tunnels of MCM-41 meso-porous sieves. UV-Vis spectra showed that MCM-41 extracted CdS nanoparticles effectively from the reverse micelles by the chelation of thiol-groups. The changes of meso-tunnel diameter of MCM-41 were also observed with the introducing of nanoparticles in the low angle XRD patterns.

Keywords: CdS    TiO2    MCM-41    Nano-composite  
Received: 2004-03-25 Accepted: 2004-05-28 Publication Date (Web): 2004-01-15
Corresponding Authors: Zhang Jin-Long Email:

Cite this article: Chen Feng; Zhu Yi-Ping; Ma Hong-Liao; Bo Zi-Long; Zhang Jin-Long. Preparation and Characterization of TiO2--CdS-MCM-41 Nano-composite[J]. Acta Phys. -Chim. Sin., 2004,20 (11): 1292-1296.    doi: 10.3866/PKU.WHXB20041102
1. WANG Li-Juan, LI Qi, HAO Yan-Zhong, SHEN Shi-Gang, XU Dong-Sheng.Improvement of Quantum Dot Coverage of CdS/CdSe/TiO2 Hierarchical Hollow Sphere Photoanodes[J]. Acta Phys. -Chim. Sin., 2016,32(4): 983-989
2. LI Hui, LIU Xiang-Xin, ZHANG Yu-Feng, DU Zhong-Ming, YANG Biao, HAN Jun-Feng, BESLAND Marie-Paule.Synthesis of CdS with Large Band Gap Values by a Simple Route at Room Temperature[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1338-1344
3. BAI Shou-Li, LU Wen-Hu, LI Dian-Qing, LI Xiao-Ning, FANG Yan-Yan, LIN Yuan.Synthesis of Mesoporous TiO2 Microspheres and Their Use as Scattering Layers in Quantum Dot Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1107-1112
4. NI Ting, ZOU Fan, JIANG Yu-Rong, YANG Sheng-Yi.To Improve the Efficiency of Bulk Heterojunction Organic Solar Cells by Incorporating CdSe/ZnS Quantum Dots[J]. Acta Phys. -Chim. Sin., 2014,30(3): 453-459
5. LI Wen-Zhe, WANG Li-Duo, GAO Rui, DONG Hao-Peng, NIU Guang-Da, GUO Xu-Dong, QIU Yong.Transforming Organic Ligands into a ZnS Protective Layer through the S2- Intermediate State in ex situ CdSe Quantum Dot Devices[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2345-2353
6. LIN Pei-Bin, YANG Yu, CHEN Wei, GAO Han-Yang, CHEN Xiao-Ping, YUAN Jian, SHANGGUAN Wen-Feng.Hydrothermal Synthesis and Activity of NiS-PdS/CdS Catalysts for Photocatalytic Hydrogen Evolution under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1313-1318
7. GUO Xu-Dong, Ma Bei-Bei, WANG Li-Duo, GAO Rui, DONG Hao-Peng, QIU Yong.Electron Injection and Photovoltaic Properties in CdSe/ZnS Quantum Dot Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1240-1246
8. SUN Bao, HAO Yan-Zhong, GUO Fen, LI Ying-Pin, LUO Chong, PEI Juan, SHEN Shi-Gang.Photoelectrochemical Properties of CdS/ZnO Shell-Core Nanorod Arrays Modified with P3HT[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2861-2866
9. PENG Jing, FANG Xiao-Ming, CHEN Zhi-Hong, ZHANG Zheng-Guo.Effects of CdSe Layer Number on the Optical Properties and Microstructures of CdTe/CdSe (II) Core/Shell Quantum Dots[J]. Acta Phys. -Chim. Sin., 2012,28(01): 232-238
10. SHI Cheng-Wu, CHEN Zhu, SHI Gao-Yang, SUN Ren-Jie.Preparation of Large Grain and Dense CdS Thin Films Using Ultrasonic Agitation Chemical Bath Deposition[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2821-2825
11. MIN Shi-Xiong, Lü Gong-Xuan.Preparation of CdS/Graphene Composites and Photocatalytic Hydrogen Generation from Water under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2178-2184
12. LIU Bai-Jun, MENG Qing-Lei, WANG Hui, MENG Qing-Min.Synthesis and Characterization of Al MCM-41 Mesoporous Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3257-3262
13. ZHANG Qiao-Bao, FENG Zeng-Fang, HAN Nan-Nan, LIN Ling-Ling, ZHOU Jian-Zhang, LIN Zhong-Hua.Preparation and Photoeletrochemical Performance of CdS Quantum Dot Sensitized ZnO Nanorod Array Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2927-2934
14. FU Dong-Wei, CHENG Ke, PANG Shan, DU Zu-Liang.Solution Based Synthesis of ZnO/CdS Composite Nanorod Array Film and Its Photoelectric Properties[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2575-2580
15. ZHAO Hui-Ling, SHEN Huai-Bin, WANG Hong-Zhe, LI Lin-Song.Phosphine-Free Synthesis of High Quality CdSe Nanocrystals and Their Optical Properties[J]. Acta Phys. -Chim. Sin., 2010,26(03): 691-694
16. WANG Xiao-Po, XU Hong-Tao, TAO Lei-Ming, WU Yan-Qiang, AN Yan-Qing, DU Zu-Liang, WU Si-Xin.Syntheses of Cadmium Sulfide Nanorods and Network Nanowires by Bovine Serum Albumin[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1769-1774
17. ZHAO Feng-Ming; SHEN Hai-Ping; CHEN Zhao-Yang; MA Chun-An.Electrocatalytic Reduction of Maleic Acid at Bundles of TiO2 Anodization Film[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2139-2142
18. HUANG Li-Hua; YANG Li-Li; XU Bo-Lian; FAN Yi-Ning.Catalytic Properties of PtSn/Al2O3/MCM-41 Catalysts for Propane Dehydrogenation[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1297-1301
19. TANG Yu-Xin; TAO Jie; TAO Hai-Jun; WU Tao; WANG Ling; ZHANG Yan-Yan; LI Zhuan-Li; TIAN Xi-Lin.Fabrication and Characterization for Transparent Electrodes of TiO2 Nanotube Arrays on Fluorine-Doped Tin Oxide-Coated Glass[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1120-1126
20. CHEN Qiao-Lin; ZHOU Jian-Zhang; LIANG Jin-Ling; LIN Ling-Ling; LIN Zhong-Hua.Spectroscopic and Photoelectrochemical Properties of DNA/CdS Nanoparticle Composites[J]. Acta Phys. -Chim. Sin., 2008,24(05): 749-754
21. LIU Shou-Xin; CHEN Xiao-Yun.Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO2/AC Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(03): 533-538
22. LIN Tao; LI Wei; GONG Mao-Chu; YU Yao; DU Bo; CHEN Yao-Qiang.Prepareration of ZrO2-TiO2-CeO2 and Its Application in the Selective Catalytic Reduction of NO with NH3[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1851-1856
23. ZHANG Tian-Yong; FAN Qiao-Fang; ZENG Miao; WANG Zheng; XIA Wen-Juan; CHI Li-Feng.Photocatalytic Degradation of Light Fast Scarlet BBN and Surfactant Bicomponents[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1803-1807
24. ZHANG Wei; WANG Shu-Liang; MA Yun-Qing; WANG Cui-Ping; LIU Xing-Jun.Influence of Interface Diffusion between Al Substrate and TiO2 Filmon Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1347-1352
25. WU Liang-Zhuan; ZHI Jin-Fang.One-step Synthesis of Anatase-Crystalline Titania Hollow Spheres in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1173-1177
26. ZHAO Meng; WANG Jin-Xing; FENG Cai-Hui; ZOU Bo; CHEN Cheng; WANG Zhu-Yi; WU Feng-Qing; ZOU Le-Hui.Preparation and Gas Sensing Properties to Formaldehyde of TiO2/Ag2O Nanocrystalline[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1003-1006
27. WU Lun-Peng; ZHAO Lian-Hua; ZHANG Hai-Ming; ZHAO Qing-Nan.Effects of the Adsorption of Oxygen on the Photocatalytic Activity of TiO2 Films Using PhotocurrentMethod[J]. Acta Phys. -Chim. Sin., 2007,23(05): 765-768
28. WANG Shi-ming; LIU Ping; FU Xian-zhi.Preparation and Optical Properties of Nanocrystalline Cadmium Sulfide in Perfluorinated Ionomer Membrane[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1151-1155
29. CHEN Shu-Tang; XU Ji-Chuan; WANG Yu-Ping; LI Hu-Lin.Synthesis of CdSe Nanocrystals by the Pyrolysis Methods[J]. Acta Phys. -Chim. Sin., 2005,21(02): 113-116
30. Yin Hao-Yong; Xu Zhu-De; Zheng Yi-Fan; Wang Qing-Sheng; Chen Wei-Xiang.In situ Growth of CdSe Quantum Dots on MWCNTs with Thioglycollic Acid as the Stabilizer[J]. Acta Phys. -Chim. Sin., 2004,20(11): 1308-1312
31. Liu Ze-Hua;Lai Ren-Fu;Guo Hai-Qing.Assembly of Fluorescent and Reactive Organic Ammoniums with CdSe Nanocrystals[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1067-1070
32. Nie Qiu-Lin;Yuan Qiu-Li;Xu Zhu-De;Chen Wei-Xiang.Study on the Morphology Control of CdS Nanocrystals Synthesized by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1138-1142
33. Wang Bin;Gao Fei;He Bin;Zhang Dong-Bai;Cheng Hu-Min;Ma Ji-Ming;Qi Li-Min.Optic Property of CdS/TiO2 Composite Nanoparticle Prepared in the Reversed Microemulsion[J]. Acta Phys. -Chim. Sin., 2003,19(01): 21-24
34. Song Hui-Hua;Fang Zhen;Guo Hai-Qing.Synthesis and Characterization of CdSe/Poly (4-vinylpyridine) Quaternary Ammonium Nanocomposite[J]. Acta Phys. -Chim. Sin., 2003,19(01): 9-12
35. Kuang Han-Mao;Deng Zhao-Xiang;Li Chun-Hui;Sun Xiao-Ming;Zhuang Jing;Li Ya-Dong.Synthesis and Photoluminescent Properties of CdS/SiO2 Nanorod[J]. Acta Phys. -Chim. Sin., 2002,18(05): 477-480
36. Xiao Xu-Rui;Zhang Jing-Bo;Lin Yuan;Yin Feng;Li Xue-Ping.Study of the Kinetics of Nanocrystalline Semiconductor Thin Film Electrode Processes by Intensity Modulated Photocurrent Spectroscopy[J]. Acta Phys. -Chim. Sin., 2001,17(10): 918-923
37. Zhang Yu, Fu De-Gang, Cai Jian-Dong, Zhu Chun-Xia, Liu Ju-Zheng, Lu Zu-Hong.Surface-modification of CdS Nanoparticle and its Optical Properties[J]. Acta Phys. -Chim. Sin., 2000,16(05): 431-436
38. Xu Bin, Cheng Hu-Min, Wang Yan-Qin, Ma Ji-Ming.Preparation and Properties of Nanosized Composite Particle SnO2/CdS[J]. Acta Phys. -Chim. Sin., 1999,15(10): 925-929
39. Xu Ya-Jie, Xu Dong-Sheng, Chen Da-Peng, Guo Guo-Lin, Li, C. J..Electrochemistry Preparation and Characterization of CdS Nanowire Arrays[J]. Acta Phys. -Chim. Sin., 1999,15(07): 577-580
40. Li Yan, Wan Jing-Hua, Gu Zhen-Nan.Templated Synthesis of CdS Nanowires in Hexagonal Liquid Crystal Systems[J]. Acta Phys. -Chim. Sin., 1999,15(01): 1-4
41. Yu Gang,Wang Kai-Xuan,Huang Jian-Bin,Zhao Bi-Ying.Low Frequency Raman Scattering of CdS Nanocrystallites Embedded in Silicate Glasses[J]. Acta Phys. -Chim. Sin., 1997,13(03): 230-235
42. Wang Su-Hua,Chen De-Wen.The Study on the Photochemical Degradation of ρ-Substituted Sdium Phenylsulphonate[J]. Acta Phys. -Chim. Sin., 1996,12(04): 315-319
43. Wang Bao-Hui,Wang De-Jun,Cao Yun-Wei,Zhang Jie,Li Tie-Jin.Investigation of Photo-induced Interfacial Charge Transfer of CuPc-modified Q-CdS Ultrafine Particle Films[J]. Acta Phys. -Chim. Sin., 1996,12(02): 177-180
44. ZHOU Li, LIU Huan-Huan, YANG Yu-Lin, QIANG Liang-Sheng.SILAR Prepared TiO2/CdS/Co-Pi Water Oxidation Photoanode and Its Performance[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top