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Acta Phys. -Chim. Sin.  2005, Vol. 21 Issue (11): 1211-1216    DOI: 10.3866/PKU.WHXB20051104
Article     
A Model of Stoichiometric Displacement for the Adsorption of Benzoic Acid and Benzene by Silica Gel from Cyclohexane Solution
CHEN Yu-yin; LIU Fan; LIU Yong-chun
Department of Environment and Life Science, Leshan Teachers College, Leshan, Sichuan 614004
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Abstract  Adsorption of benzoic acid and benzene from cyclohexane solution by silica gel was studied under 293~313 K. It was indicated that adsorption of benzoic acid by silica gel well fit the stoichiometric displacement mode for adsorption (SDM-A). But for benzene, when treated with SDM-A there was a turning point in its adsorption isotherm, which corresponding to the dividing point between monomolecular and multimolecular layer adsorption. Thermodynamics formulae of adsorption were also set up based on SDM-A. It was demonstrated that benzoic acid was spontaneously adsorbed by silica gel accompanied with an entropy increase process, but for benzene it was accompanied with an entropy decrease process. The free energy change for adsorption of benzoic acid was larger than that of benzene and the adsorption enthalpy change was reversed because of the stronger affinity to silica gel and the stronger solvophobic ability for benzoic acid than that for benzene.

Key wordsSilica gel      Adsorption      Benzoic acid      Benzene      Cyclohexane solution      SDM-A      Adsorption thermodynamics     
Received: 04 March 2005      Published: 15 November 2005
Corresponding Authors: CHEN Yu-yin     E-mail: chy514cn@yahoo.com.cn
Cite this article:

CHEN Yu-yin; LIU Fan; LIU Yong-chun. A Model of Stoichiometric Displacement for the Adsorption of Benzoic Acid and Benzene by Silica Gel from Cyclohexane Solution. Acta Phys. -Chim. Sin., 2005, 21(11): 1211-1216.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB20051104     OR     http://www.whxb.pku.edu.cn/Y2005/V21/I11/1211

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