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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2004,Vol.20>> Issue(09)>> 1163-1166     doi: 10.3866/PKU.WHXB20040921         中文摘要
In-situ SERS of Dissociative Adsorption and Oxidation of Ethanol on Roughed Platinum Electrodes
Zhong Qi-Ling;Zhang Bin;Zhang Lei;Yang Xiong-Yuan;Huang Peng
College of Chemistry, Jiangxi Normal University, Nanchang 330027
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The behaviors of adsorption and oxidation of ethanol on a roughened platinum electrode with high SERS activity were studied by using cyclic voltammetry and in-situ surface enhanced Raman spectroscopy, surface Raman spectra of dissociative adsorption of ethanol on Pt electrode in acid medium have been obtained. The results show that ethanol can be dissociated on the Pt surface in acid medium to produce poisoning intermediate CO, which suppresses the further oxidation of ethanol, and some informations of Pt-C and Pt-C-Pt stretching vibration from linearly-adsorbed and bridged-adsorbed CO located in low frequency were obtained, respectively. The investigation also shows that the electro-oxidtion of ethanol on the roughened platinum was a diffuse-controlled reaction in sulfuric acid. By correlating the in-situ SERS data with the electrochemical data,it was found that the oxidation of ethanol proceeded via the parallel mechanism.

Keywords: Ethanol   Platinum electrode   Dissociative adsorption   Electronic oxidation   In-situ SERS  
Received: 2004-02-26 Accepted: 2004-05-10 Publication Date (Web): 2004-09-15
Corresponding Authors: Zhong Qi-Ling Email: zhqiling@163.com


Cite this article: Zhong Qi-Ling;Zhang Bin;Zhang Lei;Yang Xiong-Yuan;Huang Peng. In-situ SERS of Dissociative Adsorption and Oxidation of Ethanol on Roughed Platinum Electrodes[J]. Acta Phys. -Chim. Sin., 2004,20 (09): 1163-1166.    doi: 10.3866/PKU.WHXB20040921
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101. Li Hong, Jiang Lin-Cai, Jiang Xiong.Underpotential Deposition of Antimony(III) at a Platinum[J]. Acta Phys. -Chim. Sin., 1994,10(11): 1049-1054
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