ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2004,Vol.20>> Issue(09)>> 1163-1166     doi: 10.3866/PKU.WHXB20040921         中文摘要
In-situ SERS of Dissociative Adsorption and Oxidation of Ethanol on Roughed Platinum Electrodes
Zhong Qi-Ling;Zhang Bin;Zhang Lei;Yang Xiong-Yuan;Huang Peng
College of Chemistry, Jiangxi Normal University, Nanchang 330027
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The behaviors of adsorption and oxidation of ethanol on a roughened platinum electrode with high SERS activity were studied by using cyclic voltammetry and in-situ surface enhanced Raman spectroscopy, surface Raman spectra of dissociative adsorption of ethanol on Pt electrode in acid medium have been obtained. The results show that ethanol can be dissociated on the Pt surface in acid medium to produce poisoning intermediate CO, which suppresses the further oxidation of ethanol, and some informations of Pt-C and Pt-C-Pt stretching vibration from linearly-adsorbed and bridged-adsorbed CO located in low frequency were obtained, respectively. The investigation also shows that the electro-oxidtion of ethanol on the roughened platinum was a diffuse-controlled reaction in sulfuric acid. By correlating the in-situ SERS data with the electrochemical data,it was found that the oxidation of ethanol proceeded via the parallel mechanism.

Keywords: Ethanol   Platinum electrode   Dissociative adsorption   Electronic oxidation   In-situ SERS  
Received: 2004-02-26 Accepted: 2004-05-10 Publication Date (Web): 2004-09-15
Corresponding Authors: Zhong Qi-Ling Email:

Cite this article: Zhong Qi-Ling;Zhang Bin;Zhang Lei;Yang Xiong-Yuan;Huang Peng. In-situ SERS of Dissociative Adsorption and Oxidation of Ethanol on Roughed Platinum Electrodes[J]. Acta Phys. -Chim. Sin., 2004,20 (09): 1163-1166.    doi: 10.3866/PKU.WHXB20040921
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98. Kang Qing-Hua,Zhong Shun-He.Mechanism of Laser Stimulated Surface Reaction of Ethanol Oxidative Coupling to 1,4-Butanediol[J]. Acta Phys. -Chim. Sin., 1995,11(06): 498-503
99. Zhao Bing, YUAN Chun-Bei, Zhao Da-Qing, Ni Jia-Zuang.Study of FT-Raman Spectroscopy on the Effects of Lanthanide Ions and Their Complexes on the Fluidity of Dipalmitoylphosphatidylethanolamine Bilayer[J]. Acta Phys. -Chim. Sin., 1995,11(05): 429-432
100. Sun Shi-Gang, Lu Guo-Qiang.Kinetics and Time Resolved FTIR Spectroscopic Characters of Dissociative Adsorption of HCOOH on Pt Electrode[J]. Acta Phys. -Chim. Sin., 1995,11(01): 56-60
101. Li Hong, Jiang Lin-Cai, Jiang Xiong.Underpotential Deposition of Antimony(III) at a Platinum[J]. Acta Phys. -Chim. Sin., 1994,10(11): 1049-1054
102. Wang Ze-Xin, Zhang Ji-Shu, Yu Xiao-An, Hao Ce, Chen Zong-Qi.Effect of the Ni(510) Step Surface for the Dissociative Adsorption of Hydrogen Molecule[J]. Acta Phys. -Chim. Sin., 1994,10(10): 915-920
103. Shan Jin-Huan, Liu Tie-Ying.Kinetics and Meckanism of Oxidation of Ethanolamine by Diperiodatocuprate(III)Ion in Alkaline Medium[J]. Acta Phys. -Chim. Sin., 1994,10(10): 947-949
104. Tao Zu-Yi; Dou Hui-Yuan; Wang Chang-Shou.Intrinsic Protonation Constants of Chelating ion Exchange Resin[J]. Acta Phys. -Chim. Sin., 1993,9(04): 516-522
105. Gao Ying; Wang Zhi-Pu.Study on the Kinetics and Mechanism of Oxidation of Ethanolamide with Potassium Ferrate (VI) by the Stopped-Flow Method[J]. Acta Phys. -Chim. Sin., 1993,9(01): 70-76
106. Sun Shi-Gang; Wang Jin-Jian; Mu Ji-Qian.A Dynamic Investigation of the Dissociative Adsorption of Hcooh on Pt(100) Single Crystal Electrode[J]. Acta Phys. -Chim. Sin., 1992,8(06): 732-735
107. Zhou Zhi-Hua; Hu Wei-Dong; Lu Wen-Qing; Zhou Yi-Ming; Xue Kuan-Hong.Effect of Supporting Electrolyte on the Electrochemical Oxidation Pathways of Anhydrous Methanol at Gold Electrode[J]. Acta Phys. -Chim. Sin., 1992,8(05): 707-711
108. Sun Shi-Gang; Yang Dong-Fang; Tian Zhao-Wu.IN-SITU FTIR Studies on Adsorption and Oxidation of 1,2-Propanediol at a Platinum Electrode in Acid Solutions[J]. Acta Phys. -Chim. Sin., 1992,8(01): 59-63
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110. Wu Ji-Lan; Su Ya-Li; Qi Sheng-Chu; Wang Wen-Qing; Zhang Xu-Jia.Investigation of the Mechanism of Gamma Radiolysis of Ethanol[J]. Acta Phys. -Chim. Sin., 1991,7(01): 22-29
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