Acta Phys. -Chim. Sin. ›› 2004, Vol. 20 ›› Issue (03): 309-312.doi: 10.3866/PKU.WHXB20040319

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Selective Oxidation of Propane over Mo-V-Zr-O Catalysts

Yi Xiao-Dong;Lin Hong;He Yi-Ming;Huang Chuan-Jing;Weng Wei-Zheng;Wan Hui-Lin   

  1. Department of Chemistry, State Key Laboratory for Physical Chemistry of Solid Surfaces, Institute of Physical Chemistry, Xiamen University, Xiamen 361005
  • Received:2003-08-29 Revised:2003-10-15 Published:2004-03-15
  • Contact: Wan Hui-Lin E-mail:hlwan@xmu.edu.cn

Abstract: A detailed study on the promotion effect of Zr on Mo-V mixed oxide catalysts in the selective oxidation of propane to acrolein was performed. The catalysts were characterized by BET, XRD, H2-TPR, NH3-TPD and isopropanol decomposition reaction. The addition of Zr modifies the catalysts phase composition and improves their redox and acid-base properties. As a result, the higher catalytic activity and selectivity were obtained over Mo2VZr0.5Ox catalyst.

Key words: Propane, Selective oxidation, Acrolein, Mo-V-O based catalyst