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Acta Physico-Chimica Sinica  2008, Vol. 24 Issue (03): 465-470    DOI: 10.3866/PKU.WHXB20080320
Article     
Influence of Interphase Distribution of Reactants on Preparation of Nano-CuO by Adsorption Phase Technique
LI Yuan-Pu; JIANG Xin
College of Materials and Chemical Engineering, Zhejiang University, Hangzhou 310027, P. R. China
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Abstract  CuO nanoparticles were synthesized in a nanoreactor formed by adsorption layer on silica surface. Adsorption capacity measuration experiment with different water concentrations, solvent substitution experiment and reaction-before-adsorption experiment showed that the water adsorption layer existed on the SiO2 surface and served as a place reaction mainly occurring. The three-region distribution model of Cu2+ in this system was proposed according to the adsorption data. The increase of water concentration and NaOH concentration in system will both made more Cu2+ migrate to the adsorption layer region. XRD analysis indicated that the rise of temperature and the increase of NaOH concentration were both in favor of the smaller CuO grain formation. The growth of CuO grain was restricted by the adsorption layer, which became thinner with temperature rising. And the nucleation rate accelerated as the supersaturation degree in adsorption layer increased with the NaOH concentration rising.

Key wordsAdsorption layer      Nanoreactor      Adsorption phase reaction technique      CuO nanoparticles     
Received: 23 October 2007      Published: 23 January 2008
MSC2000:  O647  
  TQ03  
Corresponding Authors: JIANG Xin     E-mail: jiangx@zju.edu.cn
Cite this article:

LI Yuan-Pu; JIANG Xin. Influence of Interphase Distribution of Reactants on Preparation of Nano-CuO by Adsorption Phase Technique. Acta Physico-Chimica Sinica, 2008, 24(03): 465-470.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20080320     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2008/V24/I03/465

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