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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2008,Vol.24>> Issue(03)>> 513-519     doi: 10.3866/PKU.WHXB20080329         中文摘要
Synthesis of LiNi1/3Co1/3Mn1/3O2 Cathode Material by Eutectic Molten Salt LiOH-LiNO3
CHANG Zhao-Rong; CHEN Zhong-Jun; WU Feng; TANG Hong-Wei; ZHU Zhi-Hong
College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, Henan Province, P. R. China; College of Chemical Engineering and Environmental, Beijing Institute of Technology, Beijing 100080, P. R. China
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The powder of LiNi1/3Co1/3Mn1/3O2 were prepared directly without artificial grinding and washing by a eutectic molten-salt mixture (0.38LiOH·H2O-0.62LiNO3) method. According to this method, the eutectic molten-salt mixture was self-mixed with precursor thoroughly at low temperature, and then sintered at a certain temperature. The tap-density of the powder obtained was 2.87 g·cm-3. The well-layered 琢-NaFeO2 structure and regular morphology were confirmed by X-ray diffraction (XRD) and scanning electronmicroscopy (SEM).XPSstudies showed that the predominant oxidation states of Ni, Co, andMn in the compound were 2+, 3+, and 4+, respectively. Cathodic behaviour was examined by charge-discharge cycling. The synthesized powder showed a reversible capacity of 160 mAh·g -1 at a specific current of 0.2C in the rang 3.0-4.3 V up to 50 cycles without noticeable capacity-fading.

Keywords: Eutectic molten salt   Cathode material   XPS   LiNi1/3Co1/3Mn1/3O2  
Received: 2007-09-07 Accepted: 2007-12-18 Publication Date (Web): 2008-01-21
Corresponding Authors: WU Feng Email: wufeng863@vip.sina.com


Cite this article: CHANG Zhao-Rong; CHEN Zhong-Jun; WU Feng; TANG Hong-Wei; ZHU Zhi-Hong. Synthesis of LiNi1/3Co1/3Mn1/3O2 Cathode Material by Eutectic Molten Salt LiOH-LiNO3[J]. Acta Phys. -Chim. Sin., 2008,24 (03): 513-519.    doi: 10.3866/PKU.WHXB20080329
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88. Gong Hai-Ning;Shen Hua;Huang Hui-Zhong;Wu Nian-Zu.Preliminary Exploration of Touggard′s Method Used for the Background[J]. Acta Phys. -Chim. Sin., 2002,18(04): 326-331
89. Xi Jing-Yu;Wang Zhi-Fei;Wang Wei-Ping;Lü Gong-Xuan.In-situ XPS Study for Reaction Mechanism of Methanol Decomposition over Cu-Ni/Zn Catalyst[J]. Acta Phys. -Chim. Sin., 2002,18(01): 82-86
90. Zhao Liang-Zhong;Liu Fen;Li Jian-Zhang;Xu Yong-Tong.XPS Study of Three Dimensional C/SiC Composites[J]. Acta Phys. -Chim. Sin., 2001,17(09): 802-805
91. Liu Jin-Cui;Mu Shao-Lin;Li Yong-Fang.Growth of Poly(methylene blue) Film and Properties of the Film[J]. Acta Phys. -Chim. Sin., 2001,17(03): 229-233
92. Xia Sheng-Qing;Chen Sheng-Pei;Sun Shi-Gang.The Preparation and Characterization of Platinum Based PbSb Surface Alloy Electrode[J]. Acta Phys. -Chim. Sin., 2001,17(02): 134-139
93. Ren Si-Li;Yang Sheng-Rong;Xue Qun-Ji.Perfluorodecanoic Acid Ultrathin Film on Single Crystal Silicon Substrate Coated with Polyethyleneimine[J]. Acta Phys. -Chim. Sin., 2001,17(02): 97-100
94. Zhang Yu-Zhi;Kuai Su-Lan;Huang Yin-Song;Wang Zhong-Chun;Hu Xing-Fang.X-ray Photoelectron Spectroscopic Study on Electrochromic Molybdenum Oxide Films[J]. Acta Phys. -Chim. Sin., 2001,17(01): 79-82
95. Deng Zong-Wu, Guo Wei-Min, Liu Huan-Ming, Cao Li-Li.Band Bending of Cleaved GaAs(100) Surface[J]. Acta Phys. -Chim. Sin., 1999,15(06): 528-532
96. Zhao Liang-Zhong, Wang Rui-Lan, Xu Hong-Yu, Li Hong-Cheng, Liu Shi-Hong.XPS Studies of Superconducting Gd-Ba-Cu-O Films[J]. Acta Phys. -Chim. Sin., 1999,15(05): 398-402
97. Deng Zong-Wu, Guo Wei-Min, Liu Huan-Ming, Cao Li-Li.Band Bending of Cleaved InP(110) Surface[J]. Acta Phys. -Chim. Sin., 1999,15(04): 303-307
98. Yang Ru, Hu Tian-Dou, Liu Tao, Xiang Hong-Wei, Zhong Bing, Xu Yao, Wu Dong.Characterization of CuO-BaO/SiO2 Catalysts Structure[J]. Acta Phys. -Chim. Sin., 1998,14(07): 590-596
99. Ouyang Jian-Ming, Tai Zi-Hou, Tang Wen-Xia.XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal Ions[J]. Acta Phys. -Chim. Sin., 1998,14(01): 84-87
100. Xiao Zhong-Dang, Huang Dan, Gu Jian-Hua, Lu Zu-Hong.X-ray Photoelectron Spectroscopy Study of the Deposition of TiO2 Thin Films on Self-assembly Monolayer[J]. Acta Phys. -Chim. Sin., 1998,14(01): 57-62
101. Zhang Guo-Qing,Liu Bing,Yao Su-Wei,Guo He-Tong,He Fei,Gong Zheng-Lie.XPS Evidence for the Diffusion and Formation of Metal Silicide at Atmospheric Temperature on the Interface of NiPd/Si[J]. Acta Phys. -Chim. Sin., 1997,13(02): 164-168
102. Li Xing-Lin,She Yi-Min,Guo Jun,Jiang Da-Zhen.XPS Study of the Interaction between Layers and Pillars of Layered Double Hydroxides Pillared with Heteroplyanion(II)[J]. Acta Phys. -Chim. Sin., 1996,12(10): 929-932
103. Wu Zheng-Hua,Qiu Si-Chou,Huang Han-Yao,He Hua-Hui.Study on the Characteristics and Mechanism of Electrochromism of NiOxHy Thin Film[J]. Acta Phys. -Chim. Sin., 1996,12(07): 615-620
104. Zhang Han-Chang,Zuo Xiao-Bing,Ji Ming-Rong,Wu Shou-Guo.Properties of Anodically Oxidative Glass Carbon Electrodes(GCE) in Strong Alkaline solutions[J]. Acta Phys. -Chim. Sin., 1996,12(07): 649-653
105. Luo Sheng-Cheng,Gui Lin-Lin,Tang You-Qi.The Characterisation of the Adsorption of H2S on MoO3/TiO2-Al2O3 by XPS[J]. Acta Phys. -Chim. Sin., 1996,12(04): 341-345
106. Fu Xian-Zhi,Huang Hui-Zhong,Zhu Lin,Luo Sheng-Cheng,Gui Lin-Lin.Investigation of Sulfidation Processes for Hydrotreating Catalysts by[J]. Acta Phys. -Chim. Sin., 1995,11(12): 1071-1076
107. Yang Xiang-Guang,Liu She-Tian,Ye Xing-Kai,Wu Yue,Sheng Shi-Shan,Xiong Guo-Xing.X-Ray Photoelectron Spectroscopy Study of LaMn1-xFexO3(x=0-1) Oxides[J]. Acta Phys. -Chim. Sin., 1995,11(08): 681-687
108. Xiong Guo-Xing, Xia Xin-Rui, Chen Heng-Rong, Guo Xie-Xian.Synergetic Effect between NaCl and B2O3 in Modified FeOχ Catalysts[J]. Acta Phys. -Chim. Sin., 1994,10(11): 971-977
109. Chen Xue-An, Chen De-Jun, Xu Cui-Ying, Zhang Jin-Biao, Zhu Dao-Ben, Yang De-Liang.The Effect of Cu2S Addition on the Superconductivity of Bi-Pb-Sr-Ca-Cu-O System[J]. Acta Phys. -Chim. Sin., 1994,10(08): 704-709
110. Zhang Rui-Feng, Li Xing-Lin, Liu She-Tian, Yu Zuo-Long, Wu Yue.XPS Study of the Oxygen State in LaMnyCo1-yO3 Catalysts[J]. Acta Phys. -Chim. Sin., 1994,10(08): 720-723
111. Zhai Run-Sheng, Cai Mao-Sheng, D.M.Kolb.XPS Evidence of Sulfate Anion Adsorption on Emersed Pt(111) in H2SO4 Solution[J]. Acta Phys. -Chim. Sin., 1994,10(08): 741-743
112. Yan Jian-Hua; Liu Ying-Jun; Gui Lin-Lin; Tang You-Qi.The Surface Structure of WO3/Titania-alumina System[J]. Acta Phys. -Chim. Sin., 1993,9(01): 13-20
113. Wu Hui-Huang; Wu Bao-Zhang; Zhou Shao-Min.Electrochemistry and XPS of Palladium Oxides[J]. Acta Phys. -Chim. Sin., 1992,8(04): 519-522
114. Zhao Liang-Zhong; Guo Zhong-Cheng; Liang Zhen-Hua; Hu Yu-Xiu; Liu Han-Fan.Variations in the Elemental Concentration in Surface Region of the YBCO Films and Interactions of the Films with Substrate in Heating Process Studied by Angular Deprndent XPS[J]. Acta Phys. -Chim. Sin., 1991,7(03): 305-310
115. Zhu Wen-Xiang; Zhao Ji-Zhou; Yang Rui-Na; Huang Hui-Zhong.Investigation on XPS of Lanthanide Complexes of Crown Ethers[J]. Acta Phys. -Chim. Sin., 1991,7(03): 371-374
116. Wang Dian-Xun; Li Er-Cheng; Xu Guang-Zhi; Zhang Lun.Studies of XPS Satellite Peaks and its Valence Band Spectra of the Pyridoygen Complexes of Rare Earth Decahydro-Decaborate[J]. Acta Phys. -Chim. Sin., 1991,7(02): 234-237
117. HUANG Wei, WU Chun-Yang, ZENG Yue-Wu, JIN Chuan-Hong, ZHANG Ze.Surface Analysis of Lithium-Rich Cathode Material Li1.2Mn0.54Co0.13Ni0.13NaxO2 by Advanced Electron Microscopy[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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