ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2008,Vol.24>> Issue(04)>> 581-586     doi: 10.3866/PKU.WHXB20080407         中文摘要
Au/γ-Al2O3 Catalyst Prepared from Octanethiolate Monolayer Protected Au Nanoparticles for CO Oxidation
WEN Li; LIN Zhong-Yu; ZHOU Jian-Zhang; GU Ping-Ying; FU Jin-Kun; LIN Zhong-Hua
State Key Laboratory of Physical Chemistry of Solid Surfaces; Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
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Octanethiolate self-assembled monolayer-protected gold nanoparticles (C8AuNPs) were synthesized using a two-phase protocol. Au/γ-Al2O3 catalysts for low-temperature oxidation of CO were prepared by depositing C8AuNPs in hexane colloidal solution on γ-Al2O3 using“step-by-step soakage”method and by carrying out vacuum dryness and thermal treatment. For the as-prepared C8AuNPs/γ-Al2O3 catalysts, the majority of the gold nanoparticles deposited on the support was in a narrow size range of 2-3 nm. Even after 600 h of reaction, the gold particles were still in the size range of 2-4 nm. The vacuum dryness temperature affected significantly on the particle size, which increased with raising the vacuum dryness temperature. It was found from the evaluation results of catalytic performances that the 2.5%(mass fraction, w) Au/γ-Al2O3 completely converted CO to CO2 at -19 ℃ and maintained the catalytic activity at nearly 100% CO conversion for at least 900 h at 15 ℃, and the 4.0% (w) Au/γ-Al2O3 maintained the catalytic activity at nearly 100% conversion of CO for at least 2000 h in the presence of the reaction gas containing H2O at 15 ℃. Evidently, the catalyst had higher activity, good long-termstability and strong anti-moisture performance. The effect of possible factors on the catalytic activity of Au/γ-Al2O3 was studied based on the above results.

Keywords: Au catalyst   CO oxidation   Au nanoparticles   Dryness temperature   Stablility   Anti-moisture  
Received: 2007-10-22 Accepted: 2007-12-28 Publication Date (Web): 2008-03-05
Corresponding Authors: LIN Zhong-Hua Email:

Cite this article: WEN Li; LIN Zhong-Yu; ZHOU Jian-Zhang; GU Ping-Ying; FU Jin-Kun; LIN Zhong-Hua. Au/γ-Al2O3 Catalyst Prepared from Octanethiolate Monolayer Protected Au Nanoparticles for CO Oxidation[J]. Acta Phys. -Chim. Sin., 2008,24 (04): 581-586.    doi: 10.3866/PKU.WHXB20080407
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90. WANG Xiao-Lei, PAN Xiang-Min, LIN Rui, KOU Su-Yuan, ZOU Wei-Bing, MA Jian-Xin.Dimethyl Ether Steam Reforming for Hydrogen Production over Cu-Ni/γ-Al2O3 Bi-Functional Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1296-1304
91. LIANG Jing, QIAN Yan, XIE Ling-Hai, SHI Nai-En, CHEN Shu-Fen, DENG Xian-Yu, HUANG Wei.Spectral Stability of Polyfluorene-Based Semiconductors[J]. Acta Phys. -Chim. Sin., 2010,26(04): 946-963
92. YU Chu-Hong, ZHANG Jia-Wei, DAI Jing, PENG Jing, LI Jiu-Qiang, ZHAI Mao-Lin.Radiation Stability and Analysis of Radiolysis Product of 1-Octanol[J]. Acta Phys. -Chim. Sin., 2010,26(04): 988-992
93. YANG Gui-Ling, WANG Chun, YANG Xiao-Min, ZHAO Na, JIAO Xiao-Yan.Synergistic Effect of a Nonmetal and a Metal on the Electrochemical Properties of a Mg-Based Hydrogen Storage Alloy[J]. Acta Phys. -Chim. Sin., 2010,26(04): 833-839
94. ZHANG Xiao-Guang, LIU Jie-Xiang, WANG Hai-Ying, WANG Man-Yi, FAN Zhi-Jin.Stability of Avermyctin Emulsion in Water[J]. Acta Phys. -Chim. Sin., 2010,26(03): 617-625
95. SUN Dun, HE Jian-Ping, ZHOU Jian-Hua, WANG Tao, DI Zhi-Yong, WANG Dao-Jun, DING Xiao-Chun.MClx(M=Pd, Fe, Cr) Assisted Synthesis of Ordered Mesoporous Carbon and Their Electrocatalytic Performance after Loading with Pt Nanoparticles[J]. Acta Phys. -Chim. Sin., 2010,26(02): 385-391
96. MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao, LU Guan-Zhong.Effect of Hydrothermal Treatment on the Acidity and Catalytic Performance of Nanosized HZSM-5 Zeolites for the Conversion of Methanol to Propene[J]. Acta Phys. -Chim. Sin., 2010,26(02): 338-344
97. CUI Xiao-Ying, JIA Jian-Feng, YANG Bin-Sheng, WU Hai-Shun.Stability Comparison between (BCO)12 and (CH)12 by Ring Strain Analysis[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2501-2506
98. SHAN Xin-Li, WANG Jian-Ping, LIU Yan, ZHANG Xing-Xiang.Fabrication and Characterization of Microencapsulated n-Octadecane with an Acrylic Co-polymeric Shell[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2590-2596
99. WANG Xiao-Wen, ZHOU Zheng-Fa, REN Feng-Mei, WANG Jin, MA Hai-Hong, XU Wei-Bing.Deblocking Kinetics of Water-Solubility Blocked Isophorone Diisocyanate[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2181-2185
100. LIU Rui-Hui, ZHANG Cun-Man, MA Jian-Xin.Al2O3-Modified Fe2O3 Based Gold Catalysts with Good Thermal Stability[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2261-2269
101. ZHAN Wei-Shen, PAN Shi, LI Yuan-Zuo, CHEN Mao-Du.A Comparison of Indoline Dyes as Photosensitizers in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2087-2092
102. LV Xue-Chuan, TAN Zhi-Cheng, GAO Xiao-Han.Synthesis and Thermochemical Properties of New Ternary Lanthanum Complex La(Glu)(Im)6(ClO4)3·4HClO4·4H2O[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1945-1950
103. LI Gui-An, ZHU Ting-Liang, YE Lu-Yuan, DENG Zhong-Xun, ZHANG Ya-Juan, JIAO Fei, ZHENG Hai-Rong.Hydrophobic Silica Aerogel Prepared In-situ by Ambient Pressure Drying and Its Thermal Stability[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1811-1815
104. HUANG Xiao-Xuan, XU Xuan.Ir-Hg Interactions and the Nature of Redox Reactions in Ir(CO)Cla(Ph2Ppy)2HgClb(HgCl2)c (a, b=1, 2|c=0, 1)[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1362-1366
105. LI Lei, ZHAN Ying-Ying, CHEN Chong-Qi, SHE Yu-Sheng, LIN Xing-Yi, ZHENG Qi.Effect of CeO2 Support Preparaed with Different Methods on the Activity and Stability of CuO/CeO2 Catalysts for the Water-Gas Shift Reaction[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1397-1404
106. HU Jie, YUAN An-Bao, WANG Yu-Qin, WANG Xiu-Ling.Improved Cyclability of Nano-MnO2/CNT Composite Supercapacitor Electrode Derived fromRoom-Temperature Solid Reaction[J]. Acta Phys. -Chim. Sin., 2009,25(05): 987-993
107. XIAO Xiao-Yan, LU Ji-Qing, SU Xiao-Wen, GUO Ming, LUO Meng-Fei.PdO-CeO2 Composite Catalysts for Low Temperature CO Oxidation[J]. Acta Phys. -Chim. Sin., 2009,25(03): 561-566
108. LUO Xiao-Yan; JIA Wen-Hong; ZHANG Cong-Jie.Structure and Electronic Properties of InnNa and InnNa+(n=2-8) Clusters[J]. Acta Phys. -Chim. Sin., 2009,25(02): 261-266
109. KE Xi; CUI Guo-Feng; SHEN Pei-Kang.Stability of Pd-Fe Alloy Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(02): 213-217
110. CHENG Hai-Bin; WANG Jin-Ming; MA Hui-Ru; HOU Peng; GUAN Jian-Guo; ZHANG Qing-Jie.Stability and Anti-Oxidization of Aqueous MR Fluids Improved by Modifying Iron Particle Surface with Organic Molecule[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1869-1874
111. MA Wen-Jin; ZHANG Xian-Ming; XU Xiao-Hong; WANG Yan-Bin; WU Hai-Shun.Structure Characteristics and Stability of CnAl2 (n=1-10) Clusters[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1477-1480
112. TIAN Zhen-Ning; XU Xuan.Theoretical Study on the Isomers of [M(CO)3(PPh2py)2] (M=Fe, Ru) Complex[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1482-1486
113. SHI Yan-Hua; MENG Hui-Min; SUN Dong-Bai; YU Hong-Ying; FU Hua-Rong.Manganese Oxide Coating Electrodes Prepared by Pulse Anodic Electrodeposition[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1199-1206
114. PAN Hai-Bo; WANG Fang; HUANG Jin-Ling; CHEN Nai-Sheng.Binding Characteristics of CoPc/SnO2 by In-situ Process and Photocatalytic Activity under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2008,24(06): 992-996
115. AI Hong-Qi; YANG Ai-Bin; LI Yun-Gang.Theoretical Study on the Interactions between Zn2+ and Adenine Isomers in Aqueous Phase[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1047-1052
116. WANG Ya-Ming; LIU Lan; LUO Yuan-Fang; JIA De-Min.Thermal Stability of Fluoroelastomer/MEPDM Blends[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1100-1104
117. GENG Chun-Yu; DING Li-Ying; HAN Qing-Zhen; WEN Hao.Influence of Gas Molecule on Stability of Methane Hydrate[J]. Acta Phys. -Chim. Sin., 2008,24(04): 595-600
118. LIANG Chu; LI Guang-Xu; LAN Zhi-Qiang; LIU Yi-Xin; WEI Wen-Lou; GUO Jin.Bond Characters and Thermodynamic Stabilities of LiAlH4 and Li3AlH6[J]. Acta Phys. -Chim. Sin., 2008,24(04): 686-690
119. ZHANG Cai-Yun; CUI Li-Ya; WU Hai-Shun.Structure and Stability of Endohedral Complexes X@(HAlNH)12 (X=Be,Mg, Ca, Zn, Al+, Ga+)[J]. Acta Phys. -Chim. Sin., 2008,24(03): 405-410
120. JI Yong-Jun; WU Hai-Shun; ZHANG Fu-Qiang; JIA Jian-Feng.Structure and Stability of (MN)nHm (M=Ga, In; n=1-4; m=1, 2) Clusters[J]. Acta Phys. -Chim. Sin., 2008,24(02): 257-262
121. XU Bo-Hua; LI Lai-Cai; WANG Xin; TIAN An-Min.Theoretical Study on the Structures and Stabilities of the N5H5 Isomers[J]. Acta Phys. -Chim. Sin., 2008,24(01): 67-73
122. ZHAN Ying-Ying; CAI Guo-Hui; ZHENG Yong; SHEN Xiao-Nv; ZHENG Ying; WEI Ke-Mei.Synthesis of High Surface Area Silicon Carbide and Its Application in CO Oxidation Reaction[J]. Acta Phys. -Chim. Sin., 2008,24(01): 171-175
123. GUO Ying-Jun; CHEN Hui; QI Lu.Progress in Electrolyte Solutions for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 80-89
124. LIANG Yun-Xiao; SHUI Miao; LI Rong-Sheng.Structures and Stabilities of Boron/Nitrogen-Doped Fullerene C20[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1647-1651
125. YIN Kai-Liang; ZOU Ding-Hui; ZHANG Xue-Hong; XI Hai-Tao; XIA Qing.Discussion of Correlations between the Chains in Au-Containing Nanoparticles and Molecular Simulation on Their Thermal Stabilities[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1207-1212
126. WANG Yan-Bin; MA Wen-Jin; ZHANG Jing; WU Hai-Shun.Structure Characteristics and Stability of CnAl (n=2-11) Clusters[J]. Acta Phys. -Chim. Sin., 2007,23(06): 873-876
127. LIU Hong-Jing; HE Gao-Hong; LIN Chang; ZHAO Wei; XIAO Gong-Kui.Controlling Water Transport in W/O/W Multiple Emulsion[J]. Acta Phys. -Chim. Sin., 2007,23(06): 935-939
128. ZHANG Jing; WANG Yan-Bin; WU Hai-Shun.Structure and Stability of the (BCO)+n (n=1-12) Clusters[J]. Acta Phys. -Chim. Sin., 2007,23(05): 733-737
129. MA Wen-Jin;WANG Yan-Bin;ZHANG Jing;WU Hai-Shun .Structure Characteristics and Stability of BmN (m=2~9) Clusters[J]. Acta Phys. -Chim. Sin., 2007,23(02): 169-172
130. JIA Jian-Feng;WU Hai-Shun.Structure and Properties of C-NT@BN-NT[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1520-1525
131. LI Quan;LI De-Hua;SHENG Yong;ZHU Zheng-He.Structure and Stability of PdYn±(n=0, 1, 2, 3) Molecular Ions[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1516-1519
132. DU Xin-Zhen;ZHOU Rong;TAO Xiao-Juan;WANG Fang-Ping;CHEN Hui.A Study of Cage-type Inclusion Complexes of Modified β-cyclodextrins with 2′-ethylhexyl-4-(N,N-dimethylamino)-benzoate[J]. Acta Phys. -Chim. Sin., 2006,22(09): 1065-1070
133. TIAN Xin-Xin;ZHANG Fu-Qiang;FENG Rui-Juan;WU Hai-Shun.Stability of B28N28Alternant Cages and Their Dependence on Bonds between Squares[J]. Acta Phys. -Chim. Sin., 2006,22(08): 937-941
134. GAO Jie;WANG Shi-Zhong.Study of Ni Composite Anodes for Dimethyl Ether Fuel Cell[J]. Acta Phys. -Chim. Sin., 2006,22(07): 851-855
135. XIAO Jian-Hua;LI Xue-Hui;DENG Sha;XU Jian-Chang;WANG Le-Fu.The NOx Oxidation-Storage and Tolerance of SO2 Poison of Mn/Ba/Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2006,22(07): 815-819
136. WANG Li-Jiang;ZHANG Cong-Jie.Structure and Stability of 2Cn+(n=1~9) Clusters[J]. Acta Phys. -Chim. Sin., 2006,22(06): 726-731
137. ZHANG Xiao-Qing;JIA Jian-Feng;WU Hai-Shun;PEI Xiao-Qin.Theory Investigation of (BCO)n(n=1~12)[J]. Acta Phys. -Chim. Sin., 2006,22(06): 684-690
138. XU Can;CAO Juan;ZHU Li-Fang;GAO Chen-Yang.Stability and Size Effect of Silica Nanotube[J]. Acta Phys. -Chim. Sin., 2006,22(04): 451-455
139. XU Meng-Qing; ZUO Xiao-Xi; LI Wei-Shan; ZHOU Hao-Jie; LIU Jian-Sheng; YUAN Zhong-Zhi.Effect of Butyl Sultone on the Li-ion Battery Performance and Interface of Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2006,22(03): 335-340
140. YAN Bin; AN Xue-qin; BAI Jing; ZHANG Ying-hua.Preparation of Cefazolin Sodium Liposomes by Supercritical Carbon Dioxide Method[J]. Acta Phys. -Chim. Sin., 2006,22(02): 226-229
141. MA Wen-jin; WU Hai-shun.Structure and Stability of AlmN2 (m=1~8) Clusters[J]. Acta Phys. -Chim. Sin., 2006,22(02): 178-182
142. GAO En-jun; DING Li-na; LIU Qi-tao; SUN Ya-guang.Studies on Stability of Pd(Ⅱ)Ternary Complexes and Interaction with DNA[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1091-1095
143. WANG Li-Jiang; ZHANG Cong-Jie; WU Hai-Shun.Structure, Stability and Spectra of CnBδ(δ=0, ±1; n=1~6) Clusters[J]. Acta Phys. -Chim. Sin., 2005,21(03): 244-249
144. TIAN Na;CHEN Wei;SUN Shi-Gang.Spectroscopic Characterization and Electrocatalytic Properties of Core-Shell Au-Pt Nanoparticles[J]. Acta Phys. -Chim. Sin., 2005,21(01): 74-78
145. Wang Shu-Rong;Wu Shi-Hua;Shi Juan;Zheng Xiu-Cheng;Huang Wei-Ping.Preparation and Catalytic Activity of Au/SnO2 for Low-temperature CO Oxidation[J]. Acta Phys. -Chim. Sin., 2004,20(04): 428-431
146. Ma Wen-Jin;Wu Hai-Shun.Study on the Structure and Stability of AlmN2 (m= 1~8) Clusters by DFT[J]. Acta Phys. -Chim. Sin., 2004,20(03): 290-295
147. Zeng Li;Wang Chun-Ming;Wei Ji-Ying;Zhu Yue-Xiang;Xie You-Chang.Preparation and Characterization of CrOx/ZrO2 with High Thermal Stability and High Specific Surface Area[J]. Acta Phys. -Chim. Sin., 2004,20(03): 251-255
148. Zhang Cai-Yun;Wu Hai-Shun.Structures and Stabilities of Borane and Guest Species Icosahedral Clusters[J]. Acta Phys. -Chim. Sin., 2004,20(02): 118-122
149. Yang Gang;Wang Yan;Zhou Dan-Hong;Zhuang Jian-Qin;Liu Xian-Chun;Han Xiu-Wen;Bao Xin-He.Investigation on the Thermal Stability of La/ZSM-5 Zeolite and the La3+ Species[J]. Acta Phys. -Chim. Sin., 2004,20(01): 60-64
150. Yang Hong-Ping;Wang Xian-You;Wang Xing-Yan;Huang Wei-Guo;Luo Xu-Fang;Zhuo Hai-Tao.Preparation and Performance of Electrode Materials for Super-iron (VI) Battery[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1150-1153
151. Li Zeng-He;Yin Chen;Wang Ru-Ji;Wang Ping;Guo Hong-You.Synthesis and Crystal Structure of an Inorganic-Organic Hybrid CompoundCo(μ2-bpy)V2O6 (bpy=4,4’-bipyridine)[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1133-1137
152. Zheng Jun-Lin;Zhang Ye;Wei Wei; Wu Dong;Sun Yu-Han;Deng Feng;Luo Qing;Yue Yong.Hydrothermally Stable Mesoporous Aluminosilicates with Strongly Acidic Sites[J]. Acta Phys. -Chim. Sin., 2003,19(10): 907-912
153. Zhang Rong-Bin;Li Feng-Yi;Yang Mei-Hua.The Effect of Support Al2O3 and Sm on the Thermal Stability of Amorphous NiB Alloy[J]. Acta Phys. -Chim. Sin., 2003,19(10): 970-973
154. Ma Wen-Jin;Wu Hai-Shun.Study on the Structure and Stability of the AlmN(m=2~9) Clusters by DFT[J]. Acta Phys. -Chim. Sin., 2003,19(10): 927-932
155. Yang Rui;He Shui-Yang;Gu Ai-Ping;Wen Zhen-Yi;Lin Xiang; Wen Hui-Zhong.Synthesis, Thermostability and Bioactivity of Mixed Ligand Complexes of Lanthanum with Alanine and Imidazoles[J]. Acta Phys. -Chim. Sin., 2003,19(07): 610-615
156. An Zeng-Jian;Zhou Peng;Jian Xi-Gao;Cai Tian-Xi.Sulfonated Poly (phthalazinone ether sulfone ketone) Catalyst with High Thermal Stability[J]. Acta Phys. -Chim. Sin., 2003,19(07): 654-656
157. Xu Yi-Ting;Dai Li-Zong;He Yun-You;Tahina Rakotoartsoa;JeanYves Gal;Wu HuiHuang.Electrochemical and Electrocatalytic Properties of Polyaniline Derivatives Membrane Modified Electrode[J]. Acta Phys. -Chim. Sin., 2003,19(06): 564-568
158. Yu Hai-Tao;Chi Yu-Juan;Fu Hong-Gang;Li Ze-Sheng;Sun Jia-Zhong.The Stability of Phosphaalkynes R-C≡P (R=-BH2, -CH3,-NH2, -OH) and Their Isomers[J]. Acta Phys. -Chim. Sin., 2003,19(02): 125-129
159. Zhang Min;Jin Zhen-Sheng;Wang Shou-Bin;Zhang Shun-Li;Zhang Zhi-Jun.The Photocatalytic Enhancement Effect of CO on Pd/TiO2[J]. Acta Phys. -Chim. Sin., 2003,19(02): 100-104
160. Cao Lin-You;Diao Peng;Liu Zhong-Fan.Preparation of Au (core)-Cu (shell) Nanoparticles Assembly by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1062-1067
161. Liu Feng-Ling.The Morse’s Type Potential Function for C60-C60 Interactions and Its Applications[J]. Acta Phys. -Chim. Sin., 2002,18(11): 967-972
162. Li Quan;Xu Cheng-Gang;Wang Hong-Yan;Zhu Zheng-He.Thermodynamic Stability of PuH2 (g) Molecules[J]. Acta Phys. -Chim. Sin., 2002,18(10): 952-955
163. Zhou Ling-Ping;Li Wei;Tao Ke-Yi;Li He-Xuan;Li Xuan-Wen.The Stability with Time-on-Stream of NaBr-Promoted KY Zeolite Catalyst for the Oxidative Methylation of Toluene with Methane[J]. Acta Phys. -Chim. Sin., 2002,18(10): 916-919
164. Chen Fu-Liang;Wang Yi;Zheng Fei-Neng;Liang Wen-Ping.Stability of Agrochemical Microemulsions at Low Temperature[J]. Acta Phys. -Chim. Sin., 2002,18(07): 661-664
165. Hu Wei;Ye Ru-Qiang;Wu Shu-Sen;Liu Hong-Lai.Influence of Alcohol on the Properties of Colloidal Liquid Aphrons[J]. Acta Phys. -Chim. Sin., 2002,18(02): 122-126
166. Yu Hai-Tao;Chi Yu-Juan;Fu Hong-Gang;Huang Xu-Ri;Sun Jia-Zhong.The Structures and Relative Stabilities of HBO2 Isomers[J]. Acta Phys. -Chim. Sin., 2002,18(01): 87-90
167. Fan Yin-Heng;Liao Shi-Jian;Li Wei-Na;Xu Jie;Wang Fu-Dong.Thermal Stability of NanoKH Particles and Their Chemical[J]. Acta Phys. -Chim. Sin., 2002,18(01): 55-58
168. Liu Dong-Yan;Fan Yan-Zhen;Zhang Yuan-Li;Wang Gui-Xiang;Wu Dong;Ren Jie.Surface Area Stability of Al2O3 Modified by Alkaline Earths[J]. Acta Phys. -Chim. Sin., 2001,17(11): 1036-1039
169. Li Quan;Wang Hong-Yan;Jiang Gang;Zhu Zheng-He.Structure and Potential Energy Function of PuX+(X=O,H,N,C)[J]. Acta Phys. -Chim. Sin., 2001,17(07): 622-625
170. Wang Shu-Guo;Wu Dong;Sun Yu-Han;Zhong Bing;Deng Feng;Yue Yong;Luo Qin.Synthesis of MCM-48 under High Pressure[J]. Acta Phys. -Chim. Sin., 2001,17(07): 659-661
171. Li Xiao-Feng, Chen Zhi-Rong, Liu Di-Xia, Pan Hai-Hua, Li Hao-Ran, Han Shi-Jun.Effect of Initial Emulsifier Locations on Emulsion Stability[J]. Acta Phys. -Chim. Sin., 2000,16(11): 964-967
172. Li Quan, Liu Xiao-Ya, Gao Tao, Zhu Zheng-He, Fu Yi-Bei, Wang Xiao-Lin, Sun Ying.Potentional Energy Function and Stability of PuOn+[J]. Acta Phys. -Chim. Sin., 2000,16(11): 987-991
173. Tao Chang-Yuan, Yan Hong-Mei, Liu Xin-An, Zhang Sheng-Tao, Luo Liu-Li.Influence of the Acid on the Belousov-Zhabotinskii Oscillating Reaction[J]. Acta Phys. -Chim. Sin., 2000,16(09): 835-838
174. Liu Hai-Bo, Hou Zhan-Jia, Liu Li-Ying, Xu Zhi-Ling, Xu Lei, Wang Wen-Cheng, Li Fu-Ming, Ye Ming-Xin.Optical Properties of Melamine Formaldehyde Resin[J]. Acta Phys. -Chim. Sin., 2000,16(06): 563-567
175. Liu Yong, Wang Jing-Xian, Yang Zhu-Xian, He A-Di, Chen Xiao-Yin.Thermal Stabilization of Barium on the Alumina at High Tempeiature[J]. Acta Phys. -Chim. Sin., 2000,16(06): 533-537
176. Wang Bang-Ning, Han Bu-Xing, Tan Fu.Effect of Solution Composition of Thermostability of Aconitase Conformation[J]. Acta Phys. -Chim. Sin., 2000,16(03): 284-288
177. Hou Ting-Jun, An Yu, Ru Bing-Gen, Xu Xiao-Jie.Theoretic Studies of Dynamics Stability to Three Kinds of Metallothioneins[J]. Acta Phys. -Chim. Sin., 2000,16(03): 221-225
178. Zhang Jian-Ye, Li Xuan-Wen, Liu Xing-Yun.Study on the Framework Stability and Surface Acidity of Hβ Zeolite by lnfrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 1999,15(12): 1092-1097
179. Zeng Jian-Qing, Zhang Jing-Cheng, Zhong Bing.Monte Carlo Simulation of CO Oxidation Reaction on Fractal Surface[J]. Acta Phys. -Chim. Sin., 1999,15(06): 555-559
180. Liu Ying-Jun, Zhang Ji-Jun, Li Neng, Lin Bing-Xiong.The Effect of CO2 on Catalytic Activity of Cu-Ce-O Complex Oxides for CO Oxidation[J]. Acta Phys. -Chim. Sin., 1999,15(02): 97-100
181. Zhang Ji-Jun, Liu Ying-Jun, Li Neng, Lin Bing-Xiong.Synergistic Effect between CuO and CeO2 for CO Oxidation[J]. Acta Phys. -Chim. Sin., 1999,15(01): 15-21
182. Fan Yin-Heng, Liao Shi-Jian, Yu Dao-Rong.Thermal Stability and Chemical Reactivity of Nanometric Sodium Hydride[J]. Acta Phys. -Chim. Sin., 1998,14(12): 1057-1060
183. Fu Jin-Kun, Liu Yue-Ying, Hu Rong-Zong, Zeng Jin-Long, Xu Pian-Pian, Lin Zhong-Yu, Yao Bing-Xin, Weng Cheng-Zhou.Preparation of Highly Dispersive Supported Gold Catalyst by Microbial Reduction Method[J]. Acta Phys. -Chim. Sin., 1998,14(09): 769-771
184. Zhou Li-Xin, Huang Zun-Xing, Tian An-Min, Wu Li-Ming, Hu Jian-Ming, Li Jun-Jian.Ab initio Study on the Relative Stability of C4Sm-4[J]. Acta Phys. -Chim. Sin., 1998,14(08): 752-756
185. Chen Zhao-Xu, Xiao He-Ming, Gao Bao-Hua.Theoretical Study on Tetrazole and its Derivatives(6)[J]. Acta Phys. -Chim. Sin., 1998,14(08): 757-764
186. He Xu, Zhao Guo-Xi, Zhu Bu-Yao.Study on the Properties of Vesicles in Aqueous Solution of Triethanolamine Dilaurate[J]. Acta Phys. -Chim. Sin., 1998,14(06): 509-513
187. Wang Jian, Zhu Tao, Fu Xiao-Yi, Liu Zhong-Fan.Study of Chemical Enhancement in SERS from Au Nanoparticles Assembly[J]. Acta Phys. -Chim. Sin., 1998,14(06): 485-489
188. Ma Zhi, Qin Yong-Ning, Qi Xiao-Zhou, Liang Zhen-Cheng, He Fei.Studies on Prepartion and CO Oxidation Activity of LaSrBO4 Compound[J]. Acta Phys. -Chim. Sin., 1998,14(05): 453-457
189. Zheng Kang-cheng, Rao Huo-Feng, He Feng, Xu Zhi-Tao, Liu Han-Qin.Ab initio Calculations of 1,2-Bidentate Thiolato Complexes of Fe,Co and Ni[J]. Acta Phys. -Chim. Sin., 1998,14(04): 299-304
190. Li Wen-Zhong, Miao Fang-Ming.Solvation Interaction and Stability of Modified Superoxide Dismutase[J]. Acta Phys. -Chim. Sin., 1998,14(04): 289-292
191. Zhou Ren-Xian, Chen Fang, Jiang Xiao-Yuan, Zheng Xiao-Ming.The Dispersed States of Manganese Species on Mn-O/ZrO2 Catalysts and its Influents on the Catalytic Performance[J]. Acta Phys. -Chim. Sin., 1998,14(02): 178-180
192. Li Hai-Yang,Ma Chen-Sheng,Bai Ji-Ling,He Guo-Zhong.Valence of Precursor Compound Effects on the Stability and Composition of Cu/Cl Binary Cluster Produced by Laser Vaporization[J]. Acta Phys. -Chim. Sin., 1997,13(10): 933-937
193. Liu Zhao-Yang,Huang Rong-Bin,Zheng Lan-Sun.Ab initio Calculation of Linear CnAl-(n=1~11)[J]. Acta Phys. -Chim. Sin., 1997,13(07): 621-625
194. Lin Hua-Kuan,Zhu Shou-Rong,Appolin,B.Kondiano,Kou Fu-Ping,Chen Rong-Ti.Study on Stability of Copper(II)-5-Substituted-1,10-Phenanthrolines-Dioxotraamines Macrocycles Ternary Systems[J]. Acta Phys. -Chim. Sin., 1997,13(05): 417-424
195. Wu Hai-Shun,Xu Xiao-Hong,Zhang Cong-Jie,Zhou Wei-Liang.Theoretical Study on the Structures and Stabilization of Metallic Borides[J]. Acta Phys. -Chim. Sin., 1997,13(03): 258-263
196. Guo Yang,Zhao Bi-Ying,Tang You-Qi.Effect of Surface Monolayer Modification by Oxides on the Thermal Stability of Tin Dioxide Ultrafine Powder[J]. Acta Phys. -Chim. Sin., 1997,13(02): 97-100
197. Zhou Ren-Xian,Jiang Xiao-Yuan,Lv Guang-Lie,Zheng Xiao-Ming.Desorption of Surface Oxygen on Cu/ZrO2-γ-Al2O3 and its Influence on the Catalytic Performance[J]. Acta Phys. -Chim. Sin., 1997,13(02): 128-133
198. Zeng Jian-Qing,Zhang Jing-Cheng,Guo Xiang-Yun,Zhong Bing.The Influence of Diffusion on the First Order Phase Transition Point of CO Oxidation:Monte Carlo Simulation[J]. Acta Phys. -Chim. Sin., 1997,13(02): 183-187
199. He Chong-Min,Zhang Wen-Min,Wang Ren.Surface Area Stability of Aluminas Modified by Rare Earths[J]. Acta Phys. -Chim. Sin., 1996,12(11): 971-975
200. Qian Jian-Gang,Gu Ti-Ren.Effect of Adsorption and Surface Micellization of Dodecylammonium Acetate on the Stability of Silica Suspension[J]. Acta Phys. -Chim. Sin., 1996,12(08): 698-703
201. Wang zhu,Zhu Ling-Feng,Zhang Guo-Bao,Zhao Gen-Suo,Zhu Yan.Investigation of the Thermal Decomposition Kinetics of Modified Carboxyl Hydroxypropyl Sesbania Gum[J]. Acta Phys. -Chim. Sin., 1996,12(07): 598-603
202. Li Xu-Yuan,Zhang Zi-Ping,Ma Jian-Tai,Zhu Zong-Zhen,Meng Yi-Min.The Catalytic Activity for CO Oxidation and Characterization of Perovskite-type Oxides Catalysts La1+X/2Sr1-x/2Co1-xCuxO3[J]. Acta Phys. -Chim. Sin., 1996,12(06): 502-507
203. ZHOU Ren-Xian, WEI Jian-Gen, ZHENG Xiao-Ming, WU Hong-Li, LV Guang-Lie.Study on Phase Structure, Pore Structure and catalytic Property of Out-layer ZrO2 on Alumina Base[J]. Acta Phys. -Chim. Sin., 1995,11(12): 1097-1100
204. Wen Zhao-Yin,Lin Zu-Xiang,Chen Kun-Gang.Hydrothermal Synthesis and Characteristics of a Layered Compound[J]. Acta Phys. -Chim. Sin., 1995,11(10): 876-880
205. Zhu Yong-Fa,Ye Xiao-Yan,Yao Wen-Qing,Chen De-Pu,Cao Li-Li.The Stability of C60 Film Bombarded by Ar Ion Beam[J]. Acta Phys. -Chim. Sin., 1995,11(08): 699-703
206. Huang Yin-Yan,Zhao Bi-Ying,Xie You-Chang.Structural Characterization of Solid Superacid Catalyst SO2-4-WO3-ZrO2[J]. Acta Phys. -Chim. Sin., 1995,11(06): 547-552
207. Liu Pei-Yan, Chu Ying, Wu Zi-Sheng, Yan Zhong, Kang Wan-Li.Study on the Stability of Liquid Membrane[J]. Acta Phys. -Chim. Sin., 1995,11(04): 320-324
208. Li Guang-Ping, Zhang Hua-Bei, Tian An-Min, Yan Guo-Sen.Theoretical Investigation of AlCn and AlC+n n=1-4 Series[J]. Acta Phys. -Chim. Sin., 1995,11(03): 211-217
209. Zhang Ju, Zheng Xiao-Meng, Wu Nian-Ci, Ding Yun-Jie.Study on the Chemical Preparation of Ultrafine Amorphous Ni-Co-B Alloy and their Thermal Stability[J]. Acta Phys. -Chim. Sin., 1995,11(02): 113-117
210. Xia Hai-Tao, Lin Hua-Kuan, Chen Rong-Ti.Thermodynamic and Kinetic Study on the Formation of Ternary Complex of Cobalt(II)-Bipyridyl-α-Aminoacids[J]. Acta Phys. -Chim. Sin., 1995,11(01): 74-78
211. Xian Jing-Chun, Zhu Shou-Rong, Lin Hua-Kuan, Chen Rong-Ti.Linear Free Energy Relationships of Complexes(XIX)[J]. Acta Phys. -Chim. Sin., 1994,10(09): 841-846
212. Xie Zhi-Ming; Gao Pian; Li Zhuo-Mei.Study on the Stability of Soap-free Water-Solubilized Polyacrylic Colloidal Dispersions[J]. Acta Phys. -Chim. Sin., 1994,10(05): 438-443
213. Shang Hai-Rong; Yu Cheng; Ying Li-Ming; Gao Pan-Liang; Zhao Xin-Sheng.The Stability of the à 3E State Methylnitrene Radical[J]. Acta Phys. -Chim. Sin., 1993,9(05): 594-596
214. Li Si-Dian; R.Johnston; J.Murrell.Structures and Relative Stabilities of tin Clusters[J]. Acta Phys. -Chim. Sin., 1993,9(05): 642-649
215. Zhu Hong-Yao; Jiang Yuan-Sheng.Cluster-Bethe-Lattice Model for Infinite Lattice Systems[J]. Acta Phys. -Chim. Sin., 1993,9(04): 473-477
216. Lin Hua-Kuan; Liu Zai-Jun; Tang Xiang-Hai; Chen Rong-Ti.Further Study of Linear Free Energy Relationships in Complex Compounds[J]. Acta Phys. -Chim. Sin., 1993,9(04): 565-568
217. Zhang Di-Chang; Zong Bao-Ning; Jin Ze-Ming; Tian Min; Min En-Ze.Effect of rare Earth(Y、Ce、Sm)) on Thermal Stability of Amorphous Ni-P Alloy[J]. Acta Phys. -Chim. Sin., 1993,9(03): 325-330
218. Kan Jin-Qing; Mu Shao-Lin.The Study of Properties for the Polyaniline Uricase Electrode[J]. Acta Phys. -Chim. Sin., 1993,9(03): 345-350
219. Shi Yang; Zhang Nan; Gao Zhen; Zhu Qi-He; Kong Fan-Ao.A Primary Study for the Formation and Photodissociation of Aluminum Sulfide Cluster Ions[J]. Acta Phys. -Chim. Sin., 1993,9(03): 299-301
220. Zhao Dong-Yuan; Yang Ya-Shu; Guo Xie-Xian; Wang Guo-Jia.Preparation,Pillarinc Structure and Thermal Stability of Hydroxy-Fe-Al Pillared Clays Containing Mixed-Metal Complexes(I)[J]. Acta Phys. -Chim. Sin., 1993,9(02): 193-199
221. Zhang He-Zhe; Bai Guang-Yue; Wang Yue-Jie; Yang Zhong.Studying on Stability of Emulsion Liquid Membrane with Moving Single Drop Method[J]. Acta Phys. -Chim. Sin., 1993,9(02): 233-237
222. Guo Ning; Zeng Guang-Fu; Xi Shi-Quan.Thermal Analysis nad Infrared Spectra of Dialkylammonium Tetrachlorocuprate[J]. Acta Phys. -Chim. Sin., 1992,8(06): 783-788
223. Du Shao-Bin; Wang Jin; Ma Fu-Tai; Zheng Hong-Yuan; Lou Hui; Jing Cheng-Heng.Correlation of Composition、Crystal Structure、Reducibility and Catalytic Oxidation Activity on La-Mn-Ni-O System[J]. Acta Phys. -Chim. Sin., 1992,8(05): 630-635
224. Feng Ke; Zeng Zhao-Hua; Li Zhuo-Mei.Study on Sulfonated EPDM Ionomers Containing Various Ions[J]. Acta Phys. -Chim. Sin., 1992,8(03): 370-375
225. Tang Da-Xin; Dong Xi-Juan; Wang Hui; Bai Yu-Bai; Li Li-Hua; Li Tie-Jin.Linear Dichroism Spectra of Langmuir-Blodgett Film of Cd Salt of 10,12-Tricosadiynoic Acid[J]. Acta Phys. -Chim. Sin., 1992,8(03): 394-397
226. Guo Rong.The Effects of Chain Length of Straight Chain Alcohol on the Strucutre and Stability of Lamellar Liquid Crystal[J]. Acta Phys. -Chim. Sin., 1991,7(06): 703-707
227. Cai Guo-Qiang; Dong Nan.Ab initio Molecular Orbital on the Acetaldehyde Dimer[J]. Acta Phys. -Chim. Sin., 1991,7(03): 270-275
228. ZHAI Wei, WANG Jian-yuan.【Retracted】Stability of Au Nanocrystals in 2D Superlattice[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
229. SHAI Xu-Xia, LI Dan, LIU Shuang-Shuang, LI Hao, WANG Ming-Kui.Advances and Development of Perovskite Materials for Solar Cells Application[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
230. LIANG Mei-Qing, YIN Hong-Yao, FENG Yu-Jun.Smart Aqueous Foams: State of the Art[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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