Article
Kinetic Behavior of Visible Light Photocatalytic Oxidation of Propylene for N-Doped Nano-TiO2
FENG Cai-Xia; WANG Yan; JIN Zhen-Sheng; ZHANG Shun-Li
College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan Province, P. R. China; Functional Material Research Center, Kaifeng University, Kaifeng 475004, Henan Province, P. R. China
College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan Province, P. R. China; Functional Material Research Center, Kaifeng University, Kaifeng 475004, Henan Province, P. R. China
N-doped TiO2 (anatase) with high visible light photocatalytic activity was prepared by treating nanotube titanic acid (NTA) in NH3 flowat different temperatures. The crystalline structure of N-doped TiO2 determined by XRD was anatase when the treating temperature was higher than 400 ℃, however, a newphase (TiN) emerged at 700 ℃. The UV-Vis diffuse reflectance spectra (DRS) display that N-doped TiO2 has a continuous absorption at λ=400 nm. The photocatalytic activity of the N-doped TiO2 was determined by the photocatalytic oxidation of propylene under visible light irradiation. The highest photocatalytic activity was obtained for the catalyst treated at 600 ℃ in NH3 flow, which was active even under λ=500 nm, its kinetic behavior was accordant with the first order reaction formula.
Keywords: Nanotube titanic acid Dioxide titanium Nitrogen doped Visible light photocatalysis
Received: 2007-08-22 Accepted: 2007-12-26 Publication Date (Web): 2007-03-03
Corresponding Authors: JIN Zhen-Sheng Email: zhenshengjin@henu.edu.cn
Cite this article: FENG Cai-Xia; WANG Yan; JIN Zhen-Sheng; ZHANG Shun-Li. Kinetic Behavior of Visible Light Photocatalytic Oxidation of Propylene for N-Doped Nano-TiO2[J]. Acta Phys. -Chim. Sin., 2008,24 (04): 633-638. doi: 10.3866/PKU.WHXB20080415
Keywords: Nanotube titanic acid Dioxide titanium Nitrogen doped Visible light photocatalysis
Received: 2007-08-22 Accepted: 2007-12-26 Publication Date (Web): 2007-03-03
Corresponding Authors: JIN Zhen-Sheng Email: zhenshengjin@henu.edu.cn
Cite this article: FENG Cai-Xia; WANG Yan; JIN Zhen-Sheng; ZHANG Shun-Li. Kinetic Behavior of Visible Light Photocatalytic Oxidation of Propylene for N-Doped Nano-TiO2[J]. Acta Phys. -Chim. Sin., 2008,24 (04): 633-638. doi: 10.3866/PKU.WHXB20080415
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97． Wang Li-Ying,Zhang Yan,Zeng Guang-Fu,Xi Shi-Quan.Preparation of TiO2 Film through Hydrolysis of Titanium Butoxide and Interaction between Sensitizing Dyes and the Film[J]. Acta Phys. -Chim. Sin., 1997,13(08): 752-755
98． Zhang Jun,Luo Sheng-Cheng,Gui Lin-Lin,Tang You-Qi.Synthesisi and Characterization of New PMMA-TiO2 Organic-Lnorganic Hybrid Glasses[J]. Acta Phys. -Chim. Sin., 1996,12(04): 289-292
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2． GUO Qing, ZHOU Chuan-Yao, MA Zhi-Bo, REN Ze-Feng, FAN Hong-Jun, YANG Xue-Ming.Fundamental Processes in Surface Photocatalysis on TiO2[J]. Acta Phys. -Chim. Sin., 2016,32(1): 28-47
3． LI Xiao-Kun, MA Dong-Dong, ZHENG Yan-Ping, ZHANG Hong, DING Ding, CHEN Ming-Shu, WAN Hui-Lin.Performance of CO Oxidation over Highly Dispersed Gold Catalyst on TiOx/SiO2 Composite Supports[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1753-1760
4． HU Hai-Feng, HE Tao.Controlled Aspect Ratio Modulation of ZnO Nanorods via Indium Doping[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1421-1429
5． SHI Chen-Yang, HE Hui-Bin, HONG Zan-Fa, ZHAN Hong-Bing, FENG Miao.Effect of HCl Post-Treatment on Morphology of Hydrothermally Prepared Titanate Nanomaterials with Optical Limiting Properties[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1430-1436
6． LI Zhen-Jiang, MA Feng-Lin, ZHANG Meng, SONG Guan-Ying, MENG A-Lan.Preparation, Field Emission Characteristics and First-Principles Calculations of La-Doped or N-Doped SiC Nanowires[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1191-1198
7． ZHANG Qiao-Ling, LI Lei, LIU You-Zhi, WEI Bing, GUO Jia-Xin, FENG Yu-Jie.Grafting Dynamics, Structures and Properties of Nano TiO2-SA Photocatalytic Materials[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1015-1024
8． XU Jing, YANG De-Zhi, LIAO Xiao-Zhen, HE Yu-Shi, MA Zi-Feng.Electrochemical Performances of Reduced Graphene Oxide/Titanium Dioxide Composites for Sodium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2015,31(5): 913-919
9． CHEN Hong, WANG Shi-Xian, ZHAO Wan-Long, ZHANG Neng-Neng, ZHENG Ying-Ping, SUN Yue-Ming.Preparation of Pt/TiO2 Nanofibers and Their Electrocatalytic Activity towards Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2015,31(2): 302-308
10． TIAN Hong, WANG Hui-Xiang, SHI Wei-Mei, XU Yao.Microwave-Assisted Solvothermal Synthesis of In-Si Co-Modified TiO2 Photocatalysts with Enhanced Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1543-1549
11． YAN Jing-Sen, WANG Hai-Yan, ZHANG Jing-Ru, XU Hui-Juan.Effect of TiO2-Al2O3 Support Preparation Technique on Hydrodenitrogenation of Ni2P/TiO2-Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2014,30(7): 1309-1317
12． WANG Shi-Mao, DONG Wei-Wei, FANG Xiao-Dong, DENG Zan-Hong, SHAO Jing-Zhen, HU Lin-Hua, ZHU Jun.Modification of Single-Crystal TiO2 Nanorod Arrays and Its Application in Quantum Dot-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(5): 873-880
13． AO Ping, XU Xiang-Sheng, XU Xiao-Xiao, LI Jia-Heng, YAN Xin-Huan.Low-Temperature Total Oxidation of Toluene over Assembled Pt/TiO2 Catalyst[J]. Acta Phys. -Chim. Sin., 2014,30(5): 950-956
14． LAN Ben-Yue, SHI Hai-Feng.Review of Systems for Photocatalytic Conversion of CO2 to Hydrocarbon Fuels[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2177-2196
15． JIANG Chun-Xiang, HU Yu-Xiang, DONG Wen, ZHENG Fen-Gang, SU Xiao-Dong, FANG Liang, SHEN Ming-Rong.Bias-Determined Cu2O and Cu Growth on TiO2 Surface and Their Photoelectrochemical Properties[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1867-1875
16． WEI Mei-Ju, JIA De-Qiang, CHEN Fei-Wu.Geometric Structures, Excitation Energies and Dipole Moments of the Ground and Excited States of TiO2[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1441-1452
17． LONG Mei, CONG Ye, LI Xuan-Ke, CUI Zheng-Wei, DONG Zhi-Jun, YUAN Guan-Ming.Hydrothermal Synthesis and Photocatalytic Activity of Partially Reduced Graphene Oxide/TiO2 Composite[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1344-1350
18． LI Na, CHEN Qiu-Yan, LUO Meng-Fei, LU Ji-Qing.Kinetics Study of CO Oxidation Reaction over Pt/TiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1055-1062
19． LIU Su-Qin, DAI Gao-Peng, LIANG Ying, LIU Hua-Jun, LIANG Gui-Jie.Fabrication and Visible-Light Photocatalytic Activity of In situ Carbon and Nitrogen Co-Doped TiO2 Hollow Sphere[J]. Acta Phys. -Chim. Sin., 2013,29(03): 585-589
20． JIN Tao, XU Di, DIAO Peng, XIANG Min.Preparation and Photoelectrocatalytic Water Oxidation Properties of FeO(OH)-TiO2/CoPi Composite Photoanodes[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2276-2284
21． LI Jie-Bin, XU You-Long, DU Xian-Feng, SUN Xiao-Fei, XIONG Li-Long.Improved Electrochemical Stability of Zn-Doped LiNi1/3Co1/3Mn1/3O2 Cathode Materials[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1899-1905
22． LIU Hao, LIN Meng-Hai, TAN Kai.A Tight-Binding Density Functional Theory Study on Single-Walled Nanotubes from Anatase TiO2 (101) Sheets[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1843-1848
23． ZHAO Peng-Jun, WU Rong, HOU Juan, CHANG Ai-min, GUAN Fang, ZHANG Bo.One-Step Hydrothermal Synthesis and Visible-Light Photocatalytic Activity of Ultrafine Cu-Nanodot-Modified TiO2 Nanotubes[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1971-1977
24． HU Wen-Liang, XU Gang, MA Jian-Wei, XIONG Bin, SHI Ji-Fu.Optical and Phase Transition Properties of TixV1-xO2 Thin Films[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1533-1538
25． LIU Qiu-Ping, HUANG Hui-Juan, ZHOU Yang, DUAN Yan-Dong, SUN Qing-Wen, LIN Yuan.Photovoltaic Performance of Dye-Sensitized Solar Cells Based on Al-Doped TiO2 Thin Films[J]. Acta Phys. -Chim. Sin., 2012,28(03): 591-595
26． SONG Hua, ZHANG Yong-Jiang, SONG Hua-Lin, DAI Min.Effect of Citric Acid on the Hydrodesulfurization Performance of Ni2P/TiO2-Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2012,28(03): 661-666
27． XIAO Yao-Ming, WU Ji-Huai, YUE Gen-Tian, LIN Jian-Ming, HUANG Miao-Liang, FAN Le-Qing, LAN Zhang.Preparation of Single-Crystalline TiO2 Nanowires and Their Application in Flexible Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2012,28(03): 578-584
28． GAO Yue-Jun, XU Yi-Ming.Effect of Fluoride Doping and Adsorption on the Photocatalytic Activity of TiO2[J]. Acta Phys. -Chim. Sin., 2012,28(03): 641-646
29． YAN Bing-Xi, LUO Sheng-Yun, SHEN Jie.Photoelectric Properties of Mo Doped TiO2 Thin Films Deposited by DC Reactive Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2012,28(02): 381-386
30． DONG Hua-Qing, PAN Xi, XIE Qin, MENG Qiang-Qiang, GAO Jian-Rong, WANG Jian-Guo.CO Adsorption and Oxidation on Metal-Doped TiO2 Nanotube Arrays[J]. Acta Phys. -Chim. Sin., 2012,28(01): 44-50
31． NIE Long-Hui, HU Yao, ZHANG Wang-Xi.Preparation of a Ag@AgCl-Modified TiO2-xCx Photocatalyst and Its Performance for Degradation of Pollutants under Visible Light[J]. Acta Phys. -Chim. Sin., 2012,28(01): 154-160
32． HU Xian-Chao, CHEN Dan, SHI Bin-Bin, LI Guo-Hua.Preparation of Tungsten Carbide and Titania Nanocomposite and Its Electrocatalytic Activity for Methanol[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2863-2871
33． CHEN Shu-Hai, XU Yao, LÜ Bao-Liang, WU Dong.Microwave-Assisted Hydrothermal Synthesis of Ag-Loaded Titania Nanotubes and Their Photocatalytic Performance[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2933-2938
34． YAN Shi, HUANG Qin-Dong, LIN Jing-Dong, YUAN You-Zhu, LIAO Dai-Wei.Photocatalytic Activity of Cobalt Doped Titania for H2 Evolution[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2406-2410
35． TONG Xin, CHEN Rui, CHEN Tie-Hong.Photocatalytic Activity of TiO2 with Micrometer-Sized Macropores[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1941-1946
36． CONG Ye, QIN Yun, LI Xuan-Ke, DONG Zhi-Jun, YUAN Guan-Ming, CUI Zheng-Wei.Preparation and Visible Light Photocatalytic Activity of Titanium Dioxide Coated Multiwalled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1509-1515
37． LI Huan-Huan, CHEN Run-Feng, MA Cong, ZHANG Sheng-Lan, AN Zhong-Fu, HUANG Wei.Titanium Oxide Nanotubes Prepared by Anodic Oxidation and Their Application in Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1017-1025
38． JIANG Jing-Jing, LONG Ming-Ce, WU De-Yong, CAI Wei-Min.Preparation of F-Modified Nanosized TiO2 and Its Methyl Orange Photodegradation Mechanism[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1149-1156
39． LAO Chun-Feng, CHU Zeng-Ze, ZOU De-Chun.Self-Assembly of 3-Aminopropyltrimethoxysilane to Improve the Efficiency of Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(02): 419-424
40． LIU Jia, YANG Hao-Tian, ZHANG Jing-Bo, ZHOU Xiao-Wen, LIN Yuan.Room Temperature Synthesis of Rutile TiO2 and Its Application in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(02): 408-412
41． WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng.Preparation and Characterization of One-Dimensional TiO2 Nanowire Films on a Flexible Stainless Steel Substrate[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3087-3094
42． QIAN Di-Feng, ZHANG Qing-Hong, WAN Jun, LI Yao-Gang, WANG Hong-Zhi.Enhancing the Photovoltaic Performance of Dye Sensitized Solar Cells with the TiO2 Sol Infiltrated Nanocrystalline Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2745-2751
43． LIU Yu-Liang, YOU Cui-Rong, LI Yang, HE Tao, ZHANG Xiang-Qin, SUO Zhang-Huai.Preparation of Au@TiO2 Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2455-2460
44． SONG Hua,GUO Yun-Tao, LI Feng ,YU Hong-Kun.Preparation, Hydrodesulfurization and Hydrodenitrogenation Performance of a Ni2P/TiO2-Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2461-2467
45． XU Ping-Chang, LIU Yang, WEI Jian-Hong, XIONG Rui, PAN Chun-Xu, SHI Jing.Solvothermal Preparation of Ag/TiO2 Nanoparticles and Their Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2261-2266
46． ZHAI Xiao-Hui, LONG Hui-Jin, DONG Jiang-Zhou, CAO Ya-An.Doping Mechanism of N-TiO2/ZnO Composite Nanotube Arrays and Their Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2010,26(03): 663-668
47． ZHANG Qiong, HE Yun-Qiu, CHEN Xiao-Gang, HU Dong-Hu, LI Lin-Jiang, YIN Ting, JI Ling-Li.Intercalated Structure and Photocatalytic Properties of TiO2-Graphite Oxide Composite[J]. Acta Phys. -Chim. Sin., 2010,26(03): 654-662
48． ZHANG Xiao-Yan, CUI Xiao-Li.Preparation and Photocatalytic Hydrogen Evolution Performance of C-N Co-doped Nano TiO2 Photocatalysts[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1829-1834
49． DONG Xiang, TAO Jie, LI Ying-Ying, WANG Tao, ZHU Hong.Photoelectrochemical Properties of Three-Dimensional Network TiO2 Nanowire Film Prepared by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1874-1882
50． DU Wei-Ping, LI Zhen, LENG Wen-Hua, XU Yi-Ming.Photocatalytic Reduction of Silver Ions on Ferric Oxides and Ferric Hydroxides[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1530-1534
51． FENG Li-Li, ZHAO Wei, LIU Yang, JIAO Liang, LI Xing-Guo.Photocatalytic Degradation of Rhodamine B by Nanocrystalline TiO2 Loaded into MCM-41 Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2009,25(07): 1347-1351
52． LEI Jian-Fei, LI Wei-Shan.Photoelectrocatalytic Performance of Arrayed Porous TiO2/Ti[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1173-1178
53． YU Zhi-Yong; ZHANG Wei; MA Ming; CUI Xiao-Li.Visible Light Photoelectrochemical Response of Nitrogen-Doped TiO2 Thin Films Prepared by Anodic Oxidation of Titanium Nitride Films[J]. Acta Phys. -Chim. Sin., 2009,25(01): 35-40
54． CHANG Guo-Qing, ZHENG Xi, CHEN Ri-Yao, CHEN Xiao, CHEN Li-Qin, CHEN Zhen.Silver Nanoparticles Filling in TiO2 Hollow Nanofibers by Coaxial Electrospinning[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1790-1796
55． LI Hai-Long; LUO Wu-Lin; CHEN Tao; TIAN Wen-Yu; SUN Mao; LI Chun; ZHU Di; LIU Ran-Ran; ZHAO Yu-Liang; LIU Chun-Li.Preparation and Photocatalytic Performance of Titania Nanotubes Loaded with Ag Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1383-1386
56． SHI Jian; LI Jun; CAI Yun-Fa.Fabrication of C, N-Codoped TiO2 Nanotube Photocatalysts with Visible Light Response[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1283-1286
57． PAN Hai-Bo; WANG Fang; HUANG Jin-Ling; CHEN Nai-Sheng.Binding Characteristics of CoPc/SnO2 by In-situ Process and Photocatalytic Activity under Visible Light Irradiation[J]. Acta Phys. -Chim. Sin., 2008,24(06): 992-996
58． LUO Da-Chao; ZHANG Lan-Lan; LONG Hui-Jin; CHEN Yong-Mei; CAO Ya-An.Effect of Surface Modification by Ni2+ on Photocatalysis Activity of TiO2[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1095-1099
59． CHEN Kun; FAN Guang-Han; ZHANG Yong; DING Shao-Feng.First-Principle Calculation of Nitrogen-Doped p-Type ZnO[J]. Acta Phys. -Chim. Sin., 2008,24(01): 61-66
60． WU Yu-Cheng; LIU Xiao-Lu; YE Min; XIE Ting; HUANG Xin-Min.Preparation and Properties of Carbon Nanotube-TiO2 Nanocomposites[J]. Acta Phys. -Chim. Sin., 2008,24(01): 97-102
61． ZHANG Jun-Jie; WU Min; QIN Yan-Tao; CHEN Rui; JIANG Yin-Hua; SUN Yue-Ming; YANG Zhao-Hui.Study on Zn(II) Tetracarboxy Phthalocyanine Doped TiO2 Electrode Using Electrochemical Impedance Spectrum[J]. Acta Phys. -Chim. Sin., 2008,24(01): 79-84
62． CHEN Qi-Yuan; TONG Hai-Xia; YIN Zhou-Lan; HU Hui-Ping; LI Jie; LIU Liang-Liang.Preparation, Characterization and Photo-catalytic Behavior of TiO2 Catalysts with Oxygen Vacancies[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1917-1921
63． ZHU Lei; CUI Xiao-Li; SHEN Jie; YANG Xi-Liang; ZHANG Zhuang-Jian.Visible Light Photoelectrochemical Response of Carbon-doped TiO2 Thin Films Prepared by DC Reactive Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1662-1666
64． YANG Hui; SHEN Qian-Hong; GAO Ji-Wei.Morphology Control of Anatase TiO2 Films Prepared at Low Temperature Using 4,4’-isopropylidenediphenol[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1269-1274
65． HUANG Dong-Sheng; ZENG Ren-Jie; CHEN Chao-Feng; LI Yu-Hua.Hydrophilicity of TiO2 Thin Films Codoped with Iron and Nitrogen[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1037-1041
66． YAN Zhi-Ying; WU Li-Yan; SUN Gui-Xiang; ZHANG Ning; ZHENG Wen-Jun.Structural Characterization of Nanocrystalline TiO2 fromIonic Liquid-Water Solvent Mixture and Its Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1032-1036
67． DING Ying-Ying; LI Kui-Ying.Photoacoustic and Surface Photovoltaic Characters of Nanocrystalline TiO2[J]. Acta Phys. -Chim. Sin., 2007,23(04): 569-574
68． CHEN Hong-Sheng;QI Jun-Jie;HUANG Yun-Hua;LIAO Qing-Liang;ZHANG Yue.Synthesis, Structure and Properties of Sn-doped ZnO Nanobelts[J]. Acta Phys. -Chim. Sin., 2007,23(01): 55-58
69． GU Hong;XU Bo-Lian;ZHOU Jing;LI Yuan-Zhi;FAN Yi-Ning.Catalytic Properties of Supported Pd/TiO2 and Pd-Ag/TiO2 Catalysts for Selective Hydrogenation of Acetylene[J]. Acta Phys. -Chim. Sin., 2006,22(06): 712-715
70． ZHANG Xue-Hong;TANG Xing-Hua;CHENG Xin-Sun.Synthesis and Application of Ce-doped Mesoporous TiO2[J]. Acta Phys. -Chim. Sin., 2006,22(05): 532-537
71． WANG Peng; CHEN Dong; LIU Jian-Shu; TANG Fang-Qiong.Synthesis and Characterization of Monodisperse TiO2 Colloid Particles[J]. Acta Phys. -Chim. Sin., 2006,22(03): 365-368
72． LIU Juan; ZHANG Yue; QI Jun-jie; HE Jian; HUANG Yun-hua; ZHANG Xiao-mei.Fabrication and Characterization of In-doped Zinc Oxide Nanodisks[J]. Acta Phys. -Chim. Sin., 2006,22(01): 38-42
73． LI Zhi-Jie; HOU Bo; XU Yao; WU Dong; SUN Yu-Han.Preparation and Characterization of Silica-modified Titanium Dioxide Nanoparticles by Co-precipitation Method[J]. Acta Phys. -Chim. Sin., 2005,21(03): 229-233
74． YAN Qing-Zhi;SU Xin-Tai;ZHOU Yan-Ping;GE Chang-Chun.Controlled Synthesis of TiO2 Nanometer Powders by Sol-gel Auto-igniting Process and Their Structural Property[J]. Acta Phys. -Chim. Sin., 2005,21(01): 57-62
75． Li Yue-Xiang; Wang Tian-Hui; Peng Shao-Qin1 Lü Gong-Xuan; Li Shu-Ben.Synergistic Effect of Eu3＋ and Si4＋ Co-doping on Photocatalytic Activity of Titanium Dioxide[J]. Acta Phys. -Chim. Sin., 2004,20(12): 1434-1439
76． Shen Jie;Wo Song-Tao;Cui Xiao-Li;Cai Zhen-Wei;Yang Xi-Liang;Zhang Zhuang-Jian.Photoelectrochemical Characteristics of Nano-Titanium Dioxide Thin Films Prepared by RF Magnetron Sputtering[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1191-1195
77． Zhang Qi;Li Xin-Jun;Li Fang-Bai;Chang Jie.Investigation on Visible -light Activity of WOx/TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2004,20(05): 507-511
78． Liu Shou-Xin;Sun Cheng-Lin.Mechanism of Silver Modification for the Enhanced Photocatalytic Activity of Cr(VI) Reduction on TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2004,20(04): 355-359
79． Zhang Jin-Long;Zhao Wen-Juan;Chen Hai-Jun;Xu Hua-Sheng;Chen Ai-Ping;Anpo Masa-Kazu.Study of Loaded Photocatalysts by Precious Metals on the Photocatalytic Reactivity[J]. Acta Phys. -Chim. Sin., 2004,20(04): 424-427
80． Wu ShuXin;Ma Zhi;Qin Yong-Ning;Qi Xiao-Zhou;Liang Zhen-Cheng.Photocatalytic Redox Activity of Doped Nanocrystalline TiO2[J]. Acta Phys. -Chim. Sin., 2004,20(02): 138-143
81． Ding Zheng-Xin;Hou Yi-Dong;Li Dan-Zhen;Wang Xu-Xu;Fu Xian-Zhi;Liu Ping.Effect of Morphological Structure and Photoelectric Properties on Photocatalytic Performance of TiO2[J]. Acta Phys. -Chim. Sin., 2003,19(10): 978-981
82． Wu Shu-Xin;Ma Zhi;Qin Yong-Ning;He Fei;Jia Li-Shan;Zhang Yan-Jun.XPS Study of Copper Doping TiO2 Photocatalyst[J]. Acta Phys. -Chim. Sin., 2003,19(10): 967-969
83． Ren Da-Sen;Cui Xiao-Li;Zhang Qun;Wo Song-Tao;Yang Xi-Liang;Zhang Zhuang-Jian;Lu Ming.Characteristics of SiO2-TiO2 Complex Thin Films Prepared by Sol Method[J]. Acta Phys. -Chim. Sin., 2003,19(09): 829-833
84． Zhang Sheng-Mao;Zhang Zhi-Jun;Dang Hong-Xin;Liu Wei-Min;Xue Qun-Ji.Preparation and Characterization of TiO2/Poly(butyl acrylate) Nanocomposite Film[J]. Acta Phys. -Chim. Sin., 2003,19(02): 171-173
85． Qin Cao;Wang Ting-Jie;Jin Yong.The Coating Process of Nano-scale Hydrous Silica Film on TiO2 Particles by Chemical Deposition in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2002,18(10): 884-889
86． Li Dan-Zhen;Zheng Yi;Fu Xian-Zhi.Study on the Effect and Mechanism of the Coupling between Microwave and Photocatalysis[J]. Acta Phys. -Chim. Sin., 2002,18(04): 332-335
87． Chen Hong-Ling;Wang Yan-Ru;Shi Jun.Preparation of Monodispersed Superfine Titanium Dioxide Particles and Size Control[J]. Acta Phys. -Chim. Sin., 2001,17(08): 713-717
88． Zou Ling;Wu Xue-Dong;Chen Hai-Gang;Wang Da-Pu.Structural Characterization and Formation Mechanism of SurfaceModified Titanium Dioxide Nanoparticles[J]. Acta Phys. -Chim. Sin., 2001,17(04): 305-309
89． Guo Yuan;Li Yong-Jun;Xia Xi;Zhang Xiao-Gang;He Mao-Xia.Effect of Extrinsic Factors on the CPE Behavior of Film TiO2 Electrode[J]. Acta Phys. -Chim. Sin., 2001,17(04): 372-376
90． Liu Hong;Wu Ming;Wu He-Jin;Sun Fu-Xia;Zheng Yun;Li Wen-Zhao.Photocatalytic Activity and Electrochemical Impedance Spectroscopy of TiO2 Thermally Treated by Hydrogen[J]. Acta Phys. -Chim. Sin., 2001,17(03): 286-288
91． Li Dan-Zhen;Zheng Yi;Fu Xian-Zhi;Liu Ping.SO2-4/TiO2 Catalyst Prepared by Microwave Method and the Research of its Photocatalytic Oxidation Activity[J]. Acta Phys. -Chim. Sin., 2001,17(03): 270-272
92． Su Wen-Yue;Fu Xian-Zhi;Wei Ke-Mei.Effect of Sulfation on Structure and Photocatalytic Performance of TiO2[J]. Acta Phys. -Chim. Sin., 2001,17(01): 28-31
93． Li Fang-Bai, Gu Guo-Bang, Li Xin-Jun, Wan Hong-Fu.Preparation,Characterization and Photo-catalytic Behavior of WO3/TiO2 Nanopowder[J]. Acta Phys. -Chim. Sin., 2000,16(11): 997-1002
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