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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2008,Vol.24>> Issue(05)>> 737-742     doi: 10.1016/S1872-1508(08)60030-3         中文摘要
Mechanism of Methane’s Adsorption on Nanometer Active Carbon at Supercritical State
GUO Liang; WU Zhan-Song
Department of Thermal Engineering, Tsinghua University, Beijing 100084, P. R. China
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Isosteric heats and adsorption isotherms of methane on nanometer active carbon were measured at supercritical temperature (273-373 K) and pressure from 0 to 10 MPa. The measured data agreed well with Dubinin-Astakhov (DA) model at lower pressure but failed when pressure exceeded a special range. General Freundlich (GF) equation was used to modify the DA equation at high pressure and thus formed a combined bisection model GFDA. The adsorption mechanism of methane on nanometer active carbon was raised according to GFDA model and the heterogeneous energy distribution of the adsorbent was analyzed.

Keywords: Supercritical   Nanometer active carbon   Adsorption potential   Methane  
Received: 2007-10-11 Accepted: 2008-01-24 Publication Date (Web): 2008-03-13
Corresponding Authors: WU Zhan-Song Email: wzs@mail.tsinghua.edu.cn


Cite this article: GUO Liang; WU Zhan-Song. Mechanism of Methane’s Adsorption on Nanometer Active Carbon at Supercritical State[J]. Acta Phys. -Chim. Sin., 2008,24 (05): 737-742.    doi: 10.1016/S1872-1508(08)60030-3
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