ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2008,Vol.24>> Issue(08)>> 1503-1506     doi: 10.3866/PKU.WHXB20080830         中文摘要
Supramolecular Complexation in Water-Methanol Mixtures
ZHENG Bo; LI He-Xian; WANG Guo-Chang; LIU Kun; YUAN Wei; LI He; LIANG Bo
Key Laboratory of Functional Polymer Materials, Ministry of Education, Institute of Polymer Chemistry, Nankai University, Tianjin 300071, P. R. China
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The complex structures in the entire composition range of water-methanol mixture were studied by pyrene fluorescence probe. The results showed that the decrease rate of I1/I3, the pyrene scale for solvent polarity, exhibited clear dependence on the mole fraction (xm) range of methanol in the mixture, while the relative quantum yield of pyrene fluorescence showed a remarkable maximum at xm=0.18. These results revealed that in a wide range of 0.18<xm<0.75, the molecules of water and methanol mainly formed water/methanol (W/M) complexes (W5M1-5) and methanol/water (M/W) complexes (M6W2-4, M8W1-3), and a transition of“W/M→M/W”complexes would occur at xm≈0.50. This notion provides a conjuncture to reconcile the two existing formulations about water-methanol complexation.

Keywords: Water-methanol   Complex structure   Pyrene   Fluorescence probe   Hydrogen bond  
Received: 2008-02-27 Accepted: 2008-04-18 Publication Date (Web): 2008-06-05
Corresponding Authors: WANG Guo-Chang Email:

Cite this article: ZHENG Bo; LI He-Xian; WANG Guo-Chang; LIU Kun; YUAN Wei; LI He; LIANG Bo. Supramolecular Complexation in Water-Methanol Mixtures[J]. Acta Phys. -Chim. Sin., 2008,24 (08): 1503-1506.    doi: 10.3866/PKU.WHXB20080830
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100. Liu Shou-Xin;Liu Ming-Zhu.Fluorescence Probe Studies on the Conformation Behavior of P(DEAM-co-MAA) in Dilute Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2004,20(05): 478-482
101. Li Lai-Cai;Qian Yi-Ming;Zhu Yuan-Qiang;Tian An-Min.Theoretical Study on the Reaction Mechanism of the CH3 Radical with HNCO[J]. Acta Phys. -Chim. Sin., 2004,20(03): 228-232
102. Huang Jian-Gou;Xu Man-Cai;Li Hai-Tao;Shi Zuo-Qing;He Bing-Lin.Adsorption Thermodynamics of Macroporous Cross-linked Poly (N-methyl-N-p- vinylbenzylacetamine) Resin for Phenols from Non-aqueous System[J]. Acta Phys. -Chim. Sin., 2003,19(03): 208-211
103. Li Rui-Hua;Jiang Zhan-Peng;Shi Shao-Qi;Yang Hong-Wei.Raman Spectroscopic Study of Effect of CaCl2 and MgCl2 on Structure of Water[J]. Acta Phys. -Chim. Sin., 2003,19(02): 154-157
104. Bian Feng-Ling;Liu Ming-Zhu.The Temperature Dependence of the Viscosity of Poly (N,N-diethylacrylamide) Solutions[J]. Acta Phys. -Chim. Sin., 2002,18(09): 776-780
105. Kuang Han-Mao;Deng Zhao-Xiang;Li Chun-Hui;Sun Xiao-Ming;Zhuang Jing;Li Ya-Dong.Synthesis and Photoluminescent Properties of CdS/SiO2 Nanorod[J]. Acta Phys. -Chim. Sin., 2002,18(05): 477-480
106. Fang Yun;Liu Xue-Feng;Xia Yong-Mei;Yang Yang;Cai Kun;Suh Jung-Mok;Cho Heon-Young.Determination of Critical Micellar Aggregation Numbers by Steadystate Fluorescence Probe Method[J]. Acta Phys. -Chim. Sin., 2001,17(09): 828-831
107. Fu Xu-Chun, Yu Qing-Sen, Liang Wen-Quan.Calculation of Hydrogen-Bond Basicity by Artificial Neural Network Method[J]. Acta Phys. -Chim. Sin., 2000,16(09): 844-849
108. Shi Tu-Jin, Liu Li, Yang Da-Lin, Zhu Qi-He.Ab initio Study on Hydrogen Bonding Clusters between 1,4-dioxane and Ammonia[J]. Acta Phys. -Chim. Sin., 2000,16(05): 416-421
109. Zhang Lian-Qi, Zhang Bao-Wen, Cao Yi.A Study on Photophysical Behavior of 1,3-diphenyl-5-(2)-pyrenyl-2-pyrazoline[J]. Acta Phys. -Chim. Sin., 1999,15(10): 911-917
110. Feng Hai-Yan, Liu Xiao-Di, He Shu-Mei, Wu Ke-Zhong, Zhang Jian-Ling.Studies on Solid-Solid Phase Transition of Polyols and their Binary Mixtures by Infrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 1999,15(09): 850-855
111. Zhou Ping, OU Yang-Zhi-Xun, Meng Qing-An.The Second Sphere Interaction in the Supramolecular Complexes Studiey by 59Co Solid Static NMR[J]. Acta Phys. -Chim. Sin., 1999,15(06): 533-540
112. Shi Xiang-Yang, Wu Shi-Kang.A Study on the Micellar Polarity of Hydrophobic Poly(N-isopropylacrylmides)[J]. Acta Phys. -Chim. Sin., 1999,15(02): 127-132
113. Wang Yi-Xuan, Li Hong-Ping, Wang Jin-Ben, Zhang Fu-Qiang, Zhao Jian-Ping, Dai Ming.Infrared Spectroscopic Studies of Interactions of the Diols with Aprotic Solvents[J]. Acta Phys. -Chim. Sin., 1998,14(06): 514-519
114. Zhu Ai-Ping, Wu Shi-Kang.The Fluoresence Behavior of 4-(N,N-dimethylaminostryl) Coumarin in Different Solvent[J]. Acta Phys. -Chim. Sin., 1998,14(06): 552-556
115. Chen Shun-Qing, Yang Ya-Hong.The Fluorescence Studies of a Hydrophobically Modified Polyelectrolytes[J]. Acta Phys. -Chim. Sin., 1998,14(04): 380-384
116. Zhang De-Chun, Zhang Yan-Qiu, Lu Cheng-Rong.Resonance-Assisted Intramolecular Hydrogen Bonding in Substituted Phenols[J]. Acta Phys. -Chim. Sin., 1998,14(01): 63-67
117. Zhang Chang-Shuan,Jiang Hong,Li Jie,Li Tie-Jin.The Study to the Energy Migration between Anthraquinone and Rare-earth Ion[J]. Acta Phys. -Chim. Sin., 1997,13(04): 370-375
118. Chen Wen-Wu,Gao Yi-Qin,Wu Guo-Sheng,Yang Da-Lin,Sheng Liu-Si,Wu Guo-Hua,Ye Wei-Q.The Study of the 6-H Pyridine Clusters[J]. Acta Phys. -Chim. Sin., 1996,12(12): 1067-1070
119. Zou Shou-Zhong,Chen Yan-Xia,Tian Zhong-Qun,Zhang Yun-Hong.Studies on the Effects of Inorganic Ions and their Concentrations on Raman Spectra of Water[J]. Acta Phys. -Chim. Sin., 1996,12(02): 130-135
120. Gu Xin-Hua,Dai Guang-Song,Wu Shi-Kang.A Study on the Properties of Micelle Formed by Ethyleneoxide-Propyleneoxide Copolymer with Fluorescent Probe Method[J]. Acta Phys. -Chim. Sin., 1995,11(11): 985-990
121. He Xu,Gu Xin-Hua,Zhao Guo-Xi,Dai Guang-Song,Wu Shi-Kang.Fluorescence Method for Studying the Fusion of Vesicle[J]. Acta Phys. -Chim. Sin., 1995,11(06): 504-508
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123. Jiang Yun-Bao, Wang Xiu-Juan.Cyclodextrin Induced Micelle Formation as Studied by TICT Fluorescent Probe[J]. Acta Phys. -Chim. Sin., 1994,10(08): 716-719
124. Jiang Yong-Cai, Wu Shi-Kang.The Effect of Additives on the Premicell Formation in Different Surfactant Solutions[J]. Acta Phys. -Chim. Sin., 1994,10(04): 381-384
125. Lin Hua-Kuan, Lu Xiang-Sheng, Gu Zong-Xin, Li Wei-Hong, Chen Rong-Ti.Calorimetric Study of Ni(II), Co(II), Zn(II)-N-(para-cubstitutd Pheny1) Iminodiacetic Acid[J]. Acta Phys. -Chim. Sin., 1994,10(03): 212-216
126. Huang Jian-Bin; Zhao Guo-Xi; Jiang Yong-Cai; Wu Shi-Kang.Fluorescence Probe Study on the Self-organized Assemblies of the Mixed Catanionic Surfactants[J]. Acta Phys. -Chim. Sin., 1993,9(05): 577-580
127. Jiang Yun-Bao; Xu Jin-Gou.Behavior of Quenching of Pyrene Fluorescence by Alkylbenzylammonium in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 1992,8(05): 697-701
128. Wang Jin-Ben; Wang Yi-Xuan; Zhang Fu-Qiang; Zhao Jian-Ping; Dai Ming.A Study on Association of Amine With Several Solutes by Infrared Spectrometry[J]. Acta Phys. -Chim. Sin., 1992,8(04): 481-486
129. Huang Rong-Bin; Zheng Lan-Sun; Zhu Yong-Bao; Zhang Qian-Er.Generation of a New Type of Borane Anions with Laser Ablation[J]. Acta Phys. -Chim. Sin., 1992,8(04): 438-440
130. Xu Jian-He; Sun Xian-Da; Lu Wei-Qin; Gao Hong-Jin.Study of Hydrogen Bond Association of Alcohol Molecules in Alkanes by IR Quantitative Analysis[J]. Acta Phys. -Chim. Sin., 1992,8(03): 358-363
131. Wang Peng-Fei; Wu Shi-Kang.The Spectra and Photophysics of the Intramolecular Charge Transfer Compound[J]. Acta Phys. -Chim. Sin., 1992,8(03): 405-409
132. Wu Jiong-Ru; Tian Yong-Chi; Liang Ying-Qiu.Phase Transition of Sodium Dodecyl Sulfate-Water System: Probing by Pyrene Fluorescence[J]. Acta Phys. -Chim. Sin., 1991,7(03): 329-332
133. LIU Shan-Shan, JI Shan, CHEN Qi-Bin, PENG Chang-Jun, LIU Hong-Lai.Surface Patterning and Force-induced Reversible Structure Transformation of Supramolecular Polymer Brush PVP-Chol[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
134. WANG Yun-He, QIN Yuan, YAO Man, WANG Xu-Dong, LI Shu-Ying, WANG Dong, CHEN Ting.Molecular Dynamics Simulation of Chiral Self-assembly Structure on HOPG Surface Driven by Hydrogen Bonds for BIC and HA Systems[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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