Acta Phys. -Chim. Sin. ›› 1995, Vol. 11 ›› Issue (04): 375-380.doi: 10.3866/PKU.WHXB19950418

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Research on Electron Transfer in Phosphorylated Peptide by ESR

Wang Zhi-Yong, Zhang Zhi-Cheng| Zhang Man-Wei, Yao Si-De, Tu Tie-Cheng, Lin Nian-Yun, Zhang Qi-Jin   

  1. Department of Chemical Physics,University of Science and Technology of China,Hefei 230026|Laboratory of Radiation Chemistry,Shanghai Institute of Nuclear Research,Shanghai 201800|Department of Material Science and Engineering,University of Science and Technology of China,Hefei 230026
  • Received:1994-01-25 Revised:1994-07-27 Published:1995-04-15
  • Contact: Wang Zhi-Yong

Abstract:

Electron transfer (ET) is an important elementary step of chemical reaction. Phosphorus is the center of energy expression in biological system. As a result, the research on the ET of phosphoryl and nonphosphoryl peptides is very important for us to understand the role of phosphorus in life and reveal the secrets of life. In this paper, the ET in some phosphoryl and nonphosphoryl peptides  are studied by ESR. It is observed that the electron transfers along the backbone of the peptide and that phosphoryl group takes part in the elementary process in the phosphoryl peptide first.

Key words: Phosphorylated peptide, Electron transfer, ESR