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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2003,Vol.19>> Issue(01)>> 65-69     doi: 10.3866/PKU.WHXB20030115         中文摘要
Study on Rh-ZnO/MWNTs Catalyst for Methanol Synthesis
Wang Jin;Chen Hong-Bo;Yun Hong;Lin Jing-Dong;Yi Jun;Zhang Hong-Bin;Liao Dai-Wei
Department of Chemistry, 2State Key Laboratory for Physical Chemistry of Solid Surfaces, 3Institute of Physical Chemistry, 4Department of Ocean, Xiamen University, Xiamen 361005
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A novel catalyst for methanol synthesis, ZnO-promoted rhodium supported on multi-wall carbon nanotubes (MWNTs), was developed. As Rh content in catalyst is 4%(w), the catalyst has higher specific surfafic area of 99.6 m2•g-1 and activation energy of 68.8 kJ•mol-1. The highest catalytic activity of CH3OH, 411.4 mg /g cat•h, can be obtained at 563 K and under 1 Mpa (Table 1). The results of TEM, TPR and TPD showed that MWNTs can enhance the dispersion degree of Rh on the catalyst surface, increase the reduction temperature of the catalyst and the adsorption capacity of hydrogen species. These results will contribute to a better understanding of the synthergistic action of reaction components and the nature of catalytic activity center in the catalyst.

Keywords: Methanol synthesis   Rh catalyst   Multi-wall carbon nanotubes (MWNTs)    Hydrogen storing  
Received: 2002-04-02 Accepted: 2002-08-06 Publication Date (Web): 2003-01-15
Corresponding Authors: Chen Hong-Bo Email: hbchen@jingxian.xmu.edu.cn


Cite this article: Wang Jin;Chen Hong-Bo;Yun Hong;Lin Jing-Dong;Yi Jun;Zhang Hong-Bin;Liao Dai-Wei. Study on Rh-ZnO/MWNTs Catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2003,19 (01): 65-69.    doi: 10.3866/PKU.WHXB20030115
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100. Wang Zun-Yao;Xiao He-Ming;Li Jin-Shan.Mechanism of the Reactions F+Cl2->ClF +Cl and Cl′F+Cl->Cl′+ClF[J]. Acta Phys. -Chim. Sin., 2001,17(02): 107-110
101. Chen Bo-Zhen, Huang Ming-Bao, Su Hong-Mei, Kong Fan-Ao.Mechanism of the CH2+O2 Reaction[J]. Acta Phys. -Chim. Sin., 2000,16(10): 869-872
102. Cai Xiao-Ping, Fang De-Cai, Fu Xiao-Yuan.Reaction Mechanism of CIONO2 and O(3P)[J]. Acta Phys. -Chim. Sin., 2000,16(08): 689-693
103. Zhao Zhen-Bo, Sun Wen-Dong, Yang Xiang-Guang, Ye Xing-Kai, Wu Yue.Active Components and Mechanism of Isobutane Alkylation with Butenes in the Catalytic System of HPAs+AcOH[J]. Acta Phys. -Chim. Sin., 2000,16(07): 613-620
104. Kuang Ping-Xian, Chen Bo-Zhen, Huang Ming-Bao.Mechanism of the C(3P)H2S Reaction[J]. Acta Phys. -Chim. Sin., 2000,16(05): 389-392
105. Wu Peng, He Shao-Ren.Theoretical Study on the Mechanism of [2+2] Cycloaddition of Ketenimine with Imine[J]. Acta Phys. -Chim. Sin., 2000,16(03): 243-247
106. Meng Ling-Peng, Zheng Shi-Jun, Cai Xin-Hua.Theoretical Studies in the Reaction of Atomic O(3P) with CS2[J]. Acta Phys. -Chim. Sin., 1999,15(11): 990-996
107. Liu Dan, Chen Guang-Ju, Liu Ruo-Zhuang, Fu Xiao-Yuan.Exploration of the Mechanism of 2-bromoacetic Acid Gas-phase Elimination Process[J]. Acta Phys. -Chim. Sin., 1999,15(10): 872-876
108. Chen Tong, Li Wen-Zhao, Yu Chun-Ying.Investigation of the Interaction between NiO and Support,γ-Al2O3,for Oxidative Dehydrogenation of Ethane[J]. Acta Phys. -Chim. Sin., 1999,15(07): 613-618
109. Zhou Zhi-Gang, Dai Qian-Huan.Theoretical Study for the Mechanism of Electrophilic Addition to Alkenes Reactions[J]. Acta Phys. -Chim. Sin., 1999,15(06): 500-505
110. Wu Gui-Sheng, Ren Jie, Sun Yu-Han.The Effect of Calcination Temperature on The Performance of Cu/ZrO2 and Cu-La2O3/ZrO2[J]. Acta Phys. -Chim. Sin., 1999,15(06): 564-567
111. Shi Tu-Jin, Li Zong-He, Liu Ruo-Zhuang.Mechanism of Reaction HNCO+OH->H2O+NCO[J]. Acta Phys. -Chim. Sin., 1999,15(03): 247-252
112. Feng Hai-Xia, Zhu Zhi-Ang, Wang Chuan-Zhong, Ruan Wen-Juan, Li Ying, Chen Rong-Ti.Kinetics on the Axial Coordination Reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol[J]. Acta Phys. -Chim. Sin., 1999,15(02): 167-172
113. Wang Yan, Fang De-Cai, Fu Xiao-Yuan.Theoretical Studies on the Mechanism of Dimerization Reactions of Thioketene[J]. Acta Phys. -Chim. Sin., 1999,15(01): 35-39
114. Hu Hai-Quan, Liu Cheng-Bu.The Reaction Mechanism of the Biradical CF2 and O3[J]. Acta Phys. -Chim. Sin., 1998,14(12): 1104-1107
115. Xu Si-Chuan, Zhao Xin-Sheng.Investigation of the Reaction of Chlorine Nitrate on lce Surface[J]. Acta Phys. -Chim. Sin., 1998,14(11): 988-994
116. Chen Hong-Bo, Yu La-Jia, Liao Dai-Wei, Lin Guo-Dong, Zhang Hong-Bin, Cai Qi-Rui.The Effect of Cr2O3 over Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(06): 534-539
117. Zhang Guo-Dong.Study on the Reaction Rate and Mechanism of Ni-P Electroless Plating[J]. Acta Phys. -Chim. Sin., 1998,14(05): 429-434
118. Wang Gui-Chang, Sun Yu-Han, Zhong Bing.Simulation to the Structure Sensitive of Cu Based catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(04): 337-342
119. Xu Si-Chuan, Zhao Xin-Sheng.Reaction Mechanism of Chlorine Nitrate with HCl on lce Surface[J]. Acta Phys. -Chim. Sin., 1998,14(01): 5-7
120. Qian Ying,Wang Yan,Feng Wen-Lin,Liu Ruo-Zhuang.Theoretical Calculation on the Canonical Rate Constants for the Addition Reaction of 1,3-cyclohexa-diene with Propylene[J]. Acta Phys. -Chim. Sin., 1997,13(12): 1084-1089
121. Song Wei-Ping,Fu Xiao-Yuan,He Shao-Ren.Theoretical Studies on the Mechanism of Chloro-carboxylic Acids Gas-phase Elimination Process[J]. Acta Phys. -Chim. Sin., 1997,13(10): 908-915
122. Wang Zhi-Xiang,Huang Ming-Bao,Liu Ruo-Zhuang.Ab initio Study on the Reaction of CH Radical with O2[J]. Acta Phys. -Chim. Sin., 1997,13(05): 385-388
123. Ruan Wen-Juan,Zhu Zhi-Ang,Lin Hua-Kuan,Chen Zheng-Hua,Chen Hong-Wei,Yang Xiu-Lin.Kinetic Studies on the Formation Reaction of Zinc(II)、Cadmium(II) and Mercury(II) with Porphyrins[J]. Acta Phys. -Chim. Sin., 1997,13(04): 335-343
124. Sheng Ying-Hong,Fang De-Cai,Fu Xiao-Yuan.Theoretical Study on the Mechanism of the Cycloaddition Reactions Between Methyleneketene and 5-methylene-1,3-dioxan-4,6-dione[J]. Acta Phys. -Chim. Sin., 1996,12(06): 496-501
125. Pang Xian-Yong,Feng Wen-Lin,Wang Yan,Zhang Shao-Wen.Theoretical Study on the Singlet-state and the Triplet-state Mechanisms for the Reaction CH3O with NO[J]. Acta Phys. -Chim. Sin., 1996,12(05): 391-395
126. Zhu Zhi-Ang, Yan Xi, Zhang Zhi-Hui, Ma Gang, Lin Hua-Kuan, Chen Rong-Ti.Thermodynamics and Kinetics of Coordination Reaction of Imidazolates with Cobalt(II) Porphyrin[J]. Acta Phys. -Chim. Sin., 1996,12(04): 372-376
127. Kang Qing-Hua,Zhong Shun-He.Mechanism of Laser Stimulated Surface Reaction of Ethanol Oxidative Coupling to 1,4-Butanediol[J]. Acta Phys. -Chim. Sin., 1995,11(06): 498-503
128. Li Qing-Shui, Lin Yu-Qin, Liao Yuan-Yan.Studies on Catalytic Dehydrogenation of Methanol to Formaldehyde[J]. Acta Phys. -Chim. Sin., 1995,11(05): 442-446
129. Xu Zhi-Jin,Yan Ji-Min.Investigation on the Reaction Barriers of He+C60↔(He@C60)[J]. Acta Phys. -Chim. Sin., 1995,11(04): 346-350
130. Zhang Lin-Yang,Zhang Jia-Mu,W.Fuss.The Effect of Light Intensity on the Photoinduced BrC2F4Br+C2F4 Telomerization Reaction[J]. Acta Phys. -Chim. Sin., 1995,11(04): 308-314
131. Ruan Wen-Juan, Zhu Zhi-Ang, Huang Xiao-Qun, Chen Rong-Ti, Jiang Dong-Qing.Kinetic Study on Porphinatoiron(III) Catalyzing Decomposition of β-Carotene[J]. Acta Phys. -Chim. Sin., 1994,10(04): 312-318
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133. Zhu Zhi-Ang; Huang Xiao-Qun; Chen Rong-Ti.Kinetic Study of the Electrophilic Substitution Reaction of Copper ion with Meso-tetrakis (Meta-methylphenyl) Porphyrin Cadmium (II)[J]. Acta Phys. -Chim. Sin., 1993,9(05): 635-641
134. Jiang Xiong.An Investigation on the Cathodic Reduction of Co2+ Ions[J]. Acta Phys. -Chim. Sin., 1993,9(01): 129-133
135. Yang Song-Qing; Jiang Han-Ying.Electrochemical Studies on Pyrite[J]. Acta Phys. -Chim. Sin., 1991,7(06): 735-739
136. Dai Jian-Bo; Bai Ling-Jun; Zhang Yi-Bao; Zang Ya-Ru; Jiang Dong-Qing; Gu Zhuo-Ying; Zhao Xue-Zhuang.Research on the Oxidation of Adrenaline——Kinetics and Mechanism of the Oxidation Reaction and the Radical Intermidate[J]. Acta Phys. -Chim. Sin., 1991,7(03): 260-269
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