Acta Phys. -Chim. Sin. ›› 2003, Vol. 19 ›› Issue (10): 957-961.doi: 10.3866/PKU.WHXB20031015

• ARTICLE • Previous Articles     Next Articles

A New Mechanism Model for BR Oscillating Reaction System

Chu Xiao-Zhong;He Zhan-Bo;Zhang Feng-Cai   

  1. Department of Chemistry, School of Science, Tianjin University, Tianjin 300072
  • Received:2003-04-26 Revised:2003-07-14 Published:2003-10-15
  • Contact: He Zhan-Bo E-mail:zbhe@eyou.com

Abstract: Many features and disadvantages of reaction mechanisms and models suggested for BR (Briggs-Rauscher) oscillatory system are summarized briefly in this paper. Moreover, a simplified model for a nine-step reaction mechanism is proposed which can simulate concentration variations of the following four species HIO2, I2, I- and O2.The model exhibits periodic oscillatory behavior in a wide range of initial concentrations of inflow species, and can be used to elucidate some special experimental phenomena. Additionally, limit cycle and bistabilty are observed in this model.

Key words: BR oscillatory reaction, Mechanism, Model, Limit cycle, Bistability