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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2005,Vol.21>> Issue(02)>> 225-228     doi: 10.3866/PKU.WHXB20050224         中文摘要
A Study of CO2/H2 Adsorption on Zirconia Polymorphs
MA Zhong-Yi;YANG Cheng;DONG Qing-Nian;WEI Wei;LI Wen-Huai;SUN Yu-Han
StateKeyLaboratoryofCoalConversion,InstituteofCoalChemistry,ChineseAcademyofSciences,Taiyuan 030001;GraduateSchoolofChineseAcademyofSciences,Beijing 100039
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The adsorption behaviors of CO2 and CO2+H2 on zirconia polymorphs were investigated by FT-IR technique. The results showed that absorbed CO2 and surface intermediates varied with zirconia polymorphs. Bicarbonate and ion carbonate species were detected on amorphous zirconia. In addition to the two species, bidented carbonate was also formed on monoclinic zirconia. The strongest adsorbed CO2 and polydentate carbonate species were found on tetragonal zirconia. In the case of CO2 hydrogenation, methane was formed on monoclinic zirconia while formate species was observed on tetragonal zirconia.

Keywords: Zirconia   FT-IR   CO2 adsorption   CO2+H2  
Received: 2004-08-04 Accepted: 2004-09-28 Publication Date (Web): 2005-02-15
Corresponding Authors: SUN Yu-Han Email: yhsun@sxicc.ac.cn


Cite this article: MA Zhong-Yi;YANG Cheng;DONG Qing-Nian;WEI Wei;LI Wen-Huai;SUN Yu-Han. A Study of CO2/H2 Adsorption on Zirconia Polymorphs[J]. Acta Phys. -Chim. Sin., 2005,21 (02): 225-228.    doi: 10.3866/PKU.WHXB20050224
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