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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2005,Vol.21>> Issue(03)>> 338-342     doi: 10.3866/PKU.WHXB20050323         中文摘要
Electrochemical Properties of a V2O5/C Composite in Aqueous Solution Used for Zinc Secondary Battery
TAO Bin-Wu;LIU Jian-Hua;LI Song-Mei;ZHAO Liang
School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083
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A composite of vanadium pentoxide/carbon was prepared by sol-gel method. By using scanning electronic microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR), it was found that the composite was composed of porous particles. Inner part of the composite was carbon particles, which covered by an outer layer of vanadium pentoxide sol. The electrochemical properties of the composite as cathode material in aqueous solution for zinc secondary battery were studied by using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). When the mass ratio of V2O5/C was 1:1,the composite electrode showed good electrochemical properties: open circuit potential of its battery reached 1.64 V; zinc ions were reversibly intercalated into the composite electrode in site A at 1.26 V and site B at 1.01 V, with a highest intercalation rate 70 mA•g-1; cycling performance of the composite electrode was quite good in a test of 20 charge-discharge cycles. The reaction process of V2O5/C composite electrode was controlled by the diffusion rate of zinc ions in V2O5.

Keywords: Zinc secondary battery   Cathode material   Vanadium pentoxide    Intercalation   Electrochemical properties  
Received: 2004-09-24 Accepted: 2004-10-21 Publication Date (Web): 2005-03-15
Corresponding Authors: LIU Jian-Hua Email: liujh@buaa.edu.cn


Cite this article: TAO Bin-Wu;LIU Jian-Hua;LI Song-Mei;ZHAO Liang. Electrochemical Properties of a V2O5/C Composite in Aqueous Solution Used for Zinc Secondary Battery[J]. Acta Phys. -Chim. Sin., 2005,21 (03): 338-342.    doi: 10.3866/PKU.WHXB20050323
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86. JIA Yan-Min; LIU Fei-Ye; XIAO Xue-Zhang; HANG Zhou-Ming; LEI Yong-Quan; CHEN Li-Xin.Microstructure and Electrochemical Properties of V2.1TiNi0.4Zr0.06Cu0.03M0.10 (M=Cr, Co, Fe, Nb, Ta) Hydrogen Storage Alloys[J]. Acta Phys. -Chim. Sin., 2009,25(02): 247-252
87. ZHANG Wei; CUI Xiao-Li; JIANG Zhi-Yu.Effect of Composite Modes on Photoelectrochemical Properties of MWCNTs/TiO2 Nanocomposite Films[J]. Acta Phys. -Chim. Sin., 2008,24(11): 1975-1980
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