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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2005,Vol.21>> Issue(05)>> 565-568     doi: 10.3866/PKU.WHXB20050521         中文摘要
Microstructure and Electrochemical Properties of Amorphous Mg-Fe-Ni Hydrogen Storage Electrode Material
XIAO Xue-Zhang; CHEN Chang-Pin; WANG Xin-Hua; CHEN Li-Xin; WANG Li; GAO Lin-Hui
College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou    310027
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The amorphous Mg-Fe-Ni composites have been synthesized by mechanical ball-milling. The microstructure and electrochemical properties of the composites were characterized by XRD, SEM and electrochemical testing. The electrochemical properties of the composites vary greatly with the amount of Mg content and Ni introduced. For the (xMg+Fe)+200% (mass fraction) Ni (x=2, 3) composites, it is found that the maximal discharge capacity increases with increasing Mg content in the composites. The maximal discharge capacities of the composites with x=2, 3 were 391.9 mA•h•g-1 and 480.8 mA•h•g-1, respectively. The result also indicates that, for the ball-milled (3Mg+Fe)+y% Ni (y=50, 100, 200) composites, with increasing Ni content in the composites, the discharge capacity increases first and then decreases, and reaches a maximum value of 519.5 mA•h•g-1 as y=100. In contrast, the discharge capacity of nickel-free (3Mg+Fe) composite is just 23.8 mA•h•g-1. The microstructure analysis shows that the composites are mix structure composed two single phases with Mg and Fe for the nickel-free composite even after being milled for 120 h, but no new phase is formed. The composites milled with the addition of nickel powder could easily form Mg-Fe amorphous structure. Besides, the nickel powder in the composites plays a role of electro-catalysis, hereby the electrochemical properties of the Mg-Fe-Ni composites are effectively improved.

Keywords: Hydrogen storage electrode material   Mechanical alloying   Amorphous   Electrochemical properties   Microstructure  
Received: 2004-10-08 Accepted: 2004-12-02 Publication Date (Web): 2005-05-15
Corresponding Authors: CHEN Chang-Pin Email: cpchen@zju.edu.cn


Cite this article: XIAO Xue-Zhang; CHEN Chang-Pin; WANG Xin-Hua; CHEN Li-Xin; WANG Li; GAO Lin-Hui. Microstructure and Electrochemical Properties of Amorphous Mg-Fe-Ni Hydrogen Storage Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21 (05): 565-568.    doi: 10.3866/PKU.WHXB20050521
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