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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 1996,Vol.12>> Issue(05)>> 423-428     doi: 10.3866/PKU.WHXB19960508         中文摘要
A Mechanism Study of Sensitized Photoisomerization of Norbornadiene Derivatives
Wang Xue-Song,Zhang Bao-Wen,Cao Yi
Laboratory of Photochemistry,Institute of Photographic Chemistry,The Chinese Academy of Sciences,Beijing 100101
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The photoinduced valence isomerizations of three kinds of norbornadiene derivatives were performed under the sensitization of N-methylcarbazole. Fluoresecence quenching, chemically induced dynamic nuclear polarization (CIDNP) and thermodynamic discussion all support a mechanism involving electron transfer. The calculation of quantum yields indicates that the singlet electron transfer makes far more contributions to the photoisomerization than the triplet energy transfer. Additionally, the influence of solvent polarity on the photoisomerizations was also discussed.



Keywords: Norbornadiene derivatives   N-methylcarbazole   Photoinduced valence isomerization   Electron transfer   Energy transfer   Effect of solvent polarity  
Received: 1995-10-09 Accepted: 1995-12-13 Publication Date (Web): 1996-05-15
Corresponding Authors: Cao Yi Email:


Cite this article: Wang Xue-Song,Zhang Bao-Wen,Cao Yi. A Mechanism Study of Sensitized Photoisomerization of Norbornadiene Derivatives[J]. Acta Phys. -Chim. Sin., 1996,12 (05): 423-428.    doi: 10.3866/PKU.WHXB19960508
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