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Acta Physico-Chimica Sinica  1996, Vol. 12 Issue (04): 329-336    DOI: 10.3866/PKU.WHXB19960409
Article     
The Photoisomerization of Azobenzene for Regulating the Complex Behavior of Viologen with Eosin
Liu Tian-Jun,Wu Shi-Kang
Institute of Photographic Chemistry,Academia Sinica,Beijing 100101
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Abstract  

 In this paper, the synthesis of α, ω-azobenzen, viologen bichromophore long chain compounds, and the study on their photochemical and photophysical properties have been reported. The results indicated that the photoisomerization of azobenzene could regulat the constant of complexation between the viologen and eosin, and the photoregulating effect is correlated strongly with the length of the polymethylene spacer between two chromophores. Based on the spectra data of 1H NMR, the conformation effect has also been discussed and explained preliminarily.



Key wordsPhotoisomerization      Photoregulation      Photochemical molecular devices      Azobenzene      Eosin      Viologen     
Received: 31 August 1995      Published: 15 April 1996
Corresponding Authors: Wu Shi-Kang   
Cite this article:

Liu Tian-Jun,Wu Shi-Kang. The Photoisomerization of Azobenzene for Regulating the Complex Behavior of Viologen with Eosin. Acta Physico-Chimica Sinica, 1996, 12(04): 329-336.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB19960409     OR     http://www.whxb.pku.edu.cn/Y1996/V12/I04/329

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