Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 1996,Vol.12>> Issue(04)>> 329-336     doi: 10.3866/PKU.WHXB19960409         中文摘要
The Photoisomerization of Azobenzene for Regulating the Complex Behavior of Viologen with Eosin
Liu Tian-Jun,Wu Shi-Kang
Institute of Photographic Chemistry,Academia Sinica,Beijing 100101
Full text: PDF (1405KB) HTML Export: BibTeX | EndNote (RIS)

 In this paper, the synthesis of α, ω-azobenzen, viologen bichromophore long chain compounds, and the study on their photochemical and photophysical properties have been reported. The results indicated that the photoisomerization of azobenzene could regulat the constant of complexation between the viologen and eosin, and the photoregulating effect is correlated strongly with the length of the polymethylene spacer between two chromophores. Based on the spectra data of 1H NMR, the conformation effect has also been discussed and explained preliminarily.



Keywords: Photoisomerization   Photoregulation   Photochemical molecular devices   Azobenzene   Eosin   Viologen  
Received: 1995-08-31 Accepted: 1995-11-23 Publication Date (Web): 1996-04-15
Corresponding Authors: Wu Shi-Kang Email:


Cite this article: Liu Tian-Jun,Wu Shi-Kang. The Photoisomerization of Azobenzene for Regulating the Complex Behavior of Viologen with Eosin[J]. Acta Phys. -Chim. Sin., 1996,12 (04): 329-336.    doi: 10.3866/PKU.WHXB19960409
1. LI Bo, LÜ Gong Xuan.Highly Active and Stable Catalyst for Visible Light Hydrogen Production Based on Oxidative Quenching of Eosin Y[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1778-1784
2. LUO Wen-Li, SU Ya-Qiong, TIAN Xiang-Dong, ZHAO Liu-Bin, WU De-Yin, TIAN Zhong-Qun.Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2767-2773
3. QIAO Yin-Po, ZHU Zhen-Feng, ZHANG Yan-Bin, LIU Dian-Guang, WANG Bing-Qing, ZHANG Zhi-Chun.Tunable White Emitting in Ternary Ce/Tb/Sm Codoped CaO-B2O3-SiO2 Glasses[J]. Acta Phys. -Chim. Sin., 2012,28(03): 706-710
4. ZHANG Xiao-Jie, TANG Chang-Qing, JIN Zhi-Liang, LV Gong-Xuan, LI Shu-Ben.Photocatalytic Reduction of Water to Hydrogen over Eosin Y/Pt/SiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1143-1148
5. JIANG Min, ZHANG Hong-Yu, ZHAO Xue-Bo.Effect of Alkyl Chain Length on the Structure of Viologen Adsorbed on a Cu(100) Electrode[J]. Acta Phys. -Chim. Sin., 2011,27(01): 163-168
6. WANG Luo-Xin, YI Chang-Hai, ZOU Han-Tao, XU Jie, XU Wei-Lin.cis-trans Isomerization of Azobenzene Confined inside an Armchair (8,8) Single-Walled Carbon Nanotube[J]. Acta Phys. -Chim. Sin., 2010,26(01): 149-154
7. ZHU Yue, PU Min, HE Jing, EVANS David G..Photoisomerization Mechanism of the Trans-cis Azobenzene Sulphonate Derivatives[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2296-2304
8. SONG Bing-Lei, ZHAO Jian-Xi.Adsorption of Photosensitive Quaternary Ammonium Gemini Surfactant a4-6-m at the Air/Water Interface[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2020-2025
9. LUO Shi-Xia; ZHANG Xiao-Yi; ZHANG Si-Ting; ZHU Huai-Wu; HU Ji-Wei; WEI Gang.Influence of Substituents on Electron Transport through the Single-Molecule Mercapto-Azobenzene[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1471-1476
10. Wu Guo-Hua, Sheng Liu-Si, Zhang Yun-Wu, Gao Hui, Chen Zu-Yao.Photoionization and Photodissociative lonization of Azoxybenzene(C12H10N2O) by Vacuum Ultraviolet Synchrotron Radiation (SR)[J]. Acta Phys. -Chim. Sin., 2000,16(10): 948-951
11. Sun Jian, Liu Yang, Chen De-Wen, Zhang Qi-Yuan.Catalysis of Methyl Viologen in the Reaction between C60 and Et3N[J]. Acta Phys. -Chim. Sin., 1999,15(12): 1088-1091
12. Wu Guo-Hua, Sheng Liu-Si, Gao Hui, Zhang Yun-Wu.Studies on p-aminoazobenzene(C12H11N3)Using Photoionization Mass Spectrum with Synchrotron Radiation(SR)[J]. Acta Phys. -Chim. Sin., 1999,15(09): 860-864
13. Wang Zhen, Zhang Hao-Li, Li Hu-Lin.Self-assembly Behavior of Azobenzene Derivative β-Cyclodextrin Inclusion Complex on Gold[J]. Acta Phys. -Chim. Sin., 1999,15(07): 606-612
14. Li Hai-Ying, Zhang Hao-Li, Zhang Jin, Liu Zhong-Fan.Preparation and Structural Characterization of Self-assembled Monolayers from a New Series of Mercapto Contained Azobenzene Derivatives[J]. Acta Phys. -Chim. Sin., 1999,15(03): 198-203
15. Shao Hui-Bo, Yu Hua-Zhong, Cheng Guang-Jun, Zhang Hao-Li, Liu Zhong-Fan.Study of the Formation Process of an Azobenzene Self-assembled Monolayer on Gold Surface[J]. Acta Phys. -Chim. Sin., 1998,14(09): 846-851
16. Shao Hui-Bo, Yu Hua-Zhong, Zhang Hao-Li, Luo Ying, Cheng Guang-Jun, Liu Zhong-Fan.State of the Tunneling Mechanism for Long Range Electron Transfer in Azobenzene Self-assembled Monolayers[J]. Acta Phys. -Chim. Sin., 1998,14(09): 772-777
17. Zhang Jin,Zhao Jiang,Zhang Hao-Li,Liu Zhong-Fan,Li Hu-Lin.Influence of End Alkyl Chain Length on the Structure of Self-assembled Monolayer of Azobenzene on Gold[J]. Acta Phys. -Chim. Sin., 1997,13(10): 868-872
18. Li Jing-Hong,Cheng Guang-Jin,Dong Shao-Jun.Electrochemical Study of the Self-exchange between Viologen-thiol Self-assembled Monolayers and Alkanethiol on Gold Electrodes[J]. Acta Phys. -Chim. Sin., 1997,13(07): 655-658
19. Zhang Hao-Li,Zhang Jin,Zhao Jiang,Wang Yong-Qiang,She Jin,Yu Hua-Zhong,Li Hu-Lin.New Approach on the Synthesis of Functionalized Alkanethiols and the Structural Characterization of Their Self-Assembled Monolayers[J]. Acta Phys. -Chim. Sin., 1997,13(06): 515-524
20. Zhao Jian-Wei,Yu Hua-Zhong,Wang Yong-Qiang,Zhang Hao-Li,Liu Z.Structure-Dependent Electron Transfer Kinetics of Azobenzene Self-Assembled Monolayers on Gold[J]. Acta Phys. -Chim. Sin., 1997,13(01): 42-47
21. Zhao Jian-Wei,Yu Hua-Zhong,Wang Yong-Qiang,Tang Ming,Cai Sheng-Min,Liu Zhong-Fan.The Adsorption Kinetics and Characterization of Azobenzene Self-Assembled Monolayers on Gold[J]. Acta Phys. -Chim. Sin., 1996,12(07): 581-588
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top