Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2009,Vol.25>> Issue(05)>> 999-1003     doi: 10.3866/PKU.WHXB20090415         中文摘要
Effect of Specific Adsorption of Anions and Surface Structure of Pt(111) Electrode on Kinetics of Dissociative Adsorption of Ethylene Glycol
FAN You-Jun, ZHEN Chun-Hua, CHEN Sheng-Pei, SUN Shi-Gang
College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, Guangxi Province, P. R. China; State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
Full text: PDF (230KB) HTML Export: BibTeX | EndNote (RIS)

The effect of specific adsorption of anions and the surface structure of a Pt(111) electrode on the kinetics of dissociative adsorption of ethylene glycol (EG) was studied using cyclic voltammetry and a programmed potential step technique. Quantitative results demonstrated that the specific adsorption of anions remarkably influenced the dissociative adsorption of EG. Both the initial reaction rate (vi) of the EG dissociative adsorption and the saturated coverage of dissociative adsorbates, measured in perchloric acid media (without specific adsorption), are significantly larger than the corresponding values acquired in sulfuric acid media (with specific adsorption of SO2-40/HSO-4). We illustrate that the variation of the average reaction rate v of EGdissociative adsorption on Pt(111) in perchloric acid media with an electrode potential yields a volcano-like distribution with a maximumvalue near 0.22 V (vs SCE). Furthermore, different surface structures of the Pt(111) electrode that were obtained by different treatments also significantly affect this surface process.



Keywords: Ethylene glycol   Dissociative adsorption   Pt(111) electrode   Specific adsorption   Surface structure   Surface reaction kinetics  
Received: 2008-11-17 Accepted: 2008-12-31 Publication Date (Web): 2009-02-18
Corresponding Authors: FAN You-Jun, SUN Shi-Gang Email: youjunfan@mailbox.gxnu.edu.cn; sgsun@xmu.edu.cn


Cite this article: FAN You-Jun, ZHEN Chun-Hua, CHEN Sheng-Pei, SUN Shi-Gang. Effect of Specific Adsorption of Anions and Surface Structure of Pt(111) Electrode on Kinetics of Dissociative Adsorption of Ethylene Glycol[J]. Acta Phys. -Chim. Sin., 2009,25 (05): 999-1003.    doi: 10.3866/PKU.WHXB20090415
1. QIU Song-Bai, WENG Yu-Jing, LIU Qi-Ying, MA Long-Long, ZHANG Qi, WANG Tie-Jun.Preparation of Highly Dispersed Co/SiO2 Catalyst Using Ethylene Glycol and Its Application in Vapor-Phase Hydrogenolysis of Ethyl Lactate to 1,2-Propanediol[J]. Acta Phys. -Chim. Sin., 2016,32(6): 1511-1518
2. YANG Fan, YU Peng-Yun, ZHAO Juan, ZHAO Yan, WANG Jian-Ping.Intermolecular Hydrogen Bonding Structural Dynamics in Ethylene Glycol by Femtosecond Nonlinear Infrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1275-1282
3. HU Li-Mei, LIN Cun-Guo, WANG Li, YUAN Shi-Ling.Lysozyme Protein Adsorbed on Antifouling Polymer Film Surface[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2149-2156
4. XU Jing, QIANG Jin-Feng, WANG Rui-Juan, NIU Wen-Jun, SHEN Ming.Controllable Preparation of Rambutan-Shape AlOOH/Al2O3 Nanomaterials with a Composite Soft Template[J]. Acta Phys. -Chim. Sin., 2013,29(10): 2286-2294
5. XIA Juan, SONG Le-Xin, DANG Zheng, SHAO Zhi-Cheng.Polyethylene Glycol/Fe3O4 Nanoparticle Composite Materials: Structure, Physical Properties and Application[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1524-1533
6. ZUO Xiang, CAI Feng, LIU Xiao-Min, YANG Hui, SHEN Xiao-Dong.Synthesis and Characterization of a Novel Physically Cross-Linked Gel Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2013,29(01): 64-72
7. LIANG Gui-Jie, ZHONG Zhi-Cheng, XU Jie, ZHANG Zeng-Chang, CHEN Mei-Hua, LI Zai-Fang, HE Ping, HOU Qiu-Fei.Quasi-Solid State Dye-Sensitized Solar Cells Based on the Novel Crosslinked Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2852-2860
8. ZHENG Hua-Rong, WANG Xiao-Wei, LIN Xia-Hui, GENG Qiang, CHEN Xun, DAI Wen-Xin, WANG Xu-Xu.Promoted Effect of Polyethylene Glycol on the Photo-Induced Hydrophilicity of TiO2 Films[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1764-1770
9. LIU Jing-Ru, XU Jie, DONG Hong-Chao, YU Qiang.Effect of Hyperbranched Polyester on the Non-Isothermal Crystallization Behavior of Polyethylene Glycol[J]. Acta Phys. -Chim. Sin., 2012,28(03): 528-535
10. YANG Xing-Ye, LI Bin, SUN Liang, HUANG Zhi-Wei, CHENG Xiao-Min, ZHANG Tao-Wei, TANG Xing-Fu.Effect of Surface Structure of α-Fe2O3 on the Selective Catalytic Reduction of NO by NH3[J]. Acta Phys. -Chim. Sin., 2012,28(01): 184-188
11. ZENG Chi, ZHU Jian-Yu.Microcalorimetric Study of the Influence of Extracellular NaCl Concentration on the Growth Metabolism of Halobacterium halobiumZENG Chi1,* ZHU Jian-Yu[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1525-1530
12. ZHOU Xiao-Ling, HUANG Rui-An, WU Zhao-Cong, YANG Bin, DAI Yong-Nian.Synthesis and Electrochemical Properties of High-Rate Spinel Li4Ti5Ol2/TiN Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3187-3192
13. ZHANG Ye, FAN Guang-Yin, WANG Lei, LI Rui-Xiang, CHEN Hua, LI Xian-Jun.Hydrogenation of Pyridine and Its Derivates Catalyzed by Poly(ethylene glycol)-Stabilized Amorphous RuB Nanoparticles[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2270-2274
14. WAN Li-Hua, YA Ke-Feng, LI Xiao-Sen, FAN Shuan-Shi.Molecular Dynamics Simulation of Methane Hydrate Dissociation Process in the Presence of Thermodynamic Inhibitor[J]. Acta Phys. -Chim. Sin., 2009,25(03): 486-494
15. WU Zhuang-Zhi; WANG De-Zhi; XU Bing.Preparation of Hollow MoS2 Microspheres by Addition of PEG as Template[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1927-1931
16. ZHANG Lan; ZHANG Shi-Chao.Preparation and Characterization of Poly(acrylonitrile-methoxy polyethylene glycol (350) monoacrylate-lithium acrylate)[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1943-1947
17. YI Jian-Hua; ZHAO Feng-Qi; XU Si-Yu; GAO Hong-Xu; HU Rong-Zu; HAO Hai-Xia; PEI Qing; GAO Yin.Nonisothermal Thermal Decomposition Reaction Kinetics of Double-base Propellant Catalyzed with Lanthanum Citrate[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1316-1320
18. YANG Su-Dong; ZHANG Xiao-Gang; HUANG Jian-Shu; SUN Jing-Yu.Pd-Ni/MWCNT Electrocatalysts for Ethylene Glycol Electro-oxidation in Alkaline Medium[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1224-1228
19. CHEN Jian; HUANG Zheng-Ren; DONG Shao-Ming; JIANG Dong-Liang.Adsorption of Polyethylene Glycol on Silicon Carbide Measured by Thermal Gravimetric and Differential Thermal Analysis[J]. Acta Phys. -Chim. Sin., 2007,23(06): 926-928
20. SUN Xi-Yuan; KONG Fan-Jie; JIANG Gang; ZHU Zheng-He.Thermodynamics of Water Adsorbed on Palladium Surface[J]. Acta Phys. -Chim. Sin., 2007,23(05): 651-654
21. ZONG Ye;WANG Yu;LIN Chang-Jian .Preparation and Characterization of a High Loading Nano PtRu/C Catalysts in DMFC[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1305-1309
22. WU Qiu-mei; RUAN Jian-ming; ZHOU Zhong-cheng; HUANG Bai-yun.Study on the Rheological Properties of Silica /Polyethylene Glycol Non-Newtonian Flow[J]. Acta Phys. -Chim. Sin., 2006,22(01): 48-52
23. ZHOU Xiao-shun; XU Xiaomi; ZHONG Hui-ping; LONG La-sheng; HUANG Rong-bin; XIE Zhao-xiong; ZHENG Lan-sun; MAO Bing-wei.Adsorption of Metal-Organic Complex Molecule on Au(111) Surface[J]. Acta Phys. -Chim. Sin., 2005,21(09): 949-951
24. QU Wei-li; WU Bing; SUN Fang; GAO Ying; LU Tian-hong; LIU Chang-peng; XING Wei.Electrocatalytic Oxidation of Ethylene Glycol at Pt-WO3/C Electrode[J]. Acta Phys. -Chim. Sin., 2005,21(07): 804-807
25. HOU Hai-yun; AN Xue-qin; SHEN Wei-guo.Tricritical Phenomena in Quasi-ternary Solutions of Water+Formamide+Cyclohexane+Diethylene Glycol Monobutyl Ether[J]. Acta Phys. -Chim. Sin., 2005,21(07): 813-816
26. TANG Tian-di; CHEN Jiu-ling; LI Yong-dan.Treatment of the Carbon Nanofiber Surfaces in Mixed Concentrated HNO3-H2SO4 and the Catalytic Activity of Supported Pd-Pt for Naphthalene Hydrogenation[J]. Acta Phys. -Chim. Sin., 2005,21(07): 730-734
27. MA Hui-ru; GUAN Jian-guo; LU Guo-jun; YUAN Run-zhang.The Preparation and Characterization of PAn-PEG-PAn Rod-coil Triblock Copolymers[J]. Acta Phys. -Chim. Sin., 2005,21(06): 627-631
28. Zhong Qi-Ling;Zhang Bin;Zhang Lei;Yang Xiong-Yuan;Huang Peng.In-situ SERS of Dissociative Adsorption and Oxidation of Ethanol on Roughed Platinum Electrodes[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1163-1166
29. Gao Cai;Wang Wen-Hua;Hu Tong-Ji;Xu Yi;Zhou Guo-Yan;Hua Ze-Zhao.Glass Transition and Enthalpy Relaxation Behavior of Ethylene Glycol and Its Aqueous Solution with Different Crystallinity[J]. Acta Phys. -Chim. Sin., 2004,20(07): 701-706
30. Fan You-Jun;Fan Chun-Jie;Zhen Chun-Hua;Chen Sheng-Pei;Sun Shi-Gang.Kinetics of Dissociative Adsorption of Ethylene Glycol on Pt(111) Electrode[J]. Acta Phys. -Chim. Sin., 2004,20(04): 382-385
31. Gao Cai;Zhou Guo-Yan;Xu Yi;Hua Ze-Zhao.Freezing Properties of EG and Glycerol Aqueous Solutions Studied by DSC[J]. Acta Phys. -Chim. Sin., 2004,20(02): 123-128
32. Liang Huan-Zhen;Kim Dong-Jin;Chung Hun S.;Zhang Jie;Yu Ke-Ning;Li Shao-Hua;Li Rui-Xing.Mechanism for the Formation of Flake Silver Powder Synthesized by Chemical Reduction in Ethylene Glycol[J]. Acta Phys. -Chim. Sin., 2003,19(02): 150-153
33. Wang Qin-Ping;Lü Dian-Zhen;Zhang Li;Sun Xue-Li;Yang Jia-Zhen.Thermodynamics of Mixed Electrolytes in Mixed Solvents of Glycol and Water[J]. Acta Phys. -Chim. Sin., 2003,19(02): 115-119
34. Sun Zhen-Fan;Li Yu-Guang.Surface Structural Morphology of TiO2 Nano-Films[J]. Acta Phys. -Chim. Sin., 2002,18(10): 896-900
35. Li Qi;Wen Xiao-Quan;Cai Xiao-Hai;Wang Xian-Rong;Xie You-Chang.Software BVStr for Analyzing the Structure of Crystal and Surface Based on the Bond Valence Theory[J]. Acta Phys. -Chim. Sin., 2002,18(06): 558-562
36. Lu An-Hui;Li Wen-Cui;Zheng Jing-Tang.Preparation of PANbased Molecular Sieve ACF and Study of Surface Structure by XPS[J]. Acta Phys. -Chim. Sin., 2001,17(03): 216-221
37. Zhong Shun-He, Gao Feng, Ye Xiu-Qiang, Xiao Xiu-Fen.Study on Laser Stimulated Surface Reaction of Methanol Oxidative Coupling[J]. Acta Phys. -Chim. Sin., 2000,16(07): 601-607
38. Wang Qing-Guo, Cai Li-Xing, Liu Bo, Li Guang-Ya, Hu Ping, Zhang Yu, Cheng Rong-Shi.Eluent Gel Permeation Chromatography Method for Study of Non-associated Multi-components Solution[J]. Acta Phys. -Chim. Sin., 1998,14(03): 267-269
39. Lu Jian-Li,Jiang Wen-Hua,Han Shi-Jun.Prediction of Compatibility for Polyethylene Glycol/Chitosan by Method of Viscometry[J]. Acta Phys. -Chim. Sin., 1997,13(04): 376-379
40. Wu Xiong,Su Ke-He.Calcuation on Cluster Models of SnO2(110) Surface[J]. Acta Phys. -Chim. Sin., 1996,12(04): 357-360
41. He Zhan-Bo,Huang Zhi,Gu Ti-Ren.The Effects of Polyethylene Glycol on Oscillating Reactions[J]. Acta Phys. -Chim. Sin., 1995,11(08): 741-745
42. Hu Yong-Ren,Zhang Lan-Xin,Xin Qin,Gao Xing-Tao,Ying Pin-Liang.Infrared Studies of the Surface Structure of Commercial Pt-Re/Al2O3 Reforming Catalyst[J]. Acta Phys. -Chim. Sin., 1995,11(07): 636-641
43. Sun Shi-Gang, Lu Guo-Qiang.Kinetics and Time Resolved FTIR Spectroscopic Characters of Dissociative Adsorption of HCOOH on Pt Electrode[J]. Acta Phys. -Chim. Sin., 1995,11(01): 56-60
44. Wang Ze-Xin, Zhang Ji-Shu, Yu Xiao-An, Hao Ce, Chen Zong-Qi.Effect of the Ni(510) Step Surface for the Dissociative Adsorption of Hydrogen Molecule[J]. Acta Phys. -Chim. Sin., 1994,10(10): 915-920
45. Zhai Run-Sheng, Cai Mao-Sheng, D.M.Kolb.XPS Evidence of Sulfate Anion Adsorption on Emersed Pt(111) in H2SO4 Solution[J]. Acta Phys. -Chim. Sin., 1994,10(08): 741-743
46. Yan Jian-Hua; Liu Ying-Jun; Gui Lin-Lin; Tang You-Qi.The Surface Structure of WO3/Titania-alumina System[J]. Acta Phys. -Chim. Sin., 1993,9(01): 13-20
47. Sun Shi-Gang; Wang Jin-Jian; Mu Ji-Qian.A Dynamic Investigation of the Dissociative Adsorption of Hcooh on Pt(100) Single Crystal Electrode[J]. Acta Phys. -Chim. Sin., 1992,8(06): 732-735
48. Huang Hui-Zhong; Hu De-Hong; Gui Lin-Lin; Fu Xian-Zhi; Tang You-Qi.Characterization of Surface Structure of Novel Supported Catalysts by SSIMS[J]. Acta Phys. -Chim. Sin., 1992,8(02): 148-152
49. Wei Zhao-Bin; Wei Cheng-Dong; Xin Qin.Raman Spectroscopic Study of MoO3/TiO2-Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 1992,8(02): 261-265
50. Sun Shi-Gang; Yang Dong-Fang; Tian Zhao-Wu.IN-SITU FTIR Studies on Adsorption and Oxidation of 1,2-Propanediol at a Platinum Electrode in Acid Solutions[J]. Acta Phys. -Chim. Sin., 1992,8(01): 59-63
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top