Register
ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2009,Vol.25>> Issue(10)>> 2050-2054     doi: 10.3866/PKU.WHXB20091012         中文摘要
Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils
ZHAO Yan-Chun, LAN Huang-Xian, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang
Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources of the Ministry of Education of China, College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, Guangxi Province, P. R. China
Full text: PDF (1028KB) HTML Export: BibTeX | EndNote (RIS)

A novel nanoporous poly(N-acetylaniline) (np-PAANI) film with a network structure modified with Pt nanoparticles (C/np-PAANI/Pt) was fabricated using chemical oxidation polymerization and a reduction method. The morphology and composition of the final products were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The electrocatalytic activity of C/np-PAANI/Pt towards the oxidation of methanol was investigated using cyclic voltammetry and chronoamperometric methods in 0.5 mol·L-1 CH3OH+0.5 mol·L-1 H2SO4 mixture solution. Results indicated that C/np-PAANI/Pt catalysts exhibited improved electrocatalytic activity, anti-poisoning ability, and good stability towards methanol oxidation by comparison to C/PAANI/Pt or C/Pt.



Keywords: Poly(N-acetylaniline)   Pt particles   Nanoporous structure   Methanol   Electrocatalytic oxidation  
Received: 2009-04-12 Accepted: 2009-06-29 Publication Date (Web): 2009-08-26
Corresponding Authors: ZHAO Yan-Chun Email: yanchunzh@yahoo.cn


Cite this article: ZHAO Yan-Chun, LAN Huang-Xian, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang. Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils[J]. Acta Phys. -Chim. Sin., 2009,25 (10): 2050-2054.    doi: 10.3866/PKU.WHXB20091012
1. GUO Xing-Zhong, DING Li, YU Huan, SHAN Jia-Qi, YANG Hui.Construction and Preparation Mechanism of Hierarchically Porous SiO2 Monoliths[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1727-1733
2. HU Si, ZHANG Qing, GONG Yan-Jun, ZHANG Ying, WU Zhi-Jie, DOU Tao.Deactivation and Regeneration of HZSM-5 Zeolite in Methanol-to-Propylene Reaction[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1785-1794
3. TIAN Chun-Xia, YANG Jun-Shuai, LI Li, ZHANG Xiao-Hua, CHEN Jin-Hua.New Methanol-Tolerant Oxygen Reduction Electrocatalyst——Nitrogen-Doped Hollow Carbon Microspheres@Platinum Nanoparticles Hybrids[J]. Acta Phys. -Chim. Sin., 2016,32(6): 1473-1481
4. ZHAO Jun-Feng, SUN Xiao-Li, HUANG Xu-Ri, LI Ji-Lai.A Theoretical Study on the Reactivity and Charge Effect of PtRu Clusters toward Methanol Activation[J]. Acta Phys. -Chim. Sin., 2016,32(5): 1175-1182
5. LIU Jian-Hong, Lü Cun-Qin, JIN Chun, WANG Gui-Chang.First-Principles Study of Effect of CO to Oxidize Methanol to Formic Acid in Alkaline Media on PtAu(111) and Pt(111) Surfaces[J]. Acta Phys. -Chim. Sin., 2016,32(4): 950-960
6. TIAN Wen-Jie, WANG Hong, YIN Zhen, YANG Ying, LI Jian-Xin.Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol[J]. Acta Phys. -Chim. Sin., 2015,31(8): 1567-1574
7. HU Si, ZHANG Qing, YIN Qi, ZHANG Ya-Fei, GONG Yan-Jun, ZHANG Ying, WU Zhi-Jie, DOU Tao.Catalytic Conversion of Methanol to Propylene over HZSM-5 Modified by NaOH and (NH4)2SiF6[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1374-1382
8. ZHAO Jun-Feng, SUN Xiao-Li, LI Ji-Lai, HUANG Xu-Ri.Theoretical Study of Methanol C―H and O―H Bond Activation by PtRu Clusters[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1077-1085
9. LI Li, HE Xiao-Li, QIN Tao, DAI Fu-Tao, ZHANG Xiao-Hua, CHEN Jin-Hua.Dual-Sacrificial Template Synthesis of One-Dimensional Tubular Pt-Mn3O4-C Composite with Excellent Electrocatalytic Performance for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2015,31(5): 927-932
10. OUYANG Mi, HUANG Sen-Biao, HAN Yan-Gang, Lü Xiao-Jing, YANG Yuan, DAI Yu-Yu, Lü Yao-Kang, ZHANG Cheng.Enhanced Electrochromic Performance of Ordered Porous Monolayer PBTB Film Using Amine-Modified Polystyrene Spheres as a Template[J]. Acta Phys. -Chim. Sin., 2015,31(3): 476-482
11. CHEN Hong, WANG Shi-Xian, ZHAO Wan-Long, ZHANG Neng-Neng, ZHENG Ying-Ping, SUN Yue-Ming.Preparation of Pt/TiO2 Nanofibers and Their Electrocatalytic Activity towards Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2015,31(2): 302-308
12. GAO Hai-Li, LI Xiao-Long, HE Wei, GUO Rui-Ting, CHAI Bo.One-Step Synthesis of Reduced Graphene Oxide Supported Pt Nanoparticles and Its Electrocatalytic Activity for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2117-2123
13. ZHANG Lan-Lan, SONG Yu, LI Guo-Dong, ZHANG Shao-Long, SHANG Yun-Shan, GONG Yan-Jun.ZSM-5 Zeolite with Micro-Mesoporous Structures Synthesized Using Different Templates for Methanol to Propylene Reaction[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2139-2150
14. LI Ling-Ling, JANIK J. Michael, NIE Xiao-Wa, SONG Chun-Shan, GUO Xin-Wen.Reaction Mechanism of Methylation of 4-Methylbiphenyl with Methanol over H-ZSM-5 Zeolite[J]. Acta Phys. -Chim. Sin., 2015,31(1): 56-66
15. GAO Wen-Xiu, WANG Hong-Lei, LI Shen-Min.Molecular Dynamics Simulation Study of Structural and Transport Properties of Methanol-Water Mixture in Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1625-1633
16. WANG Li, MA Jun-Hong.Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30(7): 1267-1273
17. GAO Peng, LI Feng, ZHAO Ning, WANG Hui, WEI Wei, SUN Yu-Han .Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO2 to Methanol[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1155-1162
18. WANG Guan-Nan, CHEN Li-Min, GUO Yuan-Yuan, FU Ming-Li, WU Jun-Liang, HUANG Bi-Chun, YE Dai-Qi.Effect of Chromium Doping on the Catalytic Behavior of Cu/ZrO2/CNTs-NH2 for the Synthesis of Methanol from Carbon Dioxide Hydrogenation[J]. Acta Phys. -Chim. Sin., 2014,30(5): 923-931
19. WANG Chun, KANG Jian-Xin, WANG Li-Li, CHEN Ting-Wen, LI Jie, ZHANG Dong-Feng, GUO Lin.Synthesis of Quasi-Concave Pt-Ni Nanoalloys via Overgrowth and Their Catalytic Performance towards Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30(4): 708-714
20. TANG Wei, WANG Jing, YAO Peng-Jun, DU Hai-Ying, SUN Yan-Hui.Preparation, Characterization and Gas Sensing Mechanism of ZnO-Doped SnO2 Nanofibers[J]. Acta Phys. -Chim. Sin., 2014,30(4): 781-788
21. ZHANG Shao-Long, ZHANG Lan-Lan, WANG Wu-Gang, MIN Yuan-Yuan, MATong, SONG Yu, GONG Yan-Jun, DOU Tao.Methanol to Propylene over Nanosheets of HZSM-5 Zeolite[J]. Acta Phys. -Chim. Sin., 2014,30(3): 535-543
22. ZENG Yong-Ping, SHI Rong, YANG Zheng-Hua.Ab Initio Molecular Dynamics Simulations of Structural Properties of Be2+ in Water, Methanol and Ethanol[J]. Acta Phys. -Chim. Sin., 2013,29(10): 2180-2186
23. HAO Ai-Xiang, YU Yang, CHEN Hai-Bo, MAO Chun-Peng, WEI Shi-Xin, YIN Yu-Sheng.Effect of Surface Promoters-Modifying on Catalytic Performance of Cu/ZnO/Al2O3 Methanol Synthesis Catalyst[J]. Acta Phys. -Chim. Sin., 2013,29(09): 2047-2055
24. ZHOU Yang, LIU Wei-Ming, HU Xian-Chao, CHU You-Qun, MA Chun-An.Nano-WO3 Composite Materials as Electro-Catalyst for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1487-1493
25. CHENG Hai-Long, XU Jing-Mei, WANG Zhe, REN Chun-Li, BAI Hong-Wei, ZHAO Cheng-Ji, ZHANG Hui-Xuan.Sulfonated Poly(aryl ether ketone) on Side Chain/Sulfonated Poly(vinyl alcohol) Composite Proton Exchange Membrane for Direct Methanol Fuel Cells[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1515-1523
26. LI Ling-Ling, Janik J. Michael, NIE Xiao-Wa, SONG Chun-Shan, GUO Xin-Wen.Reaction Mechanism of Toluene Methylation with Dimethyl Carbonate or Methanol Catalyzed by H-ZSM-5[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1467-1478
27. ZHANG Jin-Gui, QIAN Wei-Zhong, TANG Xiao-Ping, SHEN Kui, WANG Tong, HUANG Xiao-Fan, WEI Fei.Influence of Catalyst Acidity on Dealkylation, Isomerization and Alkylation in MTA Process[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1281-1288
28. CUI Ying, KUANG Yin-Jie, ZHANG Xiao-Hua, LIU Bo, CHEN Jin-Hua.Spontaneous Deposition of Pt Nanoparticles on Poly(diallyldimethylammonium chloride)/Carbon Nanotube Hybrids and Their Electrocatalytic Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2013,29(05): 989-995
29. WANG Feng, YAN Shu-Jun, YONG Xiao-Jing, LUO Chun-Tao, ZHANG Qing, WEN Peng-Yu, GONG Yan-Jun, DOU Tao.Effects of Na+ in Dilution Steam and Coke Deposition on Catalytic Performance of Methanol-to-Propylene Catalysts[J]. Acta Phys. -Chim. Sin., 2013,29(02): 358-364
30. ZHOU Yang, CHU You-Qun, LIU Wei-Ming, MA Chun-An.Nano-WO3 Modified Carbon Nanotube Supported Pt and Their Electrocatalytic Activity for Methanol Electro-Oxidation[J]. Acta Phys. -Chim. Sin., 2013,29(02): 287-292
31. CHEN Fu-Xiao, FAN Wei-Qiang, ZHOU Teng-Yun, HUANG Wei-Hong.Core-Shell Nanospheres (HP-Fe2O3@TiO2) with Hierarchical Porous Structures and Photocatalytic Properties[J]. Acta Phys. -Chim. Sin., 2013,29(01): 167-175
32. LIU Meng, GUO Xiang-Fei, WANG Jing-Ming, JIANG Lei.Behavior of Bubbles on Electrodes with Hierarchical Microporous Structures and Different Wettability[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2931-2938
33. WANG Ding, TIAN Guo-Cai.Simulation Study of the Effect ofMethanol on the Structure and Properties of 1-Butyl-3-methylimidazolium Tetrafluoroborate Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2558-2566
34. CHEN Wen-Long, LIU Hai-Chao.Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2315-2326
35. ZHENG Ning, ZHU Chun-Mei, SUN Bin, SHI Zu-Jin, LIU Yan, WANG Yuan.Nanocomposite Cathode Catalyst with High Methanol Tolerance and Durability[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2263-2268
36. ZHOU Xin-Wen, GAN Ya-Li, SUN Shi-Gang.Studies of Oxidation Processes of Methanol on Hollow CoPt Nanospheres and In situ Electrochemical Fourier Transform Infrared Spectroscopy[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2071-2076
37. YAO Min, HU Si, WANG Jian, DOU Tao, WU Yong-Ping.Size Effect of HZSM-5 Zeolite on Catalytic Conversion of Methanol to Propylene[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2122-2128
38. CHEN Peng-Peng, WANG Jing, YAO Peng-Jun, DU Hai-Ying, LI Xiao-Gan.Synthesis and Gas Sensitivity of In2O3/CdO Composite[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1539-1544
39. NIE Su-Lian, ZHAO Yan-Chun, FAN Jie-Wen, TIAN Jian-Niao, NING Zhen, LI Xiao-Xiao.Highly Active Pd-Co3O4/MWCNTs Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2012,28(04): 871-876
40. WU Gui-Sheng, MAO Dong-Sen, LU Guan-Zhong, CAO Yong, FAN Kang-Nian.In situ Infrared Characterization of Methanol Adsorption on ZrO2 Modified Cu Catalysts[J]. Acta Phys. -Chim. Sin., 2012,28(02): 433-436
41. GUO Xiao-Ming, MAO Dong-Sen, LU Guan-Zhong, WANG Song.Preparation of CuO-ZnO-ZrO2 by Citric Acid Combustion Method and Its Catalytic Property for Methanol Synthesis from CO2 Hydrogenation[J]. Acta Phys. -Chim. Sin., 2012,28(01): 170-176
42. LI Qing-Wu, WEI Zi-Dong, CHEN Si-Guo, QI Xue-Qiang, LIU Xiao, DING Wei, MAYu.PtSnCo/C Anode Catalyst for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2857-2862
43. ZENG Yong-Ping, ZHU Xiao-Min, YANG Zheng-Hua.Car-Parrinello Molecular Dynamics Simulations of Microstructure Properties of Liquid Water, Methanol and Ethanol[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2779-2785
44. WU Xiao-Jing, DAI Yun, ZHANG Nan, LI Jing.Analysis and Assignment of the Fluorescence Spectra of a Salt/Methanol System[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2535-2540
45. RAO Gui-Shi, CHENG Mei-Qin, ZHONG Yan, DENG Xiao-Cong, YI Fei, CHEN Zhi-Ren, ZHONG Qi-Ling, FAN Feng-Ru, REN Bin, TIAN Zhong-Qun.Preparation of High Catalytic Platinum Hollow Nanospheres and Their Electrocatalytic Performance for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2373-2378
46. DANG Dai, GAO Hai-Li, PENG Liang-Jin, SU Yun-Lan, LIAO Shi-Jun, WANG Ye.Preparation of High Performance Core-Shell PdRu@Pt/CNT Electrocatalyst[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2379-2384
47. WEN Sheng, GONG Chun-Li, TSAI Fang-Chang, YEH Jen-Taut.Properties of SPES/AlOOH Composite Proton Exchange Membranes[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1886-1892
48. ZHAO Jing, SUN Yue, LI Yong-Jun, LIANG Ren.Preparation of ‘Sandwich-Like’ Au/Pt Composite Multilayer Films for Methanol Electrooxidation[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1868-1874
49. XU Qun-Jie, LI Jin-Guang, LI Qiao-Xia.Preparation of Mesoporous Carbon at Different Temperatures as a Catalyst Support for Direct Methanol Fuel Cells[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1881-1885
50. ZHANG Li-Zhi, YANG Hao-Lin, ZHAO Dai-Qing, JIANG Li-Qiao.Influence of Methanol Addition on the Two Stage Combustion of a Dimethyl Ether/Air Mixture[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1560-1566
51. DU Yu-Dong, ZHAO Wei-Na, GUO Xin, ZHANG Yong-Fan, CHEN Wen-Kai.Adsorption and Dissociation of Methanol on Perfect FeS2(100) Surface[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1075-1080
52. KONG De-Shuai, WANG Jian-Ming, PI Ou-Yang, SHAO Hai-Bo, ZHANG Jian-Qing.Electrochemical Fabrication and Pseudocapacitive Performance of a Porous Nanostructured Nickel-Based Complex Film Electrode[J]. Acta Phys. -Chim. Sin., 2011,27(04): 764-768
53. DING Xiao-Chun, CHEN Xiu, ZHOU Jian-Hua, WANG Tao, SUN Dun, HE Jian-Ping.Pt-Ni Catalyst Supported on CMK-5 for the Electrochemical Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2011,27(03): 711-716
54. ZHAO Yan-Chun, ZHAN Lu, TIAN Jian-Niao, NIE Su-Lian, NING Zhen.N-Doped Amorphous Carbon Supported Pd Catalysts for Methanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(01): 91-96
55. GAO Hai-Li, LIAO Shi-Jun, ZENG Jian-Huang, LIANG Zhen-Xing, XIE Yi-Chun.Preparation and Characterization of Platinum-Decorated Ru/C Catalyst with High Performance and Superior Poison Tolerance[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3193-3198
56. LI Mei-Chao, WANG Wu-Yang, ZHU Wan-Xia, MA Chun-An.Electrocatalytic Oxidation of Ascorbic Acid on a PPy-HEImTfa/Pt Electrode and Its Mechanism[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3212-3216
57. TIAN Tao, QIAN Wei-Zhong, TANG Xiao-Ping, YUN Song, WEI Fei.Deactivation of Ag/ZSM-5 Catalyst in the Aromatization of Methanol[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3305-3309
58. LIU Hai-Ying, MENG Fan-Cui, LI Ping, DING Shi-Liang.Effects of CH3OH and NH3 on the Hydrolytic Deamination Mechanismof Adenine[J]. Acta Phys. -Chim. Sin., 2010,26(11): 3067-3072
59. GONG Chun-Li, ZHOU Yi, YAN Li-Cheng, WEN Sheng, ZHENG Gen-Wen.Properties of SPES/PWA/SiO2 Composite Proton Exchange Membranes[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2967-2974
60. FU Jing, LIN Rui, LüHong, WANG Xiao-Lei, MA Jian-Xin, QIAO Jin-Li.Preparation and Properties of Poly(vinyl alcohol)/Poly(vinyl pyrrolidone) Composites for Solid Alkaline Electrolyte Membranes[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2653-2658
61. YU Xiao-Chun, LIN Ke, HU Nai-Yin, ZHOU Xiao-Guo, LIU Shi-Lin.Effects of Salts on theMicrostructure ofMethanol[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2473-2480
62. MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao.Effect of Magnesium Oxide Modification on the Catalytic Performance of Nanoscale HZSM-5 Zeolite for the Conversion of Methanol to Propylene[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2242-2248
63. ZHAO Yan-Chun, LAN Huang-Xian, DENG Bin-Bin, TIAN Jian-Niao, YANG Xiu-Lin, WANG Feng-Yang.Electrocatalytic Oxidation of Methanol with Poly Functionalized Multiwalled Carbon Nanotubes Supported Pt Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2255-2260
64. XU Qun-Jie, ZHOU Xiao-Jin, LI Qiao-Xia, LI Jin-Guang.Preparation and Electrochemical Properties of Ternary Catalyst PtRuCo/C for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2135-2138
65. ZHAO Rong-Li, LIN Ke, ZHOU Xiao-Guo, LIU Shi-Lin.Solubility of Poly(N-isopropylacrylamide) in Aqueous Methanol from Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1915-1922
66. ZHANG Sheng-Hong, ZHANG Hong-Peng, LI Wei-Zhen, ZHANG Wei, HUANG Hua, LIU Hai-Chao.Effects of Zirconia Crystallite Phases on the Structures of MoOx/ZrO2 Catalysts and Their Properties in the Selective Oxidation of Methanol[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1879-1886
67. WEN Zhu-Liang, YANG Su-Dong, SONG Qi-Jun, HAO Liang, ZHANG Xiao-Gang.High Activity of Pd/Graphene Catalysts for Ethanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1570-1574
68. AN Xiao-Sha, CHEN De-Jun, ZHOU Zhi-You, WANG Qiang, FAN You-Jun, SUN Shi-Gang.Rare Earth Eu Doped PtRu/C Catalysts and Their Properties for Methanol Electrooxidation[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1207-1213
69. LIU Bo-Jie, LI Xue-Yi, CHEN Wei, LIU Ren-Xiao, GE Guang-Lu.Surface Ligand Exchange and Phase Transfer of Iron Oxide Magnetic Nanoparticles[J]. Acta Phys. -Chim. Sin., 2010,26(03): 784-788
70. WU Yan-Ni, LIAO Shi-Jun.Shortened Carbon Nanotubes as Supports to Prepare High-Performance Pt/SCNT and PtRu/SCNT Catalysts for Fuel Cells[J]. Acta Phys. -Chim. Sin., 2010,26(03): 669-674
71. MAO Dong-Sen, GUO Qiang-Sheng, MENG Tao, LU Guan-Zhong.Effect of Hydrothermal Treatment on the Acidity and Catalytic Performance of Nanosized HZSM-5 Zeolites for the Conversion of Methanol to Propene[J]. Acta Phys. -Chim. Sin., 2010,26(02): 338-344
72. NI Zhe-Ming, MAO Jiang-Hong, PAN Guo-Xiang, XU Qian, LI Xiao-Nian.Mechanism of Palladium-Catalyzed Methanol Decomposition for Hydrogen Production[J]. Acta Phys. -Chim. Sin., 2009,25(05): 876-882
73. WANG Jian-She, GUO Xun, SONG Cheng-Ying, WANG Liu-Cheng, ZHAO Jian-Hong, QIU Xin-Ping.Promoting Methanol Electro-Oxidation through Fabricating Pore Structure in Pt/CNTs Catalyst Layer by Dissolving Away Premixed La2O3 Particles[J]. Acta Phys. -Chim. Sin., 2009,25(04): 767-772
74. YANG Hong-Yan, GUO Pan-Pan, LI Wei-Shan.Electrodeposition Preparation and Activity of CO-Resistant Catalyst Pt-HxWO3 for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2009,25(04): 719-723
75. XU Lei; WU Shu-Jie; ZHANG Wen-Xiang; JIA Ming-Jun; LIU Gang.Vapour Phase ortho-Selective Alkylation of Phenol with Methanol over Fe-Zr Oxide Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(02): 242-246
76. ZHANG Hong-Wei, ZHANG Zheng-Fu, LI Yang, YANG Xi-Hun, LIU Shuo.Structural Effects and Electrooxidation Activity of a Two-Dimensional Multilayer PtRu/PtNd Alloy Nanostructure Thin Film[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2268-2274
77. LI Lai-Cai; WANG Yi-Wei; TIAN An-Min.Adsorption of Methanol on the Pt-Mo(111)/C Surface[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2013-2018
78. ZHENG Yi-Xiong; YAO Shi-Bing; ZHOU Shao-Min.Electrooxidation of Ethanol at Ni-B Amorphous Alloy Electrode and Measurements of Kinetic Parameters[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1643-1649
79. CHANG Xiao-Tu, WANG Jian-Ming, SHAO Hai-Bo, WANG Jun-Bo, ZENG Xiao-Xu, ZHANG Jian-Qing, CAO Chu-Nan.Corrosion and Anodic Behaviors of Pure Aluminumin a Novel Alkaline Electrolyte[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1620-1624
80. ZHENG Bo; LI He-Xian; WANG Guo-Chang; LIU Kun; YUAN Wei; LI He; LIANG Bo.Supramolecular Complexation in Water-Methanol Mixtures[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1503-1506
81. ZHENG Gen-Wen; GONG Chun-Li; WEN Sheng; XIE Xiao-Lin.Preparation and Performances of Sulfonated Poly(ether imide) and Poly (ether sulfone) Blends for Proton Exchange Membrane[J]. Acta Phys. -Chim. Sin., 2008,24(05): 855-860
82. LIANG Ying; LIAO Dai-Wei.Effects of pH on the PtRu/C Catalyst Prepared by Microwave-assisted Ethylene Glycol Process[J]. Acta Phys. -Chim. Sin., 2008,24(02): 317-322
83. RAO Gui-Shi; FAN Feng-Ru; WANG Guo-Fu; WU Zhi-Xiang; YI Fei; ZHONG Qi-Ling; REN Bin; TIAN Zhong-Qun.In-situ SERS of Formic Acid Electro-catalytic Oxidation on Aucore@Ptshell/Pt Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(02): 345-349
84. DENG Hui-Ning; WANG Yu-Xin.Preparation and Properties of Proton Conducting Composite Membranes from Sulfonated Poly(phthalazinone ether keton) and Phosphotungstic Acid[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1235-1240
85. XU Hui-Yuan; CHU Wei; CI Zhi-Min.Effect of Glow Discharge Plasma on Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1042-1046
86. FAN Xiao-Yong; ZHUANG Quan-Chao; JIANG Hong-Hong; HUANG Ling; DONG Quan-Feng; SUN Shi-Gang.Three-dimensional Porous Cu6Sn5 Alloy Anodes for Lithium-ion Batteries[J]. Acta Phys. -Chim. Sin., 2007,23(07): 973-977
87. ZHENG Hai-Tao; LI Yong-Liang; LIANG Jian-Ying; SHEN Pei-Kang.Methanol Oxidation on Pd-based Electrocatalysts[J]. Acta Phys. -Chim. Sin., 2007,23(07): 993-996
88. YAN Zong-Cheng; CHEN Li; WANG Hong-Lin.Glow Discharge Plasma Electrolysis of Methanol Solutions[J]. Acta Phys. -Chim. Sin., 2007,23(06): 835-840
89. LI Lan-Lan; WEI Zi-Dong; YAN Can; LUO Yi-Hui; YIN Guang-Zhi; SUN Cai-Xin.Methanol Oxidation on a Pt ElectrodeModified by Underpotential Deposition of Ru[J]. Acta Phys. -Chim. Sin., 2007,23(05): 723-727
90. ZHAO Wen-Xia; HU Man-Cheng; LI Shu-Ni; JIANG Yu-Cheng; ZHANG Xiao-Lei; HU Lei; CHEN Huai-Jun.The Solubility of Ternary SystemRbBr/CsBr-CH3OH/C2H5OH-H2O at Different Temperatures[J]. Acta Phys. -Chim. Sin., 2007,23(05): 695-700
91. WU Wei; CAO Jie-Ming; CHEN Yu; LU Tian-Hong.Preparation of High-alloying Pt-Ru/CMK-3 Catalysts in THF-H2O-EtOH Ternary Solution System[J]. Acta Phys. -Chim. Sin., 2007,23(04): 559-564
92. ZHANG Cheng-Gen;LI Wen-Zuo;HUANG Ming-Bao.Reaction of Methyl Alcohol with Thionyl Chloride in Solution[J]. Acta Phys. -Chim. Sin., 2007,23(03): 399-403
93. ZHANG Shu-Dong;ZHU Xiang-Jun;WANG Yan;KONG Xiang-He.Multiphoton Ionization Mass Spectrum of Methanol Clusters and Ab Initio Calculations[J]. Acta Phys. -Chim. Sin., 2007,23(03): 379-383
94. DENG Hui-Ning;WANG Yu-Xin .Sulfonated Poly(phthalazinones) Membranes For Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2007,23(02): 187-191
95. HUANG Mian-Yan;CHEN Hua-Yan;GUO Jian-Zhao;WANG Zhi-Tao;XU Li;WANG Yu-Xin.Methanol Resistant Poly(Ether Sulfone)/Sulfonated Poly(Ether Ether Ketone) Blend Proton Exchange Membrane for DMFC[J]. Acta Phys. -Chim. Sin., 2007,23(01): 44-49
96. SHEN Pei-Kang;WANG Sheng-Long;HU Zhi-Yi;LI Yong-Liang;ZENG Rong;HUANG Yue-Qiang.Hydrogen Production by Alcohol Electrolysis[J]. Acta Phys. -Chim. Sin., 2007,23(01): 107-110
97. ZHANG Xue-Hong;TANG Xing-Hua;CHENG Xin-Sun.Synthesis and Application of Ce-doped Mesoporous TiO2[J]. Acta Phys. -Chim. Sin., 2006,22(05): 532-537
98. CHEN Ling; WANG Xin-dong; GUO Min.The Effect of NdOx as Co-catalyst for the Electro-oxidation of Methanol on PtRu/C[J]. Acta Phys. -Chim. Sin., 2006,22(02): 141-145
99. CHEN Yu; TANG Ya-wen; Kong Ling-yong; LIU Chang-peng; XING Wei; LU Tianhong.Effect of Surface Modification Extent of Carbon Nanotubes on Electrocatalytic Performance of Carbon Nanotubes Supported Pt catalyst[J]. Acta Phys. -Chim. Sin., 2006,22(01): 119-123
100. WANG Zhen-bo; YIN Ge-ping; SHI Peng-fei.The Influence of Three Groups of Pt-Ru/C Catalyst’s Precursors on Its Performance for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1156-1160
101. ZHANG Wen-yu; DONG Qing-nian; ZHAO Ning; WEI Wei; SUN Yu-han.The Reaction Mechanism for the Synthesis of 1-methoxy-2-propanol on MgO Catalyst[J]. Acta Phys. -Chim. Sin., 2005,21(06): 653-657
102. CHEN Yu; TANG Ya-Wen; LIU Chang-Peng; XING Wei; LU Tian-Hong.Research Progress on Proton Exchange Membranes for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2005,21(04): 458-462
103. JIA Yu-Xiang; GUO Xiang-Yun.Monte Carlo Simulation of Adsorption Process of CO and H2 in Supercritical Fluids[J]. Acta Phys. -Chim. Sin., 2005,21(03): 306-309
104. Deng Hui-Ning;Li Lei;Xu Li;Wang Yu-Xin.Comparison on Properties of Membranes for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2004,20(11): 1372-1375
105. Zhou Ming-Hua;Dai Qi-Zhou;Lei Le-Cheng;Wu Zu-Cheng;Ma Chun-An;Wang Da-Hui.Electrochemical Oxidation for the Degradation of Organic Pollutants on a Novel PbO2 Anode[J]. Acta Phys. -Chim. Sin., 2004,20(08): 871-876
106. Hu Ji-Ming;Zhang Jian-Qing;Zhang Jin-Tao;Cao Chu-Nan.Electrochemical Activities of IrO2 Electrodes in Small Organic Molecules Containing Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2004,20(07): 740-744
107. Wan Li-Juan;Gao Ying;Wu Bing;Liu Chang-Peng;Xing Wei;Lu Tian-Hong.Cocatalysis of Adsorbed Eu3+ and Ho3+ at Pt-TiO2/C Electrode for Electrooxidaton of Ethanol[J]. Acta Phys. -Chim. Sin., 2004,20(06): 616-620
108. Yun Hong;Chen Jian-Hua;Zhang Hui;Lin Jing-Dong;Chen Hong-Bo;Lin Chang-Jian.The Effects of ZrO2 on Cu-ZnO-ZrO2 Catalysts for Hydrogen Generation by Steam Reforming of Methanol[J]. Acta Phys. -Chim. Sin., 2004,20(05): 550-553
109. Yun Hong;Zhang Hui;Chen Jian-Hua;Chen Hong-Bo;Lin Chang-Jian.The Intermediate State and Mechanism of the Steam Reforming of Methanol over CuO-ZnO-ZrO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(05): 524-528
110. Peng Cheng;Cheng Xuan;Zhang Ying;Chen Ling;Fan Qing-Bai.Comparison of Methanol Electrooxidation on Carbon Supported Pt and PtRu Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(04): 436-439
111. Zhou Hai-Hui;Jiao Shu-Qiang;Chen Jin-Hua;Wei Wan-Zhi;Kuang Ya-Fei.Electrocatalytic Oxidation of Methanol on Nano-fibular Polyaniline Electrode Modified with Pt Microparticles[J]. Acta Phys. -Chim. Sin., 2004,20(01): 9-14
112. Chen Wei;Sun Shi-Gang;Si Di;Chen Sheng-Pei.Electrocatalytic Properties of Agglomerates of Pt Nanoparticles in Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2003,19(05): 441-444
113. Li Xu-Guang;Han Fei;Xing Wei;Tang Ya-Wen;Lu Tian-Hong.Influence of Methanol on the Kinetics of Oxygen Reduction on Pt/C and CoPcTc/C[J]. Acta Phys. -Chim. Sin., 2003,19(04): 380-384
114. Wang Jin;Chen Hong-Bo;Yun Hong;Lin Jing-Dong;Yi Jun;Zhang Hong-Bin;Liao Dai-Wei.Study on Rh-ZnO/MWNTs Catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 2003,19(01): 65-69
115. Zhang Xin-Rong;Shi Peng-Fei.Catalytic Production of Hydrogen from Steam Reforming of Methanol on CeO2 Promoted Cu/Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2003,19(01): 85-89
116. Chen Song-Zhe;Zhong Shun-He.The Photo Stimulated Surface Reaction of Synthesis of Methanol from Carbon Dioxide and Water on Cu/TiO2-NiO[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1099-1103
117. Wei Zi-Dong;Miki Atsushi;Ohmori Tadayoshi;Osawa Masatoshi.Methanol Electroxidation on Upd - Sn Modified Platinum Electrodes[J]. Acta Phys. -Chim. Sin., 2002,18(12): 1120-1124
118. Guo Xia;Xu Hui;Guo Rong.The Fluorescence Quenching of Anthracene by Phenothiazine in Sodium Dodecyl Sulfate / Benzyl Alcohol / Water Microemulsion[J]. Acta Phys. -Chim. Sin., 2002,18(06): 500-503
119. Yang Cheng;Dong Qing-Nian;Zhang Jing;Ren Jie;Sun Yu-Han;Xie Ya-Ning;Hu Tian-Dou.The Structural Effect of CeO2 and La2O3 Modified Pd/γ-Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2002,18(02): 170-174
120. Xi Jing-Yu;Wang Zhi-Fei;Wang Wei-Ping;Lü Gong-Xuan.In-situ XPS Study for Reaction Mechanism of Methanol Decomposition over Cu-Ni/Zn Catalyst[J]. Acta Phys. -Chim. Sin., 2002,18(01): 82-86
121. Xi Jing-Yu;Lv Gong-Xuan;Wang Zhi-Fei.Partial Oxidation of Methanol to Hydrogen over Cu/Zn and Cu/Zn/Ni Catalysts[J]. Acta Phys. -Chim. Sin., 2001,17(07): 655-658
122. Li Han-Sheng;Zhong Shun-He;Wang Jian-Wei;Xiao Xiu-Fen.Effect of K2O on Properties of Cu-Ni/V2O5-SiO2 Catalyst for the Synthesis of Dimethyl Carbonate[J]. Acta Phys. -Chim. Sin., 2001,17(06): 552-554
123. Zhong Shun-He, Gao Feng, Ye Xiu-Qiang, Xiao Xiu-Fen.Study on Laser Stimulated Surface Reaction of Methanol Oxidative Coupling[J]. Acta Phys. -Chim. Sin., 2000,16(07): 601-607
124. Zhong Shun-He, Li Han-Sehng, Wang Jian-Wei, Xiao Xiu-Fen.Cu-Ni/V2O5-SiO2 Catalyst for the Direct Synthesis of Dimethyl Carbonate from Carbon Dioxide and Methanol[J]. Acta Phys. -Chim. Sin., 2000,16(03): 226-231
125. She Pei-Liang, Yao Shi-Bing, Zhou Shao-Min.Electrocatalytic Oxidation of Ethanol on Palladium and Platinum Electrodes Prepared by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2000,16(01): 22-26
126. Zhang Xiao-Gang, Li Yong-Wang, Zhong Bing, Peng Shao-Yi.Molecular Simulation in Hydrogen,Carbon Monoxide,Methanol and Hexane System[J]. Acta Phys. -Chim. Sin., 1999,15(11): 1036-1040
127. Deng Guo-Yang, Jes Henningsen.Quantitative Measurement of Adsorption of CH3OH on Commonly Used Mterials by Photoacoustic Method[J]. Acta Phys. -Chim. Sin., 1999,15(08): 764-768
128. Zhang Rong, Sun Yu-Han, Peng Shao-Yi.Effect of Surface Properties on the Catalytic Performance of Cu/SiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 1999,15(07): 652-656
129. Wu Gui-Sheng, Ren Jie, Sun Yu-Han.The Effect of Calcination Temperature on The Performance of Cu/ZrO2 and Cu-La2O3/ZrO2[J]. Acta Phys. -Chim. Sin., 1999,15(06): 564-567
130. Chen Hong-Bo, Yu La-Jia, Liao Dai-Wei, Lin Guo-Dong, Zhang Hong-Bin, Cai Qi-Rui.The Effect of Cr2O3 over Copper-based Catalysts for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(06): 534-539
131. Wang Gui-Chang, Sun Yu-Han, Zhong Bing.Simulation to the Structure Sensitive of Cu Based catalyst for Methanol Synthesis[J]. Acta Phys. -Chim. Sin., 1998,14(04): 337-342
132. Li Ji-Tao, Zhang Wei-De, Qu Ze-Tang.Effect of CO on Methanol Synthesis from CO2 Hydrogenation[J]. Acta Phys. -Chim. Sin., 1998,14(03): 275-277
133. Zhong Chong-Min, Wang-De-Zheng, Takashi Ushikubo, Keisuke Wada.The Adsorption of Methanol,Water and Ethylene on a Niobium Oxide Thin Film[J]. Acta Phys. -Chim. Sin., 1998,14(03): 219-225
134. Zhang Xiao-Gang,Guo Xiang-Yun,Zhong Bing,Peng Shao-Yi.Monte Carlo Study of Methanol Clusters in Supercritical Cyclohexane System[J]. Acta Phys. -Chim. Sin., 1997,13(10): 898-903
135. Li Ji-Tao,Gao Li-Zhen,Zhang Wei-De.CO Adsorption and Hydrogenation on Crystalline YBa2Cu3Ox Thin Films[J]. Acta Phys. -Chim. Sin., 1997,13(08): 700-705
136. Yang Hui,Li Chang-Zhi,Lu Tian-Hong,Xue Kuan-Hong,Sun Shi-Gang,Lu Guo-Qiang,Chen.Electrocatalytic Oxidation of Methanol on Polythionine Film Modified with Pt Microparticles[J]. Acta Phys. -Chim. Sin., 1997,13(06): 542-547
137. Yang Hui,Lu Tian-Hong,Xue Kuan-Hong,Zhou Yi-Ming,Sun Shi-Gang,Chen Sheng-Pei.Cyclic Voltammetry and in-situ FTIR Spectroscopic Studies on Electro-oxidation of Formaldehyde at a Gold Electrode[J]. Acta Phys. -Chim. Sin., 1996,12(06): 527-531
138. Zhang Suo-Jiang,Han Shi-Jun,Jin Yin-Dong.Molar Conductances of NaCl and KCl in Aqueous Methanol Mixtures at 298.15K[J]. Acta Phys. -Chim. Sin., 1996,12(01): 75-80
139. Li Qing-Shui, Lin Yu-Qin, Liao Yuan-Yan.Studies on Catalytic Dehydrogenation of Methanol to Formaldehyde[J]. Acta Phys. -Chim. Sin., 1995,11(05): 442-446
140. Cai Lin-Tao, Yao Shi-Bing, Zhou Shao-Min.Electrocatalytic Oxidation of Ascorbic Acid at Polyaniline Modified Electrode and the Effects of the Magnetic Field[J]. Acta Phys. -Chim. Sin., 1995,11(02): 185-188
141. Zhang Ya-Ming, Wang Yan-Ru, Shi Jun.Enthalpies of Dilution of Calcium Chloride in Aqueous Solution of Alcohols[J]. Acta Phys. -Chim. Sin., 1994,10(06): 555-559
142. Wang Yi-Xuan; Zhao Jian-Ping; Dai Ming.Vapor-Liquid Equilibrium for Some Polar Aprotic Solvents with Methanol or 1,2-Dichloroethane[J]. Acta Phys. -Chim. Sin., 1992,8(05): 636-641
143. Zhou Zhi-Hua; Hu Wei-Dong; Lu Wen-Qing; Zhou Yi-Ming; Xue Kuan-Hong.Effect of Supporting Electrolyte on the Electrochemical Oxidation Pathways of Anhydrous Methanol at Gold Electrode[J]. Acta Phys. -Chim. Sin., 1992,8(05): 707-711
144. Dong Shao-Jun; Song Fa-Yi.Electrocatalytic Oxidation of Ascorbic Acid at Polyaniline Film Modified Glassy Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 1992,8(01): 82-86
145. Su Wen-Duan; Zhou Shao-Min; Zhou Xiao-Lin.Statistical Mechanical Treatment of Adsorbed Monolayer at Electrode/Solution Interface III. The Structure of Inner Layer Formed at the Interface of Hg/(H2O+CH3OH) Solution[J]. Acta Phys. -Chim. Sin., 1991,7(04): 443-448
146. CHENG Xiao-Meng, LI Yu, CHEN Zong, LI Hong-Ping, ZHENG Xiao-Fang.A Comparative Study on the NMR Relaxation of Methanol in Sub- and Super-critical Mixtures of CO2 and Methanol[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388 Email:whxb@pku.edu.cn
^ Top