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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2009,Vol.25>> Issue(12)>> 2475-2480     doi: 10.3866/PKU.WHXB20091202         中文摘要
Fabrication of a Spongelike Nanostructured TiO2 Filmand Its Photocatalytic Activity
WANG Meng-Ye, WANG Cheng-Lin, XIE Kun-Peng, SUN Lan, LIN Chang-Jian
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
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A spongelike nanostructured titanium dioxide (TiO2) film was fabricated on a titanium substrate by electrochemical anodic oxidation. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) experiments were performed to characterize the morphology and crystalline phase of the spongelike nanostructured TiO2 films. The effect of anodizing time on the thickness of the layers was examined. The relationship between the thickness of the spongelike nanostructured TiO2 film and its photocatalytic activity was investigated by the degradation of methyl orange solution. Results showed that the spongelike nanostructured TiO2 film had a high photocatalytic activity. The photocatalytic degradation rate of a methyl orange solution increased with the film thickness. The photocatalytic degradation rate by the spongelike nanostructured TiO2 film with a thickness of 2.2 μm was 6.4 times as large as that by the spongelike nanostructured TiO2 filmwith a thickness of 480 nm.



Keywords: Anodic oxidation   Photocatalytic activity   Spongelike nanostructured TiO2 film  
Received: 2009-07-01 Accepted: 2009-09-11 Publication Date (Web): 2009-10-14
Corresponding Authors: SUN Lan Email: sunlan@xmu.edu.cn


Cite this article: WANG Meng-Ye, WANG Cheng-Lin, XIE Kun-Peng, SUN Lan, LIN Chang-Jian. Fabrication of a Spongelike Nanostructured TiO2 Filmand Its Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2009,25 (12): 2475-2480.    doi: 10.3866/PKU.WHXB20091202
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55. Pan Zhan-Chang;Chen Qi-Yuan;Huang Hui-Min.Studies of Mn(III)/Mn(II) on Platinum Electrode in Acetic Acid-Anhydride Solution[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1067-1071
56. Xu Yan-Qi;Cai Wei-Li;Wang Yin-Hai;Mou Ji-Mei.Fabrication and Characterization of Ordered Nanoporous Ni Membranes[J]. Acta Phys. -Chim. Sin., 2001,17(11): 991-994
57. Guo Deng-Zhu;Hou Shi-Min;Shen Zi-Yong;Zhang Geng-Min;Zhao Xing-Yu;Liu Wei-Min;Wu Jin-Lei;Xue Zeng-Quan.AFM Study of Quasiordered Stripelike Nanostructures on Surfaces of Aluminum[J]. Acta Phys. -Chim. Sin., 2001,17(11): 961-965
58. Yu Jia-Guo;Zhao Xiu-Jian;Chen Wen-Mei;Lin Li;Zhang Ai-Li.Photocatalytic Activity and Hydrophilic Property of TiO2/SiO2 Composite Nanometer Thin Films[J]. Acta Phys. -Chim. Sin., 2001,17(03): 261-264
59. Xu Ya-Jie, Xu Dong-Sheng, Chen Da-Peng, Guo Guo-Lin, Li, C. J..Electrochemistry Preparation and Characterization of CdS Nanowire Arrays[J]. Acta Phys. -Chim. Sin., 1999,15(07): 577-580
60. Li Wei-Shan,Jiang Lin-Cai,Huang Zhong-Tao.Anodic Oxidation of Mn2+ Ion in H2SO4 Solutions Catalyzed by Ag+ Ion[J]. Acta Phys. -Chim. Sin., 1996,12(12): 1119-1123
61. Dai Song-Yuan,Wang Yu,Wu Qin-Chong,Wang Kong-Jia,Huo Yu-Ping.Preparation of Nanometer TiO2 Films by Anodic Oxidative Hydrolysis[J]. Acta Phys. -Chim. Sin., 1996,12(08): 758-760
62. Xu Tao,Qi Shang-Kui,Zhao Jia-Zheng,Chen Jian-Min.Study on the Surface and Interfance of Anodic Oxide Film of Aluminum[J]. Acta Phys. -Chim. Sin., 1996,12(03): 276-279
63. Jin Shi-Xiong,Wen Qing.The Kinetics of the Anodic Oxidation of Ce(III) Ion at Pt Electrode in Sulfuric Acid Solution[J]. Acta Phys. -Chim. Sin., 1995,11(08): 688-693
64. Chen Kun-Yao; Lin Zhong-Hua.The Implantation of Light-Induced CoIONS into Ti Anodic Oxide Film[J]. Acta Phys. -Chim. Sin., 1992,8(03): 326-331
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