ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2009,Vol.25>> Issue(12)>> 2481-2487     doi: 10.3866/PKU.WHXB20091209         中文摘要
Adsorption of Dye Molecules onto a Glass Surface Studied by Optical Waveguide Spectroscopy
DENG Lin, LU Dan-Feng, QI Zhi-Mei
State Key Laboratory of Transducer Technology, Institute of Electronics, Chinese Academy of Sciences, Beijing 100190, P. R. China
Full text: PDF (542KB) HTML Export: BibTeX | EndNote (RIS)

Optical waveguide (OWG) absorption spectroscopy makes use of an evanescent field to detect the polarized absorption spectra of sub-monomolecular adlayers. This technique is suitable for the investigation of adsorption kinetics at the solid/liquid interface of dyes, pigments, fluorescent molecules, quantum dots, metallic nanoparticles, and proteins with chromophores. In this work, a time-resolved optical waveguide spectrometer was constructed using a tungsten-halogen lamp, a prism-coupled thin-filmglass waveguide, and a charge-coupled device (CCD) spectral analyzer. The adsorption properties of rhodamine 6G(R6G) and methylene blue (MB) were investigated using this apparatus. By comparing the transverse electric (TE) and transverse magnetic (TM) polarized absorption spectra, the R6G molecules were found to adsorb onto the glass surface as monomers and dimers while MB adsorbed mostly as high-order aggregates. The average orientation angles of the adsorbed dye molecules were also estimated.

Keywords: Surface adsorption   Optical waveguide absorption spectroscopy   Time resolution   Dye molecule   Aggregation state   Average orientation angle  
Received: 2009-07-01 Accepted: 2009-09-04 Publication Date (Web): 2009-10-26
Corresponding Authors: QI Zhi-Mei Email:

Cite this article: DENG Lin, LU Dan-Feng, QI Zhi-Mei. Adsorption of Dye Molecules onto a Glass Surface Studied by Optical Waveguide Spectroscopy[J]. Acta Phys. -Chim. Sin., 2009,25 (12): 2481-2487.    doi: 10.3866/PKU.WHXB20091209
1. SHEN Huan, ZHANG Bing.Ultrafast Dynamics of Benzene on the S2 State Investigated by Femtosecond Time-Resolved Photoelectron Spectroscopy[J]. Acta Phys. -Chim. Sin., 2015,31(9): 1662-1666
2. CHEN Fei-Wu, LU Tian, WU Zhao.Surface Absorption of a Solution at Equilibrium[J]. Acta Phys. -Chim. Sin., 2015,31(8): 1499-1503
3. ZHU De-Hua, ZHONG Rong, CAO Yu, PENG Zhi-Hui, FENG Ai-Xin, XIANG Wei-Dong, ZHAO Jia-Long.Size-Dependent Electron Injection and Photoelectronic Properties of CuInS2 Quantum Dot Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1861-1866
4. ABULIMITI Bumaliya, ZHU Rong-Shu, QIU Xue-Jun, QIN Chen, ZHANG Bing.Studies of Ultrafast Dynamics of 3-Picoline with Femtosecond Time-Resolved Photoelectron Imaging[J]. Acta Phys. -Chim. Sin., 2014,30(1): 22-27
5. LV Yong-Gang, LI Zhi-Jun, WU Li-Zhu, WANG Peng, FU Li-Min, ZHANG Jian-Ping.Application of Time-Resolved Coherent Anti-Stokes Raman Scattering Technique on the Study of Photocatalytic Hydrogen Production Kinetics[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1632-1638
6. YU Zhan-Jiang, CHEN Yong-Qiang, YANG Xiao-Da.Effective Adsorption of Functional Biological Macromolecules on Stainless Steel Surface with Micro/Nanoporous Texture[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1595-1602
7. JIANG Li-Lin, LIU Wei-Long, SONG Yun-Fei, HE Xing, WANG Yang, WU Hong-Lin, YANG Yan-Qiang.Fluorescence and Raman Spectroscopic Characteristics of the Photo-Induced Electron Transfer of Coumarin 343 Dye-Sensitized TiO2 Nanoparticles[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2953-2957
8. DING Zhong-Hua, QIU Xue-Jun, XU Yan-Qi, WANG Yan-Mei, ZHANG Bing.Ultrafast Internal Conversion Dynamics of Benzyl Chloride by Femtosecond Time-Resolved Photoelectron Imaging[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2761-2766
9. ZHANG Rong-Rong, QIN Chao-Chao, LONG Jin-You, YANG Ming-Hui, ZHANG Bing.Ultrafast Predissociation Dynamics of Excited State of Acrylic Acid[J]. Acta Phys. -Chim. Sin., 2012,28(03): 522-527
10. ZHANG Rong-Jun, QI Zhi-Mei, ZHANG Zhe.In situ Study of Self Assembly of Gold Nanoparticles and Cytochrome c by Polarized Optical Waveguide Spectroscopy[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1757-1762
11. CHEN Ye, CHEN Jian-Hua, GUO Jin.Adsorption of O2 and CN on the Copper Activated Sphalerite (110) Surface[J]. Acta Phys. -Chim. Sin., 2011,27(02): 363-368
12. LIU Ben-Kang, WANG Yan-Qiu, WANG Li.Time-Resolved Multiphoton Ionization Process of Xenon Investigated by Photoelectron Imaging Method[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3157-3162
13. DENG Lin, QI Zhi-Mei.Study of Competitive Adsorption Behavior of Protein andMethylene Blue by Optical Waveguide Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2672-2678
14. DENG Lin, QI Zhi-Mei.Effect of Glass Silylation on the Adsorption Behavior of Rhodamine 6G and Methylene Blue[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1923-1928
15. LI Guang-Xu, CHEN Xiao-Wei, BAI Jia-Dong, LAN Zhi-Qiang, GUO Jin.Adsorption and Diffusion of H on Mg2Ni(100) Surface[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1448-1456
16. LI Tao, LV Rong, YU An-Chi.Recombination Process between Myoglobin and NO Studied by Time-Resolved Raman Spectroscopy[J]. Acta Phys. -Chim. Sin., 2010,26(01): 18-22
17. NI Bi-Lian, CAI Ya-Ping, LI Yi, DING Kai-Ning, ZHANG Yong-Fan.Geometries and Electronic Structures for the Adsorption of Li on Si(001) Surface with Different Coverages[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1535-1544
18. JI Min, ZHEN Jun-Feng, ZHANG Qun, CHEN Yang.Photodissociation Dynamics of tert-Butyl Nitrite Investigated by Time-Resolved Fourier TransformInfrared Emission Spectroscopy[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1641-1644
19. GAN Qin-Fang; NI Bi-Lian; LI Yi; DING Kai-Ning; ZHANG Yong-Fan.Geometries and Electronic Structures for the Adsorption of CO Molecule on TiC(001) Surface[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1850-1858
20. HUANG Yong-Li; LIU Zhi-Ping.DFT Study on Hydrogen and Sulfur Adsorption on (111) Surface of Pd, Cu, Au, and PdAu, PdCu Alloys[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1662-1668
21. ZHANG Lian-Shui; WANG Bai-Rong; DANG Wei; XIAO Guang-Chang-Sheng.Excited Dissociation Kinetics of H2O by Pulsed Streamer Discharge[J]. Acta Phys. -Chim. Sin., 2008,24(08): 1524-1528
22. DIAO Zhao-Yu; WU Hong-Zhang; WANG Ze-Xin; ZHANG Xue-Na; ZHANG Yan.Adsorption and Vibration of Oxygen Atomon Al(100), (110), (111) Planes[J]. Acta Phys. -Chim. Sin., 2008,24(03): 437-442
23. CAI Jian-Qiu;TAO Xiang-Ming;TAN Ming-Qiu.Atomic Geometry and Adsorption of Cu(100)/H Surface[J]. Acta Phys. -Chim. Sin., 2007,23(03): 355-360
24. ZHU Meng-Qiang;PAN Gang;LIU Tao;LI Xian-Liang;YANG Yu-Huan;LI Wei;LI Jin;HU Tian-Dou;WU Zi-Yu;XIE Ya-Ning.Zn(II) Adsorption and Precipitation on γ-MnOOH-Water Interfaces DFT and XANES Calculation[J]. Acta Phys. -Chim. Sin., 2005,21(12): 1378-1383
25. Lu Tong-Xing;Xu Xin-Sheng;Cui Zhi-Feng.Investigation on the TRESR Spectra of the Laser Photolyzed Benzoquinone Radical under Proton Exchange[J]. Acta Phys. -Chim. Sin., 2003,19(03): 268-271
26. Zhou Zhi-You;Sun Shi-Gang;Chen Sheng-Pei;Si Di;Gong Hui.Electrochemical In Situ Step-scan Time-resolved Microscope FTIR Spectroscopy[J]. Acta Phys. -Chim. Sin., 2002,18(11): 989-993
27. Yan Yun;Han Feng;Huang Jian-Bin;Li Zi-Chen;Ma Ji-Ming.The Study of Bolaamphiphile/SDS Mixed Systems by Applying the Regular Solution Theory[J]. Acta Phys. -Chim. Sin., 2002,18(09): 830-834
28. Ren Li;Kong Fan-Ao.A Study of the Reaction of OH radical with CO by Time-resolved FTIR Spectroscopy[J]. Acta Phys. -Chim. Sin., 2002,18(06): 486-489
29. Li Yong-Hui;Huang Jian-Bin;Wang Chuan-Zhong;Mao Min.The Surface Chemical Properties of Hydrolytic Surfactants[J]. Acta Phys. -Chim. Sin., 2001,17(11): 972-977
30. Chen Jian-Gang;Xiang Hong-Wei;Dong Qing-Nian;Wang Xiu-Zhi;Sun Yu-Han.H2 or CO Chemsorption on Co-based Catalysts for F-T Synthesis[J]. Acta Phys. -Chim. Sin., 2001,17(02): 161-164
31. Xiang Juan, Wu Bing-Liang, Chen Sheng-Li.An EQCM Investigation of the Mechanism of Surface Electro-oxidation of Formic Acid on Pt-electrode[J]. Acta Phys. -Chim. Sin., 2000,16(10): 906-911
32. Wang Wen-Jun, Lu Xing-Ze, Xu Jian-Hua, Liu Xiu, Jiang Yong-Qiang, Wang Gong-Ming, Cai Zhi-Gang, Yang Pei-Qing, Zhou Jian-Ying.Photoluminescence Characteristics of Hemicyanine Derivatives in Langmuir-Blodgett Multilayers[J]. Acta Phys. -Chim. Sin., 2000,16(06): 496-500
33. Wang Wen-Jun, Xu Jian-Hua, Lu Xing-Ze, Han Kui, Wang Gong-Ming, Wang Wen-Cheng, Cai Zhi-Gang, Yang Pei-Qing, Zhou Jian-Ying.Influence of the Interlayer Interactions on Aggregates in Organic Molecular Films[J]. Acta Phys. -Chim. Sin., 1999,15(05): 471-475
34. Han Guo-Bin, Wu Jin-Tian, Vignes-Adler M.Dynamic Surface Propertes of Foaming Agent C12E8[J]. Acta Phys. -Chim. Sin., 1999,15(04): 327-332
35. Shen Qiang, Li Gan-Zuo, Huang Yan-Zhang, Ye Jian-Ping.The Influence of Alcohol on the Aggregation Behavior of DDAHPS Molecules in Water[J]. Acta Phys. -Chim. Sin., 1999,15(03): 216-221
36. Mao Wen-Tao, Li Qiang, Su Hong-Mei, Kong Fan-Ao.Study of CICOCO Free Radical[J]. Acta Phys. -Chim. Sin., 1998,14(08): 673-675
37. Wang Bao-Shan, Guo Jing-Zhong, Gu Yue-Shu, Mao Wen-Tao, Kong Fan-Ao.Vibrational Energy Transfer from Highly Excited State CO to C2H2[J]. Acta Phys. -Chim. Sin., 1998,14(04): 327-331
38. He Shao-Guang, Zhao Guo-Xi.Surface Adsorption and Micelle Formation of the Aqueous Mixture of C7FNa-Et4NBr[J]. Acta Phys. -Chim. Sin., 1998,14(03): 261-266
39. He Yong, Xiong Yi-Jia, Wang Chao-Hui, Zhu Qi-He, Kong Fan-Ao.A Theoretical Study on Ultrafast Vibrational Relaxation of Dye Molecule in Solution[J]. Acta Phys. -Chim. Sin., 1998,14(02): 115-120
40. Zhao Guo-Xi,Yang Zhen-Le,Zhu Bu-Yao.Study on Surface Chemical Properties of Mixed Systems of Derivatives of 10-undecenoic Acid[J]. Acta Phys. -Chim. Sin., 1997,13(09): 773-779
41. Zheng Wen-Xia,Wang Ze-Xin.Effect of the Ni(115) Step Surface for the Chemical Kinetics of Hydrogen Atom and Molecule on the Surface[J]. Acta Phys. -Chim. Sin., 1996,12(10): 910-915
42. Zhang Ji-Shu,Zhang Wen-Xia,Wang Ze-Xin.Adsorption and Diffusion of Hydrogen Atom on Pd Loe Index Surfaces[J]. Acta Phys. -Chim. Sin., 1996,12(09): 773-779
43. Lu Xing-Ze,Ma Shi-Hong,Song Jie,Han Kui,Zheng Jia-Biao,Wang Wen-Cheng.Time-Resolved Fluorescence Lnvestigations of Aggregation in LB Films[J]. Acta Phys. -Chim. Sin., 1996,12(05): 413-417
44. Zhong Qing-Hua,Wang Zhao-Hui,Zhu Qi-He,Kong Fan-Ao.Study of the Ultrafast Processes of TPP,BuPc and NtBuPc[J]. Acta Phys. -Chim. Sin., 1996,12(03): 193-195
45. Zhang Wen-Min,He Guang-Long,Lu Tong-Xing.The CIDEP Spectra of Photolized p-benzosemiquinone and 2-hydroxy-2-propyl Radicals[J]. Acta Phys. -Chim. Sin., 1996,12(01): 18-21
46. Lv Xin,Xu Xin,Wang Nan-Qin,Zhang Qian-Er.DV-Xa Embedded Cluster Studies:Chemisorption of NO on NiO(100) Surface[J]. Acta Phys. -Chim. Sin., 1995,11(09): 796-800
47. Sun Shi-Gang, Lu Guo-Qiang.Kinetics and Time Resolved FTIR Spectroscopic Characters of Dissociative Adsorption of HCOOH on Pt Electrode[J]. Acta Phys. -Chim. Sin., 1995,11(01): 56-60
48. Tian Zhong-Qun; Li Wu-Hu; Gao Jin-Song; Mao Bing-Wei.Evidence for Different Responsing Rates of Different sers Bands of Surface Species on Change of Electrode Potentials[J]. Acta Phys. -Chim. Sin., 1993,9(06): 721-723
49. Li Hong-Zhi; Wang Xue-Bin; Kong Fan-Ao; Zhu Qi-He.High Vibrationally Excited Co(υ, X1Σ+) from the UV Laser Photolysis of CHBr3+O2 System[J]. Acta Phys. -Chim. Sin., 1993,9(04): 452-454
50. Fu Zhi-Dong; Lin Zhong-Hua; Luo Jin; Lin Zu-Geng; Tian Zhao-Wu.A New Electrochemically Modulated Time Resolved UV/VIS Spectroscopic(EMTRUV/VS) Technique and its Application in the Electrochromism of Popd Film[J]. Acta Phys. -Chim. Sin., 1992,8(01): 4-7
51. Han Ming-Yong; Liu Wang; Wang De-Jun; Xiao Liang-Zhi; Li Tie-Jin.A Sutdy of Charge Transfer Interaction Between MnPc and Surface-Adsorbed NO2[J]. Acta Phys. -Chim. Sin., 1991,7(03): 349-353
52. LI Kui, ZHAO Yao-Lin, DENG Jia, HE Chao-Hui, DING Shu-Jiang, SHI Wei-Qun.Adsorption of Radioiodine on Cu2O Surfaces: a First-Principles Density Functional Study[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
53. XING Lei, JIAO Li-Ying.Recent Advances in the Chemical Doping of Two-Dimensional Molybdenum Disulfide[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top