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Acta Physico-Chimica Sinica  2010, Vol. 26 Issue (01): 47-50    DOI: 10.3866/PKU.WHXB20100105
ELECTROCHEMISTRY     
Electrochemical Performance of 1,4,5,8-Tetrahydroxy-9,10-anthraquinone as Cathode Material in Lithium Batteries
WANG Wei-Kun, ZHANG Yong-Yong, WANG An-Bang, YU Zhong-Bao, HAN Min-Fang, YANG Yu-Sheng
School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, P. R. China; Military Power Sources Research and Development Center, Research Institute of Chemical Defense, Beijing 100191, P. R. China
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Abstract  

We investigated the use of a novel organic compound, 1,4,5,8-tetrahydroxy-9,10-anthraquinone (THAQ), and its oxidized product (O-THAQ) as cathode materials for lithium batteries. Cyclic voltammetric (CV) and charge-discharge tests of the two materials showed that during the discharge process a carbonyl-lithium enolate transformation and a hydroxyl-lithium enolate transformation occurred and the former reaction was reversible. The initial and 20th cycle capacities of O-THAQ were 250 and 100 mAh·g-1, respectively. These values were higher than those for THAQ, which showed that pre-oxidizing THAQ effectively improved its electrochemical performance. We propose a reason for this improvement.



Key wordsLithium battery      1,4,5,8-Tetrahydroxy-9,10-anthraquinone      Organic cathode material      Electrochemical performance     
Received: 19 May 2009      Published: 16 November 2009
MSC2000:  O646  
Corresponding Authors: WANG Wei-Kun     E-mail: wangweikun2002@163.com
Cite this article:

WANG Wei-Kun, ZHANG Yong-Yong, WANG An-Bang, YU Zhong-Bao, HAN Min-Fang, YANG Yu-Sheng. Electrochemical Performance of 1,4,5,8-Tetrahydroxy-9,10-anthraquinone as Cathode Material in Lithium Batteries. Acta Physico-Chimica Sinica, 2010, 26(01): 47-50.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20100105     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2010/V26/I01/47

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