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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2010,Vol.26>> Issue(01)>> 51-56     doi: 10.3866/PKU.WHXB20100112         中文摘要
ELECTROCHEMISTRY
Electrochemical Performance of LiNi0.5Mn0.5O2 as Cathode Material for Lithium-Ion Batteries Prepared by Oxalate Co-Precipitation Method
LU Hua-Quan, WU Feng, SU Yue-Feng, LI Ning, CHEN Shi, BAO Li-Ying
National Development Center of Hi-Tech Green Materials, School of Chemical Engineering & Environment, Beijing Institute of Technology, Beijing 100081, P. R. China
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The oxalate co-precipitation method was used to synthesize LiNi0.5Mn0.5O2. The effects of pH on the structure, morphology, and electrochemical performance of LiNi0.5Mn0.5O2 were investigated. The crystal structures and surface morphologies of the oxalate precursor and LiNi0.5Mn0.5O2 obtained at pH=4.0, 5.5, 7.0, 8.5 were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) methods. The electrochemical performance of LiNi0.5Mn0.5O2 was evaluated by galvanostatic charge/discharge tests. Results show that the LiNi0.5Mn0.5O2 obtained at pH=7.0 has a smaller particle size, more uniform distribution, better layered characteristics and a smaller degree of cation mixing. Electrochemical tests confirmed that the sample obtained at pH=7.0 had the best electrochemical performance. At 0.1C rate, its discharge capacity reached 185 mAh·g-1 at the first cycle and remained over 160 mAh·g-1 after the 20th cycle. X-ray photoelectron spectroscopy (XPS) results indicated that the oxidation states of Ni and Mn in the LiNi0.5Mn0.5O2 obtained at pH=7.0 were +2 and +4, respectively.



Keywords: Lithium-ion battery   Cathode material   Oxalate co-precipitation   LiNi0.5Mn0.5O2   Electrochemical performance  
Received: 2009-07-12 Accepted: 2009-09-10 Publication Date (Web): 2009-11-19
Corresponding Authors: SU Yue-Feng Email: suyuefeng@bit.edu.cn


Cite this article: LU Hua-Quan, WU Feng, SU Yue-Feng, LI Ning, CHEN Shi, BAO Li-Ying. Electrochemical Performance of LiNi0.5Mn0.5O2 as Cathode Material for Lithium-Ion Batteries Prepared by Oxalate Co-Precipitation Method[J]. Acta Phys. -Chim. Sin., 2010,26 (01): 51-56.    doi: 10.3866/PKU.WHXB20100112
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85. CHENG Feng, HUANG Ke-Long, LIU Su-Qin, FANG Xue-Song, ZHANG Xin.Surfactant Carbonization to Synthesize a Fe3O4/C Composite and Its Electrochemical Performance[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1439-1445
86. Lü Rong-Guan, YANG Jun, WANG Jiu-Lin, NULI Yan-Na.Electrodeposition and Electrochemical Property of Porous Li-Si Film Anodes for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(04): 759-763
87. TANG Yan, ZHONG Ben-He, GUO Xiao-Dong, LIU Heng, ZHONG Yan-Jun, NIE Xiang, TANG Hong.Effects of Mixed Solvents on the High-Rate Performance of Li3V2(PO4)3/C Prepared by Sol-Gel Method[J]. Acta Phys. -Chim. Sin., 2011,27(04): 869-874
88. SU Chang, LU Guo-Qiang, XU Li-Huan, ZHANG Cheng, MA Chun-An.Synthesis and Properties of Spindle-Shaped LiFePO4 for the Cathode Material of Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2011,27(03): 609-614
89. ZHANG Qiu-Mei, SHI Zhi-Cong, LI Yi-Xiao, GAO Dan, CHEN Guo-Hua, YANG Yong.Recent Advances in Fluorophosphate and Orthosilicate Cathode Materials for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(02): 267-274
90. WANG Xiao-Ya, CHENG Qian, HUANG Tao, YU Ai-Shui.Effect of Calcination Atmosphere on Li/Ni Disorder and Electrochemical Performance of Layered LiNi0.5Mn0.5O2[J]. Acta Phys. -Chim. Sin., 2011,27(02): 437-442
91. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia, ZHANG Jin-Qiu.Cathodic and Thermal Stabilities of the P(VdF-HFP)-Based Ionic Liquid Composite Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2011,27(01): 78-84
92. DENG An-Qiang, FAN Jing-Bo, QIAN Ke-Nong, LUO Yong-Chun.Effect of Heat Treatment on the Structure and Properties of La4MgNi19 Hydrogen Storage Electrode Alloys[J]. Acta Phys. -Chim. Sin., 2011,27(01): 103-107
93. CHEN Shi-Yu, WANG Zhao-Xiang, FANG Xiang-Peng, ZHAO Hai-Lei, LIU Xiao-Jiang, CHEN Li-Quan.Characterization of TiS2 as an Anode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(01): 97-102
94. ZHANG Lei-Yong, HE Shui-Jian, CHEN Shui-Liang, GUO Qiao-Hui, HOU Hao-Qing.Preparation and Electrochemical Properties of Polyaniline/Carbon Nanofiber Composite Materials[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3181-3186
95. ZHOU Xiao-Ling, HUANG Rui-An, WU Zhao-Cong, YANG Bin, DAI Yong-Nian.Synthesis and Electrochemical Properties of High-Rate Spinel Li4Ti5Ol2/TiN Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3187-3192
96. ZHANG Qiao-Bao, FENG Zeng-Fang, HAN Nan-Nan, LIN Ling-Ling, ZHOU Jian-Zhang, LIN Zhong-Hua.Preparation and Photoeletrochemical Performance of CdS Quantum Dot Sensitized ZnO Nanorod Array Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2927-2934
97. CHANG Zhao-Rong, DAI Dong-Mei, LI Bao, TANG Hong-Wei.Effect of Hydrazine on the Performance of LiNi0.5Mn1.5O4Cathode Materials[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2633-2637
98. LI Ya-Juan, ZHAN Hui, LIU Su-Qin, HUANG Ke-Long, ZHOU Yun-Hong.Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2387-2391
99. LUO Yong-Chun, ZHANG Tie-Jun, WANG Duo, KANG Long.Influence of Ball-Milling on Hydrogen Storage and Electrochemical Properties of (Ti Cr)0.497V0.42Fe0.083/30%(w) (LaRMg)(NiCoAl)3.5 Alloy Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2397-2404
100. YANG Su-Xia, LI Yuan, LIU Zhi-Ping, YANG Shu-Qin, HAN Shu-Min.Effect of Partial Substitution of Cu by Fe on the Phase Structure and Electrochemical Property of Low-Co AB5 Type Hydrogen Storage Alloys[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2144-2150
101. DAI Ke-Hua, MAO Jing, ZHAI Yu-Chun.High Rate Capability of 5 V LiNi0.5Mn1.5O4 Cathode Materials Synthesized via a Gel-Combustion Method[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2130-2134
102. QIU Xiang-Yun, ZHUANG Quan-Chao, WANG Hong-Ming, CUI Yong-Li, FANG Liang, SUN Shi-Gang.Influence of Electrolyte Composition on the Intercalation-Deintercalation Process of Lithium Ion in Spinel LiMn2O4[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1499-1506
103. QU Xiao-Hua, LIU Jie, WANG Zhao-Xiang, CAO Dian-Liang, FANG Xiang-Peng, ZHANG Ling, DUAN Jing-Lai, YAO Hui-Jun, CHEN Yan-Feng, SUN You-Mei, HOU Ming-Dong.Preparation of Microporous Membranes by Swift Heavy Ion Irradiation and Impedance Characterization[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1722-1726
104. ZHANG Xiao-Yu, JIANG Wei-Jun, ZHU Xiao-Pei, QI Lu.Characterization of LiNi1/3Mn1/3Co1/3O2 Synthesized by Wet-Chemical Method[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1507-1514
105. ZHANG Hui-Juan, SONG Huai-He, ZHOU Ji-Sheng, ZHANG Hong-Kun, CHEN Xiao-Hong.Preparation and Electrochemical Properties of SnO2/Onion-Like Hollow Carbon Nanoparticle Composites as Anode Materials for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1259-1263
106. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia.Preparation of an Ionic Liquid Gel Polymer Electrolyte and Its Compatibility with a LiFePO4 Cathode[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1233-1238
107. CHANG Yu-Qing, HUANG Ling, SUN Shi-Gang.Electrodeposition and Electrochemical Properties of Ternary Sn-Co-Zn Alloy Electrodes as Anodes for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(03): 561-566
108. XIONG Li-Zhi, HE Ze-Qiang.A New Rheological Phase Route to Synthesize Nano-LiVOPO4 Cathode Material for LithiumIon Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(03): 573-577
109. CHANG Zhao-Rong, YU Xu, TANG Hong-Wei, WEI Wen-Qiang, DAI Dong-Mei.Influence of Al Doping Content on the Structure and Electrochemical Properties of LiNi1/3Co2/3-xAlxO2[J]. Acta Phys. -Chim. Sin., 2010,26(03): 567-572
110. JIANG Lei, HUANG Hui, WANG Chun-Tao, ZHANG Wen-Kui, GAN Yong-Ping, TAO Xin-Yong.Photoelectrochromic Properties of TiO2-xNx/NiO Bilayer Thin Films[J]. Acta Phys. -Chim. Sin., 2010,26(02): 299-303
111. WANG Wei-Kun, ZHANG Yong-Yong, WANG An-Bang, YU Zhong-Bao, HAN Min-Fang, YANG Yu-Sheng.Electrochemical Performance of 1,4,5,8-Tetrahydroxy-9,10-anthraquinone as Cathode Material in Lithium Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(01): 47-50
112. YU Hong-Ming, ZHENG Wei, CAO Gao-Shao, ZHAO Xin-Bing.Effects of Optimized Carbon-Coating on High-Rate Performance of LiFePO4/C Composites[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2186-2190
113. TAN Xiao-Lan, CHENG Xin-Qun, MA Yu-Lin, ZUO Peng-Jian, YIN Ge-Ping.Film Formation and Cycleability of LiBOB-Based Electrolyte[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1967-1971
114. SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
115. ZHENG Jun-Chao, LI Xin-Hai, WANG Zhi-Xing, LI Jin-Hui, WU Ling, LI Ling-Jun, GUO Hua-Jun.A Coalescence Mechanism for the Composite Cathode Material xLiFePO4·yLi3V2(PO4)3[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1916-1920
116. ZHONG Mei-E, ZHOU Zhi-Hui, ZHOU Zhen-Tao.Electrochemical Performance of High-Density LiFePO4/C Composites Synthesized by Solid State-Carbothermal Reduction Method[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1504-1510
117. JIANG Dong-Dong, FU Yan-Bao, MA Xiao-Hua.Fabrication and Characterization of Tin Nanorod Electrodes for Lithium Ion Rechargeable Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1481-1484
118. FENG Ji-Jun, LIU Xiang-Zhe, LIU Xiao-Zhen, JIANG Jian-Zhuang, ZHAO Jing.Hydrothermal Syntheses and Properties of LiV3-xMnxO8 as Cathode Materials for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1490-1494
119. SU Zhi, XU Mao-Wen, YE Shi-Hai, WANG Yong-Long.Doping of Layered LiMnO2 as Cathode Materials for Lithium-Ion Batteries and Their Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1232-1238
120. HU Guo-Rong, CAO Yan-Bing, PENG Zhong-Dong, DU Ke, JIANG Qing-Lai.Preparation of Li2FeSiO4 Cathode Material for Lithium-Ion Batteries by Microwave Synthesis[J]. Acta Phys. -Chim. Sin., 2009,25(05): 1004-1008
121. GAO Hong-Quan, LAI Yan-Qing, ZHANG Zhi-An, LIU Ye-Xiang.Electrochemical Behaviors of New Lithium Salt LiBC2O4F2 in EC+DMC Solvents[J]. Acta Phys. -Chim. Sin., 2009,25(05): 905-910
122. FAN Xiao-Yong, ZHUANG Quan-Chao, WEI Guo-Zhen, KE Fu-Sheng, HUANG Ling, DONG Quan-Feng, SUN Shi-Gang.Fabrication and Performance of Cu6Sn5 Alloy Anode Using Porous Cu as Current Collector[J]. Acta Phys. -Chim. Sin., 2009,25(04): 611-616
123. WU Feng, WANG Meng, SU Yue-Feng, CHEN Shi.Surface Modification of LiCo1/3Ni1/3Mn1/3O2 by TiO2-Coating[J]. Acta Phys. -Chim. Sin., 2009,25(04): 629-634
124. ZHUANG Quan-Tiao, WEI Guo-Zhen, DONG Quan-Feng, SUN Shi-Gang.Influence of Temperature on the Performance of a Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(03): 406-410
125. ZHANG Guo-Qiang, MA Li, WU Zhong-Jie, ZHANG Hai-Yan, NI Pei.Electrochemical Behaviour of the Composite Polymer Electrolyte P(VDF-HFP)-PMMA/CaCO3(SiO2)[J]. Acta Phys. -Chim. Sin., 2009,25(03): 555-560
126. MA Ruo-Biao, FU Yan-Bao, MA Xiao-Hua.Preparation and Electrochemical Performance of Tin-Dioxide Filled Multi-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2009,25(03): 441-445
127. DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
128. LI Yang; XIE Hua-Qing; TU Jiang-Ping.SnS with Various Morphologies and Sizes as Anode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(02): 365-370
129. XU Jie; YAO Wan-Hao; YAO Yi-Wen; WANG Zhou-Cheng; YANG Yong.Effect of Fluoroethylene Carbonate Additive on the Performance of Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2009,25(02): 201-206
130. JIA Yan-Min; LIU Fei-Ye; XIAO Xue-Zhang; HANG Zhou-Ming; LEI Yong-Quan; CHEN Li-Xin.Microstructure and Electrochemical Properties of V2.1TiNi0.4Zr0.06Cu0.03M0.10 (M=Cr, Co, Fe, Nb, Ta) Hydrogen Storage Alloys[J]. Acta Phys. -Chim. Sin., 2009,25(02): 247-252
131. ZHANG Wei; CUI Xiao-Li; JIANG Zhi-Yu.Effect of Composite Modes on Photoelectrochemical Properties of MWCNTs/TiO2 Nanocomposite Films[J]. Acta Phys. -Chim. Sin., 2008,24(11): 1975-1980
132. LIU Fei-Ye; CHEN Li-Xin; LI Lu; JIA Yan-Min; LEI Yong-Quan.Microstructure and Electrochemical Properties of V2.1TiNi0.4Zr0.06Cux (x=0-0.12) Hydrogen Storage Alloys[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1694-1698
133. JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
134. YANG Shun-Yi; WANG Xian-You; WEI Jian-Liang; LI Xiu-Qin; TANG An-Ping.Preparation and Electrochemical Performance of Na-Mn-O Cathode Materials[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1669-1674
135. HUANG Jun-Jie; JIANG Zhi-Yu.Electrochemical Performance of LiMn2O4 Thin Film Electrode Fabricated by Ink-Jet Printing Technique[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1563-1567
136. ZHANG Hua; ZHOU Yong-Ning; WU Xiao-Jing; FU Zheng-Wen.Electrochemical Properties of CuF2 Films Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1287-1291
137. LI Fan-Qun; LAI Yan-Qing; ZHANG Zhi-An; GAO Hong-Quan; YANG Juan.Electrochemical Behaviors of Et4NBF4+LiPF6/EC+PC+DMC Electrolyte on Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1302-1306
138. WANG Meng; WU Feng; SU Yue-Feng; CHEN Shi.Electrochemical Characteristics of Y2O3-Coated LiCo1/3Ni1/3Mn1/3O2[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1175-1179
139. WEN Qing; LIU Zhi-Min; CHEN Ye; LI Kai-Feng; ZHU Ning-Zheng.Electrochemical Performance of Microbial Fuel Cell with Air-Cathode[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1063-1067
140. WANG Jian-Hua; LI Bin; WU Hai-Yan; GUO Yu-Zhong.Synthesis of Mesoporous SnO2 and Its Application in Lithium-Ion Battery[J]. Acta Phys. -Chim. Sin., 2008,24(04): 681-685
141. CHANG Zhao-Rong; CHEN Zhong-Jun; WU Feng; TANG Hong-Wei; ZHU Zhi-Hong.Synthesis of LiNi1/3Co1/3Mn1/3O2 Cathode Material by Eutectic Molten Salt LiOH-LiNO3[J]. Acta Phys. -Chim. Sin., 2008,24(03): 513-519
142.

DU Guo-Dong; NULI Yan-Na; FENG Zhen-Zhen; WANG Jiu-Lin; YANG Jun

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143. GUO Ying-Jun; LI Qi-Qi-Ge; NING Ying-Kun; QI Lu; TANG Hong-Wu.Performance of Liquid Electrolyte for Lithium-ion Battery at Elevated-temperature[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 1-4
144. WANG Ya-Dan; WANG Jian; MU Qi-Yong; LI Yong-Wei; QI Lu.Electrochemical Performances of LiMn2O4-based Electrode with Water-soluble Binder[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 14-17
145. QI Lu; SONG Zhao-Shuang; XU Hua; MAO Yong-Zhi; WU Ning-Ning; LIU Zheng-Yao.Electrochemical Performance of LithiumIon Battery Power Syetemfor Electric Vehicles[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 21-25
146. ZHANG Chun-Ling; JIANG Wei-Jun; ZHANG Jing; QI Lu.Performance of LiMn1.5Ni0.5-xCuxO4 as 5V Cathode Material for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 31-35
147. TANG Ding-Guo.Application of Polymer LithiumIon Batteries Based on IPN[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 18-20
148. HOU Xian-Quan; JIANG Wei-Jun; QI Lu; HAN Li-Juan.Synthesis and Properties of Layered LiNi0.8Co0.2-xMgxO2 Cathode Material[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 40-45
149. CHEN Yong-Chong; XU Xing-Jun; CUI Hong-Zhi; DAI Ke-Hua; SONG Zhao-Shuang; JIANG Wei-Jun; QI Lu.Synthesis Mechanisms and Properties of Cathode Material LiNixMn2-xO4[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 26-30
150. FAN Mao-Song; LEI Xiang-Li; WU Ning-Ning; QI Lu.Electrochemical Performance of LiMn2O4 Power Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 36-39
151. JIANG Wei-Jun; Sai-Xi-Ya-Le-Tu; Wu-Yun-Bi-Li-Ge; QI Lu; SHANG Shi-Bo.Performance of Nonstoichiometric Li1+xCoO2 Cathode Materials[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 56-59
152.

WANG Jian; QI Yu-Jun; LI Yong-Wei; QI Lu

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153. WANG Hai-Yan; LIU Xin-Hou; WU Da-Yong.Electrospinning and Electrospun Membranes[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 67-74
154. AN Hong-Li; WU Ning-Ning; LEI Xiang-Li; XU Jin-Long; QI Lu.Electrochemical Performance of LithiumIon Battery for Plug-in Hybrid Electric Vehicle Applications[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 60-66
155. GUO Ying-Jun; CHEN Hui; QI Lu.Progress in Electrolyte Solutions for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 80-89
156. LEE Meng-Lung; LEE Yi-Da; CHANG Chie-Tai; GAO Tong-Han; LEE Torng-Jinn.Application and Technology of Aluminum Bag Lithium-Ion Polymer Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 100-106
157. FENG Hua-Jun; CHEN Yuan;DAI Ke-Hua; SONG Zhao-Shuang; MA Jian-Wei; QI Lu.Preparation and Characterization of a Novel Kind of Polymer Electrolyte Composite Membrane for Lithium-Ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1922-1926
158. DAI Ke-Hua; WANG Yin-Jie; FENG Hua-Jun; XIE Yan-Ting; QI Lu.Preparation Conditions of LiMn0.45Ni0.45Co0.1O2 via Hydroxide Co-precipitation[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1927-1931
159. CHEN Yong-Chong; XU Xing-Jun; CUI Hong-Zhi; DAI Ke-Hua; SONG Zhao-Shuang; JIANG Wei-Jun; QI Lu.Preferred Orientation of Crystals and the Intensity Ratios of XRD Peaks of Cathode Material LiCoO2[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1948-1953
160. HOU Chun-Ping; YUE Min.A Novel Cathode Material Lithium Vanadium Phosphate Synthesized by Liquid-phase Sphericizing Granulation[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1954-1957
161. TANG Hong-Wei; ZHU Zhi-Hong; CHANG Zhao-Rong; CHEN Zhong-Jun.Drawing and Application of Phase Diagram Related to Eutectic Mixed Lithium Salts[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1265-1268
162. WEI Ying-Jin; LI Xu; WANG Chun-Zhong; ZHAN Shi-Ying; CHEN Gang.Preparation and Electrochemical Properties of Cu Doped V2O5[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1090-1094
163. ZHANG Hong-Fang; FU Ping-Ping; SONG Ying-Jie; DU Chen-Shu; YANG Hua-Bin; ZHOU Zuo-Xiang; WU Meng-Tao; HUANG Lai-He.Preparation and Properties of Sandwich-type Si/Fe/Si Film Anode for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1065-1070
164. LIU Su-Qin; GONG Ben-Li; HUANG Ke-Long; ZHANG Ge; LI Shi-Cai.Effect of Calcination Temperature on the Compositions and Electrochemical Performance of Products in the Synthesis of LiFePO4[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1117-1122
165. LIU Su-Qin; LI Shi-Cai; HUANG Ke-Long; CHEN Zhao-Hui.Effect of Doping Ti4+ on the Structure and Performances of Li3V2(PO4)3[J]. Acta Phys. -Chim. Sin., 2007,23(04): 537-542
166. FENG Zhen-Zhen;NULI Yan-Na;YANG Jun.Conductive Sulfur-Containing Material/Polyaniline Composite for Cathode Material of Rechargeable Magnesium Batteries[J]. Acta Phys. -Chim. Sin., 2007,23(03): 327-331
167. HUANG Ke-Long;YANG Sai;LIU Su-Qin;WANG Hai-Bo.Kinetics of Electrode Processes of LiFePO4 in Saturated Lithium Nitrate Solution[J]. Acta Phys. -Chim. Sin., 2007,23(01): 129-133
168. TANG Zhi-Yuan;YU Ming-Yuan;XUE Jian-Jun;GAO Fei;CUI Yan;LI Liang-Dong.Electrochemical Properties and Synthesis of LiNi0.01Co0.01Mn1.98O4 by SAC Route for Lithium Secondary Battery[J]. Acta Phys. -Chim. Sin., 2007,23(01): 134-138
169. QIN Hai-Ying;XIE Jian;MI Jian-Li;TU Jian;ZHAO Xin-Bing.Solvothermal Synthesis and Electrochemical Lithiation/Delithiation Performance of FeSb2 Nanorods[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1555-1559
170. HUANG Ling;JIANG Hong-Hong;KE Fu-Sheng;FAN Xiao-Yong;ZHUANG Quan-Chao;YANG Fang-Zu;SUN Shi-Gang.Structure and Properties of Three-dimensional Reticular Sn-Co Alloy Electrodes as Anode Material for Lithium Batteries[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1537-1541
171. XU Yu-Hong;ZHANG Bao-Hong;GONG GUI-Ying;MA Ping .Electrochemical Properties Study of Sb2O3 doped Li4Ti5O12[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1336-1341
172. XIE Jian;ZHAO Xin-Bing;YU Hong-Ming;QI Hao;CAO Gao-Shao;TU Jiang-Ping .Preparation, Characterization and Electrochemical Li-absorption/extraction Behaviors of Nanosized Co-Sn Intermetallic Compounds[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1409-1412
173. LI Chang-Yu;LÜ Zhe;LIU Li-Li;LIU Zhi-Ming;SU Wen-Hui.Preparation and Performance Test of Ni-Fe/SDC Cell Anode[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1181-1184
174. ZHUANG Da-Gao;ZHAO Xin-Bing;XIE Jian;TU Jian;ZHU Tie-Jun;CAO Gao-Shao.One-step Solid-state Synthesis and Electrochemical Performance of Nb-doped LiFePO4/C[J]. Acta Phys. -Chim. Sin., 2006,22(07): 840-844
175. TANG Ding-Guo;CI Yun-Xiang;QI Lu.Influence of Thermal Initiators on the Electrochemical Performances of Gel Polymer Electrolytes[J]. Acta Phys. -Chim. Sin., 2006,22(07): 826-830
176. WANG Zhong;TIAN Wen-Huai;LI Xing-Guo.Synthesis and Electrochemical Properties of Sn-Sb Alloy Prepared by Hydrogen Plasma-metal Reaction[J]. Acta Phys. -Chim. Sin., 2006,22(06): 752-755
177. CHEN Li-Xin;LI Lu;WANG Xin-Hua;DAI Fa-Bang;ZHENG Fang-Ping;LEI Yong-Quan.Phase Structures and Electrochemical Properties of V2.1TiNi0.4Zrx(x= 0~0.06) Hydrogen Storage Electrode Alloys*[J]. Acta Phys. -Chim. Sin., 2006,22(05): 523-527
178. YI Shuang-Ping;ZHANG Hai-Yan;PEI Lei;HU Shou-Le;ZENG Guo-Xun;CHEN Jin.Effect of CNTs Treated at Different Temperatures in Nitrogen Ambient on the Electrochemical Properties of CNTs-LaNi5 Electrodes[J]. Acta Phys. -Chim. Sin., 2006,22(04): 436-440
179. XUE Ming-Zhe; CHENG Sun-Chao; YAO Jia; FU Zheng-Wen.Electrochemical Properties of SnSe Thin Film Electrode Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2006,22(03): 383-387
180. XU Meng-Qing; ZUO Xiao-Xi; LI Wei-Shan; ZHOU Hao-Jie; LIU Jian-Sheng; YUAN Zhong-Zhi.Effect of Butyl Sultone on the Li-ion Battery Performance and Interface of Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2006,22(03): 335-340
181. ZHUANG Quan-chao; FAN Xiao-yong; XU Jin-mei; CHEN Zuo-feng; DONG Quan-feng; JIANG Yan-xia; HUANG Ling; SUN Shi-gang.Electrochemical Impedance Spectroscopic Study of the First Delithiation of Spinel Lithium Manganese Oxide[J]. Acta Phys. -Chim. Sin., 2006,22(02): 234-238
182. YANG Xiao; NI Jiang-feng; HUANG You-yuan; CHEN Ji-tao; ZHOU Heng-hui; ZHANG Xinxiang.Effect of Ti-Doping on Different Morphologic LiCoO2[J]. Acta Phys. -Chim. Sin., 2006,22(02): 183-188
183. WANG Ying; LIU Wen-yuan; FU Zheng-wen.Electrochemistry of Mn4N with Lithium[J]. Acta Phys. -Chim. Sin., 2006,22(01): 65-70
184. WANG Guo-guang WANG Jian-ming MAO Wen-qu LIU Li-qing ZHANG Jian-qing CAO Chu-nan.Structure and Electrochemical Performance of LiNiyCo0.1-yMn1.9O4 Cathode Materials Prepared by a Precipitation Method[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1285-1290
185. TANG Xin-cun; HUANG Bo-yun; HE Yue-hui.Dependence of Li+ Diffusion Coefficients in LiMn2O4 on Charge/Discharge Cycles[J]. Acta Phys. -Chim. Sin., 2005,21(09): 957-960
186. TANG Zhi-yuan; LU Xing-he; ZHANG Na.The Anion-cation Multiple Doping Effect of Spinel Cathode Materials on Electrochemical Speciality[J]. Acta Phys. -Chim. Sin., 2005,21(08): 934-938
187. HUANG You-yuan; ZHOU Heng-hui; CHEN Ji-tao; GAO De-shu; SU Guang-yao.The Effect of Ti4+, Mg2+ Co-doping on Performance of LiNi0.4Co0.2Mn0.4O2[J]. Acta Phys. -Chim. Sin., 2005,21(07): 725-729
188. XUE Ming-zhe; FU Zheng-wen.Electrochemical Properties of LiFePO4 Cathode Thin Film Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2005,21(07): 707-710
189. LIU Chun-ling; WEN Yue-hua; CHENG Jie; GUO Quan-gui; CAO Gao-ping; LIU Lang; YANG Yu-sheng.Influence of Pore Structure of Phenolic Resin Based Activated Carbon Fibers on the Electrochemical Performance of Electrical Double-layer Capacitors[J]. Acta Phys. -Chim. Sin., 2005,21(07): 786-791
190. WU Mei-Yin; WANG Jian-Ming; ZHANG Jian-Qing; CAO Chu-Nan.Structure and Electrochemical Performance of Mn-substituted Nickel Hydroxide[J]. Acta Phys. -Chim. Sin., 2005,21(05): 523-527
191. XIAO Xue-Zhang; CHEN Chang-Pin; WANG Xin-Hua; CHEN Li-Xin; WANG Li; GAO Lin-Hui.Microstructure and Electrochemical Properties of Amorphous Mg-Fe-Ni Hydrogen Storage Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(05): 565-568
192. TAO Bin-Wu;LIU Jian-Hua;LI Song-Mei;ZHAO Liang.Electrochemical Properties of a V2O5/C Composite in Aqueous Solution Used for Zinc Secondary Battery[J]. Acta Phys. -Chim. Sin., 2005,21(03): 338-342
193. LU Jun-Biao; TANG Zi-Long; ZHANG Zhong-Tai; JIN Yong-Zhu.Influence of Mg Ion Doping on the Battery Properties of LiFePO4/C[J]. Acta Phys. -Chim. Sin., 2005,21(03): 319-323
194. TANG Zhi-Yuan;ZHANG Na;LU Xing-He;HUANG Qing-Hua.Characterizations of Spinel LiMn2-xZrxO4 Cathode for Lithium-ion Batteries[J]. Acta Phys. -Chim. Sin., 2005,21(01): 89-92
195. Wang Wei-Kun; Wang An-Bang; Cao Gao-Ping; Yang Yu-Sheng.Electrochemical Performance of a Novel Cathode Material Phenyl Polysulfide for Lithium Batteries[J]. Acta Phys. -Chim. Sin., 2004,20(12): 1440-1444
196. Chang Xiao-Yan;Wang Zhi-Xing;Li Xin-Hai;Kuang Qiong;Peng Wen-Jie;Guo Hua-Jun;Zhang Yun-He.Synthesis and Performance of LiMnPO4 Used as Cathode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2004,20(10): 1249-1252
197. Wang Zhi-Xing;Xing Zhi-Jun;Li Xin-Hai;Guo Hua-Jun;Peng Wen-Jie.Study on Al2O3-modified LiMn2O4 Prepared by Heterogeneous Nucleation[J]. Acta Phys. -Chim. Sin., 2004,20(08): 790-794
198. Ni Jiang-Feng;Zhou Heng-Hui;Chen Ji-Tao;Su Guang-Yao.Effect on the Electrochemical Performance of Lithium Iron Phosphate by Cr3+ Ion Doping[J]. Acta Phys. -Chim. Sin., 2004,20(06): 582-586
199. Liu En-Hui;Li Xin-Hai;Hou Zhao-Hui;He Ze-Qiang;Deng Ling-Feng.Chemical Diffusion Behaviors of Lithium-ion in the LiV3O8 Prepared by Wet Method Reaction[J]. Acta Phys. -Chim. Sin., 2004,20(04): 377-381
200. Zhao Shi-Xi;Min Xin-Min;Liu Han-Xing;Li Qiang;Ouyang Shi-Xi.The Structural Stability of S-M (M=Al, Co) Co-doped Spinel LiMn2O4 Cathode Materials[J]. Acta Phys. -Chim. Sin., 2004,20(03): 233-236
201. Yang Hong-Ping;Wang Xian-You;Wang Xing-Yan;Huang Wei-Guo;Luo Xu-Fang;Zhuo Hai-Tao.Preparation and Performance of Electrode Materials for Super-iron (VI) Battery[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1150-1153
202. Wang Zhan-Liang;Tang Zhi-Yuan.Research on the Interfacial Properties of Polymer Electrolyte by A.C.Impedance[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1097-1101
203. Li Jian-Gang;Wan Chun-Rong;Yang Dong-Ping;Yang Zhang-Ping.Effect of Cell Temperature on the Electrochemical Reaction of LiNi3/8Co2/8Mn3/8O2[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1030-1034
204. Tang Zhi-Yuan;Xu Guo-Xiang.The Application of Poly (1-aminoanthraquinone) for Positive Electrode Material in Lithium Secondary Battery[J]. Acta Phys. -Chim. Sin., 2003,19(04): 307-310
205. Chen Ji-Tao;Zhou Heng-Hui;Chang Wen-Bao;Ci Yun-Xiang.Effect of Particle Size on Lithium Intercalation Performance of Graphite Anode[J]. Acta Phys. -Chim. Sin., 2003,19(03): 278-282
206. Tang Xin-Cun;He Li-Ping;Chen Zong-Zhang;Xia Xi.Determination of the Li+ Diffusion Coefficient in Graphite By the Method of the Ratio of Potentio-charge Capacity to Galvano-charge Capacity[J]. Acta Phys. -Chim. Sin., 2002,18(08): 705-709
207. Zhao Zhuan-Qing;Yao Su-Wei;Zhang Wei-Guo;Gong Zheng-Lie.Preparation and Photoelectrochemical Performance of Photoelectrode of TiO2 Film on Nickel[J]. Acta Phys. -Chim. Sin., 2002,18(05): 473-476
208. Wang Zhan-Liang;Tang Zhi-Yuan;Geng Xin;Xue Jian-Jun.Research on Novel PMMAbased Gel Electrolyte for Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2002,18(03): 272-275
209. Zhao Ming-Shu;Zhai Yu-Chun;Tian Yan-Wen.Study on Kinetics of Synthesizing Spinel LiMn2O4 for Lithium-ion Battery Cathode[J]. Acta Phys. -Chim. Sin., 2002,18(02): 188-192
210. Chen Ji-Tao;Zhou Heng-Hui;Chang Wen-Bao;Ci Yun-Xiang.pyrolytic Carbon Coated Graphite Anode for Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2002,18(02): 180-182
211. Tang Zhi-Yuan;Xue Jian-Jun;Li Jian-Gang;Wang Zhan-Liang.Discharge Process of Insertion Electrodes Controlled by Lithium Ion Diffusion in Solid Materials[J]. Acta Phys. -Chim. Sin., 2001,17(06): 526-530
212. Tang Zhi-Yuan;Xue Jian-Jun;Liu Chun-Yan;Zhuang Xin-Guo.Determination of the Lithium Ion Diffusion Coefficient in Graphite Anode Material[J]. Acta Phys. -Chim. Sin., 2001,17(05): 385-388
213. Li Ming, Yang Hua-Quan.Lithiation Behavior of α-Fe2O3 in LiOH Electrolyte Solution[J]. Acta Phys. -Chim. Sin., 2000,16(08): 735-740
214. Zhou Heng-Hui, Chen Ji-Tao, Ci Yun-Xiang, Liu Chang-Yan.A Simple Method to Evaluate Lithium Insertion Capacity of PPP-based Carbon[J]. Acta Phys. -Chim. Sin., 1998,14(05): 477-480
215. TANY Yan-Ping, YUAN Sha, GUO Yu-Zhong, HUANG Rui-An, WANG Jian-Hua, YANGBin, DAI Yong-Nian.Magnesiothermic Reduction Preparation and Electrochemical Properties of Highly Ordered Mesoporous Si/C Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
216. HUANG Wei, WU Chun-Yang, ZENG Yue-Wu, JIN Chuan-Hong, ZHANG Ze.Surface Analysis of Lithium-Rich Cathode Material Li1.2Mn0.54Co0.13Ni0.13NaxO2 by Advanced Electron Microscopy[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
217. WANG Jing-Lun, YAN Xiao-Dan, YONG Tian-Qiao, ZHANG Ling-Zhi.Nitrile Modified 2,5-Di-tert-butyl-Hydroquinone as Redox Shuttle Overcharge Additive for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 0,(): 0-0
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