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Acta Physico-Chimica Sinica  2010, Vol. 26 Issue (10): 2733-2738    DOI: 10.3866/PKU.WHXB20101007
Photoinduced Charge Carrier Properties and Photocatalytic Activity of N-Doped TiO2 Nanocatalysts
ZHANG Xiao-Ru, LIN Yan-Hong, ZHANG Jian-Fu, HE Dong-Qing, WANG De-Jun
College of Chemistry, Jilin University, Changchun 130012, P. R. China
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Nitrogen-doped TiO2 (N-TiO2) photocatalysts with different amounts of N doping were successfully synthesized by the hydrothermal method using urea as the nitrogen source. The samples were characterized by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV -Vis DRS),X -ray photoelectron spectroscopy (XPS), and photoluminescence (PL) spectroscopy. The photodegradation of rhodamineB (RhB) and methyl orange (MO) solutions was used to evaluate the photocatalytic activity of the catalysts under UV and visible light irradiation. Surface photovoltage (SPV) and transient photovoltage (TPV) techniques were used to investigate the separation and transport mechanism of the photogenerated charge carriers of the N-doped TiO2 nanoparticles. The relationship between the photogenerated charge carriers and photocatalytic activity was also discussed. The results showed that the SPV threshold values shifted to the visible region and a stronger photovoltaic response in the visible region was observed with an increase in N doping. We also found that the maximum TPV response time was different for N-TiO2. These results indicate that with an appropriate amount of N doping, the photoinduced charge carriers separate efficiently, the transmission time increases, and the lifetime of the photoinduced charge carriers increases. Therefore, the photocatalytic activity is enhanced. However, excessive N acts as recombination centers for photoinduced electrons and holes, which reduces their photocatalytic activity.


Key wordsN-doped TiO2      Surface photovoltage      Transient photovoltage      Photo-induced charge carrier      Photocatalytic activity     
Received: 21 May 2010      Published: 27 September 2010
MSC2000:  O643  

The project was supported by the National Key Basic Research Programof China (973) (2007CB613303), National Natural Science Foundation of China (20703020, 20873053), and Scientific Forefront and Interdisciplinary Innovation Project, Jilin University, China (421031401412).

Corresponding Authors: LIN Yan-Hong     E-mail:
Cite this article:

ZHANG Xiao-Ru, LIN Yan-Hong, ZHANG Jian-Fu, HE Dong-Qing, WANG De-Jun. Photoinduced Charge Carrier Properties and Photocatalytic Activity of N-Doped TiO2 Nanocatalysts. Acta Physico-Chimica Sinica, 2010, 26(10): 2733-2738.

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1. Mor, G. K.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes, C. A. Nano Lett., 2006, 6: 215
2. Konstantinau, I. K.; Albanis, T. A. Appl. Catal. B, 2003, 42: 319
3. Sakthivel, S.; Kisch, H. Angew. Chem. Int. Edit., 2003, 42: 4908
4. Hua, N. P.;Wu, Z. Y.; Du, Y. K.; Zou, Z. G.; Yang, P. Acta Phys. - Chim. Sin., 2005, 21: 1081 [华南平, 吴尊义,杜玉扣, 邹志刚, 杨平. 物理化学学报, 2005, 21: 1081]
5. Asahi, R.; Morikawa, T.; Ohwaki, T.; Aoki, K.; Taga, Y. Science, 2001, 293: 269
6. Lin, Z. S.; Orlov, A.; Lambert, R. M.; Payne, M. J. Phys. Chem. B, 2005, 109: 20948
7. Kuroda, Y.; Mori, T.; Yagi, K.; Makihata, N.; Kawahara, Y.; Nagao, M.; Kittaka, S. Langmuir, 2005, 21: 8026
8. Kisch, H.; Sakthivel, S.; Janczarek, M.; Mitoraj, D. J. Phys. Chem. C, 2007, 111: 11445
9. Yang, K. S.; Dai, Y.; Huang, B. B. J. Phys. Chem. C, 2007, 111: 12086
10. Tian, F. H.; Liu, C. B. J. Phys. Chem. B, 2006, 110: 17866
11. Zhou, Y. K.; Holme, T.; Berry, J.; Ohno, T. R.; Ginley, D.; Hayre, R. O. J. Phys. Chem. C, 2010, 114: 506
12. Li, J. Y.; Lu, N.; Quan, X.; Chen, S.; Zhao, H. M. Ind. Eng. Chem. Res., 2008, 47: 3804
13. Linsebigler, A. L.; Lu, G. Q.; Yates, J. T. Chem. Rev., 1995, 95: 735
14. Monllor-Satoca, D.; Gómez, R. J. Phys. Chem. C, 2008, 112: 139
15. Gross, D.; Mora-Seró, I.; Dittrich, T.; Belaidi, A.; Mauser, C.; Houtepen, A. J.; Como, E. D.; Rogach, A. L.; Feldmann, J. J. Am. Chem. Soc., 2010, 132: 5981
16. Duzhko, V.; Timoshenko, V. Y.; Koch, F.; Dittrich, T. Phys. Rev. B, 2001, 64: 075204
17. Alexander, D. Q.; Li, L. S. J. Phys. Chem. B, 2004, 108: 12842
18. Huang, D. G.; Liao, S. J.; Zhou,W. B.; Quan, S. Q.; Liu, L.; He, Z. J.;Wan, J. B. J. Phys. Chem. Sol., 2009, 70: 853
19. Sathishi, M.; Viswanathan, B.; Viswanath, R. P.; Gopinath, C. S. Chem. Mater., 2005, 17: 6349
20. Li, H.; Li, J.; Huo, Y. J. Phys. Chem. B, 2006, 110: 1559
21. Burda, C.; Lou, Y.; Chen, X.; Samia, A. C. S.; Stout, J.; Gole, J. M. Nano Lett., 2003, 3: 1049
22. Valentin, C. D.; Pacchioni, G.; Selloni, A.; Livraghi, S.; Giamello, E. J. Phys. Chem. B, 2005, 109: 11414
23. Kronik, L.; Shapira, Y. Surf. Sci. Rep., 1999, 371: 206
24. Liu, E. K.; Zhu, B. S.; Luo, J. S. Semiconductor physics. Beijing: Electronics Industry Press, 2003: 98-100 [刘恩科,朱秉升, 罗晋 生.半导体物理学.北京: 电子工业出版社, 2003: 98-100]
25. Wei, X.; Xie, T. F.; Xu, D.; Zhao, Q. D.; Pang, S.; Wang, D. J. Nanotechnology, 2008, 19: 275707

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