表面活性剂水溶液的电导率研究方法和一些特征数据的提取

doi:10.3866/PKU.WHXB20101019

Abstract

Abstract:

Conductivity is important in the investigation of the micellization behavior of ionic surfactants in an aqueous solution. We review this sensitive technique and discuss methods to determine the critical micelle concentration (cmc) and the degree of dissociation of the micelle( α) in detail. We also investigatea special situation analysis for conductivity curves and premicellar behavior. This method is useful for the investigation of surfactant systems in which strong intermolecular interactions occur.

Key words: Ionic surfactant, Conductivity, Characteristic parameters

MSC2000:

O648

ZHAO Jian-Xi. Conductivity for the Investigation of Ionic Surfactants in an AqueousSolution and Some Characteristic Parameters[J].Acta Phys. -Chim. Sin., 2010, 26(10): 2589-2596.

References

1. Zana, R. Surfactant solutions, newmethods of investigation. Trans. Tang, S. T.; Cheng, S. J. Beijing: PetroleumIndustry Press, 1992: 221-270 [Zana, R. 表面活性剂溶液研究新方法. 唐善驮,程绍进, 译.北京: 石油工业出版社, 1992: 221-270]
2. Zana, R. J. Colloid Interface Sci., 2002, 248: 203
3. Manabe, M. The differential conductivity technique and its application to mixed surfactant solutions for determining ionic constants//Abe, M.; Scamehorn, J. F. Mixed surfactant systems. 2nd ed. NewYork: Marcel Dekker, 2005: Chapter 3
4. Rosen, M. J.; Surfactants and interfacial phenomena. 2nd ed. New York: John Wiley&Sons Inc., 1988
5. Zana, R. Langmuir, 1996, 12: 1208
6. Zheng, Y. Y.; Zhao, J. X.; Zheng, O.; You, Y.; Qiu, Y. Acta Chimica Sinica, 2001, 59(5): 690 [郑玉婴,赵剑曦,郑欧, 游毅,邱羽. 化学学报, 2001, 59(5): 690]
7. Bai, G.;Wang, J.;Wang, Y.; Yan, H. J. Phys. Chem. B, 2002, 106: 6614
8. Wang, X.; Wang, J.; Wang, Y.; Ye, J.; Yan, H.; Thomas, R. K. J. Phys. Chem. B, 2003, 107: 11428
9. Rubingh, D. N. Mixed micelle solutions//Mittal, K. L. Solution chemistry of surfactants. Vol.1. NewYork: Plenum, 1979: 337-354
10. Rosen, M. J.; Hua, X. Y. J. Colloid Interface Sci., 1982, 86: 164
11. Hua, X. Y.; Rosen, M. J. J. Colloid Interface Sci., 1982, 90: 212
12. Manabe, M.; Kawamura, H.; Yamashita, A.; Tokunaga, S. J. Colloid Interface Sci., 1987, 115: 147
13. Sugihara, G.; Era, Y.; Funatsu, M.; Kunitake, T.; Lee, S.; Sasaki, Y. J. Colloid Interface Sci., 1997, 187: 435
14. Fujiwara, M.; Okano, T.; Nakashima, T. H.; Nakamura, A. A.; Sugihara, G. Colloid Polym. Sci., 1997, 275: 474
15. Sugihara, G.; Nakamura, A. A.; Nakashima, T. H.; Araki, Y. I.; Okano, T.; Fujiwara, M. Colloid Polym. Sci., 1997, 275: 790
16. Ruiz, C. C. Colloid Polym. Sci., 1999, 277: 701
17. Carcía-Mateos, I.; Velázquez, M. M.; Rodríguez, L. J. Langmuir, 1990, 6: 1078
18. Zhao, J.; Christian, S. D.; Fung, B. M. J. Phys. Chem. B, 1998, 102: 7613
19. Pérez-Rodríguez, M.; Prieto, G.; Rega, C.; Varela, L. M.; Sarmiento, F.; Mosquera, V. Langmuir, 1998, 14: 4422
20. Phillips, J. N. Trans. Faraday Soc., 1955, 51: 561
21. Williams, R. J.; Phillips, J. N.; Mysels, K. J. Trans. Faraday Soc., 1955, 51: 728
22. Carpena, P.; Aguiar, J.; Bernaola-Galván, P.; Ruiz, C. C. Langmuir, 2002, 18: 6054
23. Hirata, H.; Hattori, N.; Ishida, M.; Okabayashi, H.; Frusaka, M.; Zana, R. J. Phys. Chem., 1995, 99: 17778
24. Quagliotto, P.; Viscardi, G.; Barolo, C.; D'Angelo, D.; Barni, E.; Compari, C.; Duce, E.; Fisicaro, E. J. Org. Chem., 2005, 70: 9857
25. Pei, X. M.; Zhao, J. X.; Jiang, R. Colloid Polym. Sci., 2010, 288: 711
26. Quagliotto, P.; Barbero, N.; Barolo, C.; Costabello, K.; Marchese, L.; Coluccia, S.; Kalyanasundaram, K.; Viscardi, G. Dyes Pigments, 2009, 82: 124
27. Treiner, C.; Makayssi, A. Langmuir, 1992, 8: 794
28. Graciani, M. D.; Rodríguez, A.; Moyá, M. L. J. Colloid Interface Sci., 2008, 328: 324
29. Evans, H. C. J. Chem. Soc., 1956, 117: 579
30. Zhao, J. X.; Zheng, O. Chemistry, 2002, 65: w04 [赵剑曦, 郑欧.化学通报, 2002, 65: w046]
31. Ge, X. Y.; Guo, R.; Yan, P. Q. J. Normal Univ. Yangzhou, 1991, 11(4): 34 [葛秀英,郭荣, 严鹏权, 扬州师院学报, 1991, 11 (4): 34]
32. Yan, P. Q.; Guo, R.; Shen, M.; Li,W.; Chen, H. Y. Acta Phys.- Chim. Sin., 1994, 10: 175 [严鹏权,郭荣,沈明, 李伟,陈海燕.物理化学学报, 1994, 10: 175]
33. Corrin, M. L.; Harkins, W. D. J. Am. Chem. Soc., 1947, 69: 683
34. Zhao, G. X.; Zhu, B. Y. Principles of surfactant action. Beijing: China Light Industry Press, 2003: 264 [赵国玺,朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社, 2003: 264]
35. Zana, R. J. Colloid Interface Sci., 2002, 246: 182
36. Tsubone, K.; Arakawa, Y.; Rosen, M. J. J. Colloid Interface Sci., 2003, 262: 516
37. Jiang, Y. C.; Wu, S. K. Acta Chim. Sin., 1990, 48: 447 [姜永才, 吴世康.化学学报, 1990, 48: 447]
38. Jiang, Y. C.; Shen, S. L.; Wu, S. K. Acta Chim. Sin., 1991, 49: 32 [姜永才,沈世龙, 吴世康. 化学学报, 1991, 49: 32]
39. Jiang, Y. C.; Ye, J. P.; Wu, S. K. Acta Chim. Sin., 1992, 50: 1080 [姜永才,叶建平, 吴世康. 化学学报, 1992, 50: 1080]
40. Jiang, Y. C.; Wu, S. K. Acta Phys.-Chim. Sin., 1994, 10: 381 [姜永才,吴世康. 物理化学学报, 1994, 10: 381]
41. Hadgiivanova, R.; Diamant, H. J. Phys. Chem. B, 2007, 111: 8854
42. Menger, F. M.; Littau, C. A. J. Am. Chem. Soc., 1991, 113: 1451
43. Menger, F. M.; Littau, C. A. J. Am. Chem. Soc., 1993, 115: 10083
44. Song, L.; Rosen, M. J. Langmuir, 1996, 12: 1149
45. Rosen, M. J.; Mathias, J. H.; Davenport, L. Langmuir, 1999, 15: 7340
46. Mathias, J. H.; Rosen, M. J.; Davenport, L. Langmuir, 2001, 17: 6148
47. Pinazo, A.; Wen, X.; Perez, L.; Infante, M. R.; Franses, E. I. Langmuir, 1999, 15: 3134
48. Yoshimura, T.; Nyuta, K.; Esumi, K. Langmuir, 2005, 21: 2682
49. Laschewsky, A.; Wattebled, L.; Arotcaréna, M.; Habib-Jiwan, J. L.; Rakotoaly, R. H. Langmuir, 2005, 21: 7170
50. Jiang, Y.; Chen, H.; Cui, X. H.; Mao, S. Z.; Liu, M. L.; Luo, P. Y.; Du, Y. R. Langmuir, 2008, 24: 3118
51. Barbero, N.; Quagliotto, P.; Barolo, C.; Artuso, E.; Buscaino, R.; Viscardi, G. Dyes Pigments, 2009, 83: 396
52. Sakai, T.; Kaneko, Y.; Tsujii, K. Langmuir, 2006, 22: 2039
53. Mukerjee, P.; Yang, A. Y. S. J. Phys. Chem., 1976, 80: 1388
54. Manabe, M.; Tokunaga, A.; Kawamura, H.; Katsuura, H.; Shiomi, M.; Hiramatsu, K. Colloid Polym. Sci., 2002, 280: 929
55. Manabe, M.; Funamoto, M.; Kohgami, F.; Kawamura, H.; Katsuura, H. Colloid Polym. Sci., 2003, 281: 239
56. Manabe, M.; Kaneko, M.; Miura, T.; Akiyama, C.; Kawamura, H.; Katsuura, H.; Shiomi, M. Bull. Chem. Soc. Jpn., 2002, 75: 1967
57. Zana, R. Langmuir, 2002, 18: 7759
58. Mathias, J. H.; Rosen, M. J.; Davenport, L. Langmuir, 2002, 18: 7761

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Conductivity for the Investigation of Ionic Surfactants in an AqueousSolution and Some Characteristic Parameters

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