Please wait a minute...
Acta Physico-Chimica Sinica  2010, Vol. 26 Issue (11): 3023-3029    DOI: 10.3866/PKU.WHXB20101109
CATALYSIS AND SURFACE STRUCTURE     
Dynamic Performance of CO2 Adsorption with Amine-Modified SBA-16
SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao
Institute of Industrial Ecology and Environment, Zhejiang University, Hangzhou 310028, P. R. China
Download:   PDF(1349KB) Export: BibTeX | EndNote (RIS)      

Abstract  
Novel CO2 adsorbents for CO2 removal were prepared by introducing tetraethylenepentamine (TEPA) into SBA-16 type mesoporous silica using a post-synthetic impregnation method. The properties of the mesoporous materials before and after surface modification were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), and N2 adsorption-desorption. We confirmed that TEPA was loaded onto the surface of the channels in the mesoporous materials. The surface area, pore size, and pore volume of TEPA-loaded SBA-16 decreased with an increase in TEPA loading while its fundamental pore structure was unchanged. The dynamic adsorption of CO2 onto TEPA-loaded SBA-16 as well as its regeneration property was studied in a packed column. The total adsorption capacity and breakthrough capacity increased when the amount of loaded TEPA increased from 10% to 30% (w). The sample impregnated with 30% TEPA showed the highest breakthrough capacity and total adsorption capacity of about 0.625 and 0.973 mmol·g-1 at 60℃, respectively. From 60℃ to 80℃, the CO2 dynamic adsorption behavior of TEPA-loaded SBA-16 was stable. The total adsorption capacity of CO2 on TEPA-loaded SBA-16 dropped slightly (6.45%) after 20 adsorption-desorption regeneration cycles. Their CO2 adsorption behavior was also investigated using the deactivation model, which showed an excellent predictive capability for the breakthrough curves.

 



Key wordsSBA-16      Dynamic      Breakthrough curve      Deactivation model      CO2 adsorption     
Received: 27 June 2010      Published: 15 September 2010
MSC2000:  O647  
Fund:  

The project was supported by the National Natural Science Foundation of China (20976159).

Corresponding Authors: SHI Yao     E-mail: shiyao@zju.edu.cn
Cite this article:

SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao. Dynamic Performance of CO2 Adsorption with Amine-Modified SBA-16. Acta Physico-Chimica Sinica, 2010, 26(11): 3023-3029.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20101109     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2010/V26/I11/3023

1. Idem, R.; Tontiwachwuthikul, P. Ind. Eng. Chem. Res., 2006, 45: 2413
2. Yang, H. Q.; Xu, Z. H.; Fan, M. H.; Fan, M. H.; Gupta, R.; Slimane, R. B.; Bland, A. E.; Wright, I. J. Environ. Sci., 2008, 20: 14
3. Aaron, D.; Tsouris, C. Separ. Sci. Technol., 2005, 40: 321
4. Oyenekan, B. A.; Rochelle, G. T. AICHE J., 2007, 53: 3144
5. Veawab, A.; Tontiwachwuthikul, P.; Chakma, A. Ind. Eng. Chem. Res., 1999, 38: 3917
6. Katoh, M.; Yoshikawa, T.; Tomonari, T.; Katayama, K.; Tomida, T. J. Colloid Interface Sci., 2000, 226: 145
7. Li, P. Y.; Zhang, S. J.; Chen, S. X.; Zhang, Q. K.; Pan, J. J.; Ge, B. Q. J. Appl. Polym. Sci., 2008, 108: 3851
8. Lee, J. S.; Kim, J. H.; Kim, J. T.; Suh, J. W.; Lee, J. M.; Lee, C. H. J. Chem. Eng. Data, 2002, 47: 1237
9. Siriwardane, R. V.; Shen, M. S.; Fisher, E. P.; Poston, J. A. Energy Fuels, 2001, 15: 279
10. Son, W. J.; Choi, J. S.; Ahn, W. S. Microporous Mesoporous Mat., 2008, 113: 31
11. Wei, J.W.; Shi, J. J.; Pan, H.; Zhao,W.; Ye, Q.; Shi, Y.Microporous Mesoporous Mat., 2008, 116: 394
12. Choi, S.; Drese, J. H.; Jones, C. W. ChemSusChem, 2009, 2: 796
13. Li, L.; Yuan,W. H.; Wei, C. H. Chem. Ind. Eng. Prog., 2006, 25: 918 [李莉, 袁文辉,韦朝海.化工进展, 2006, 25: 918]
14. Xu, X. C.; Song, C. S.; Andresen, J. M.; Andresen, J. M.; Miller, B. G.; Scaroni, A. W. Microporous Mesoporous Mat., 2003, 62: 29
15. Wang, L. F.; Ma, L.; Wang, A. Q.; Liu, Q.; Zhang, T. Chin. J. Catal., 2007, 28: 805 [王林芳,马磊,王爱琴,刘茜,张涛. 催化学报, 2007, 28: 805]
16. Zhao, H. L.; Hu, J.; Wang, J. J.; Zhou, L. H.; Liu, H. L. Acta Phys. - Chim. Sin., 2007, 23: 801 [赵会玲,胡军, 汪建军,周丽绘,刘洪来.物理化学学报, 2007, 23: 801]
17. Kim, S. N.; Son, W. J.; Choi, J. S.; Ahn, W. S. Microporous Mesoporous Mat., 2008, 115: 497
18. Knofel, C.; Descarpentries, J.; Benzaouia, A.; Zelenak, V.; Mornet, S.; Llewellyn, P. L.; Hornebecq, V. Microporous Mesoporous Mat., 2007, 99: 79
19. Yue, M. B.; Sun, L. B.; Cao, Y.; Wang, Y.; Wang, Z. J.; Zhu, J. H. Chem. Eur. J., 2008, 14: 3442
20. Kim, T. W.; Ryoo, R.; Kruk, M.; Gierszal, K. P.; Jaroniec, M.; Kamiya, S.; Terasak, O. J. Phys. Chem. B, 2004, 108: 11480
21. Zhao, D. Y.; Huo, Q. S.; Feng, J. L.; Chmelka, B. F.; Stucky, G. D. J. Am. Chem. Soc., 1998, 120: 6024
22. Kleitz, F.; Czuryszkiewicz, T.; Solovyov, L. A.; Lindn, M. Chem. Mater., 2006, 18: 5070
23. Satyapal, S.; Filburn, T.; Trela, J.; Strange, J. Energy Fuels, 2001, 15: 250
24. Kim, T. W.; Ryoo, R.; Kruk, M.; Gierszal, K. P.; Jaroniec, M.; Kamiya, S.; Terasaki, O. J. Phys. Chem. B, 2004, 108: 11480
25. Yasyerli, S.; Dogu, G.; Ar, I.; Dogu, T. Ind. Eng. Chem. Res., 2001, 40: 5206
26. Kopac, T.; Kocabas, S. Chem. Eng. Commun., 2003, 190: 1041

[1] LIU Changjiang, MA Hongwen, ZHANG Pan. Thermodynamics of the Hydrothermal Decomposition Reaction of Potassic Syenite with Zeolite Formation[J]. Acta Physico-Chimica Sinica, 2018, 34(2): 168-176.
[2] LIU Fu-Feng, FAN Yu-Bo, LIU Zhen, BAI Shu. Molecular Mechanism Underlying Affinity Interactions between ZAβ3 and the Aβ16-40 Monomer[J]. Acta Physico-Chimica Sinica, 2017, 33(9): 1905-1914.
[3] WANG Xiu-Xiu, ZHAO Jian-Wei, YU Gang. Combined Effects of the Hole and Twin Boundary on the Deformation of Ag Nanowires: a Molecular Dynamics Simulation Study[J]. Acta Physico-Chimica Sinica, 2017, 33(9): 1773-1780.
[4] CAO Liao-Ran, ZHANG Chun-Yu, ZHANG Ding-Lin, CHU Hui-Ying, ZHANG Yue-Bin, LI Guo-Hui. Recent Developments in Using Molecular Dynamics Simulation Techniques to Study Biomolecules[J]. Acta Physico-Chimica Sinica, 2017, 33(7): 1354-1365.
[5] WU Guang-Xin, PENG Wang-Jun, ZHANG Jie-Yu. Statistic Thermodynamic Model of Hydrogen Absorption on Metal Powders[J]. Acta Physico-Chimica Sinica, 2017, 33(6): 1108-1113.
[6] CHEN Yi-Jian, ZHOU Hong-Tao, GE Ji-Jiang, XU Gui-Ying. Aggregation Behavior of Double-Chained Anionic Surfactant 1-Cm-C9-SO3Na at Air/Liquid Interface: Molecular Dynamics Simulation[J]. Acta Physico-Chimica Sinica, 2017, 33(6): 1214-1222.
[7] CHEN Fang, LIU Yuan-Yuan, WANG Jian-Long, Su Ning-Ning, LI Li-Jie, CHEN Hong-Chun. nvestigation of the Co-Solvent Effect on the Crystal Morphology of β-HMX using Molecular Dynamics Simulations[J]. Acta Physico-Chimica Sinica, 2017, 33(6): 1140-1148.
[8] ZHOU Ting-Ting, SONG Hua-Jie, HUANG Feng-Lei. The Slip and Anisotropy of TATB Crystal under Shock Loading via Molecular Dynamics Simulation[J]. Acta Physico-Chimica Sinica, 2017, 33(5): 949-959.
[9] PENG Li-Juan, YAO Qian, WANG Jing-Bo, LI Ze-Rong, ZHU Quan, LI Xiang-Yuan. Pyrolysis of RDX and Its Derivatives via Reactive Molecular Dynamics Simulations[J]. Acta Physico-Chimica Sinica, 2017, 33(4): 745-754.
[10] ZHAO Yuan, CAO Ze-Xing. Global Simulations of Enzymatic Catalysis[J]. Acta Physico-Chimica Sinica, 2017, 33(4): 691-708.
[11] ZHANG Ting, SHEN Jie. Aggregation Properties and Thermodynamics of Micellization of Gemini Surfactants with Diester and Rigid Spacers in Organic Alcohol-Water Mixed Media[J]. Acta Physico-Chimica Sinica, 2017, 33(4): 795-802.
[12] ZHENG Qi-Ge, LIU Hui, XIA Quan, LIU Qing-Shan, MOU Lin. Density, Dynamic Viscosity and Electrical Conductivity of Two Hydrophobic Phosphonium Ionic Liquids[J]. Acta Physico-Chimica Sinica, 2017, 33(4): 736-744.
[13] LONG Jin-You, LIU Zhi-Ming, QIU Xue-Jun, ZHANG Bing. Ultrafast Nonadiabatic Dynamics of Electronically Excited 2-Methyl Furan[J]. Acta Physico-Chimica Sinica, 2017, 33(3): 506-512.
[14] YU Hai-Yang, WANG Fang, LIU Qi-Chun, MA Qing-Yu, GU Zheng-Gui. Structure and Kinetics of Thermal Decomposition Mechanism of Novel Silk Fibroin Films[J]. Acta Physico-Chimica Sinica, 2017, 33(2): 344-355.
[15] XIAO Ming, HUANG Zai-Yin, TANG Huan-Feng, LU Sang-Ting, LIU Chao. Facet Effect on Surface Thermodynamic Properties and In-situ Photocatalytic Thermokinetics of Ag3PO4[J]. Acta Physico-Chimica Sinica, 2017, 33(2): 399-406.