ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2010,Vol.26>> Issue(12)>> 3249-3256     doi: 10.3866/PKU.WHXB20101134         中文摘要
Selective Adsorption Behavior of Cu(II) and Cr(VI) Heavy Metal Ions by Functionalized Ordered Mesoporous Carbon
CHEN Tian, WANG Tao, WANG Dao-Jun, ZHAO Jian-Qing, DING Xiao-Chun, WU Shi-Chao, XUE Hai-Rong, HE Jian-Ping
College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China
Full text: PDF (1255KB) HTML Export: BibTeX | EndNote (RIS)

An ordered mesoporous carbon -silica nanocomposite was synthesized by the evaporation - induced triconstituent co ?assembly method, wherein a soluble resol polymer was used as an organic precursor, tetraethoxysilane was used as an inorganic precursor, and the triblock copolymer F127 was used as the template. After the removal of silica with HF, ordered mesoporous pure carbon (OMC) was obtained. X-ray diffraction (XRD), N2 adsorption -desorption isotherms (BET), and transmission electron microscopy (TEM) showed that the OMC product had a highly ordered structure with a large pore size of 6.4 nm, a pore volume of 2.13 cm3·g-1, and a high surface area of 1330 m2·g-1. The OMC was subsequently functionalized with ethylenediamine by treatment with nitric acid and thionyl chloride to obtain a functionalized ordered mesoporous carbon (C-NH2(m)), m is the mass (g) of the added ethylenediamine. Fourier transform infrared (FTIR) spectroscopy showed that the amino group was successfully grafted onto the surface of the OMC. TEM images showed that C-NH2(m) had a highly ordered mesoporous structure. OMC and C?NH2(m) were used as adsorbents for the selective adsorption of Cu(II) and Cr(VI) ions from the aqueous solution. C?NH2(9.0) had a higher adsorption capacity for Cu(II) of 495.05 mg·g-1 versus 213.33 mg·g-1 for the OMC and a lower adsorption capacity for Cr(VI) of 68.21 mg·g-1 versus 241.55 mg·g-1 for the OMC, indicating its significantly favorable potential for the selective adsorption of Cu(II).

Keywords: Ordered mesoporous carbon   Amino ? functionalized grafting   Selective adsorption   Cu(II)   Cr(VI)  
Received: 2010-07-12 Accepted: 2010-08-26 Publication Date (Web): 2010-10-14
Corresponding Authors: HE Jian-Ping Email:

Fund: The project was supported by the National Natural Science Foundation of China (50871053).

Cite this article: CHEN Tian, WANG Tao, WANG Dao-Jun, ZHAO Jian-Qing, DING Xiao-Chun, WU Shi-Chao, XUE Hai-Rong, HE Jian-Ping. Selective Adsorption Behavior of Cu(II) and Cr(VI) Heavy Metal Ions by Functionalized Ordered Mesoporous Carbon[J]. Acta Phys. -Chim. Sin., 2010,26 (12): 3249-3256.    doi: 10.3866/PKU.WHXB20101134

1. Feng, X.; Fryxell, G. E.;Wang, L. Q.; Kim, A. Y.; Liu, J.; Kemner, K. M. Science, 1997, 276: 923
2. Mercier, L.; Pinnavaia, T. J. Environ. Sci. Technol., 1998, 32: 2749
3. Lee, J.; Yoon, S.; Hyeon, T.; Oh, S. M.; Kim, K. B. Chem. Commun., 1999: 2177
4. Hartmann, M.; Vinu, A.; Chandrasekar, G. Chem. Mater., 2005, 17: 829
5. Darmstadt, H.; Roy, C.; Kaliaguine, S.; Choi, S. J.; Ryoo, R. Carbon, 2002, 40: 2673
6. Lu, A. H.; Li,W. C.; Schmidt,W.; Schüth, F. Microporous Mesoporous Mat., 2005, 80: 117
7. Han, S.; Kim, M.; Hyeon, T. Carbon, 2003, 41: 1525
8. Lee, J.; Han, S.; Hyeon, T. J. Mater. Chem., 2004, 14: 478
9. Vinu, A.; Hossain, K. Z.; Kumar, G. S. Carbon, 2006, 44: 530
10. Wan, Y.; Yang, H. F.; Zhao, D. Y. Acc. Chem. Res., 2006, 39: 423
11. Tanaka, S.; Nishiyama, N.; Egashira, Y.; Ueyama, K. Chem. Commun., 2005: 2125
12. Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Yang, H. F.; Li, Z.; Yu, C. Z.; Tu, B.; Zhao, D. Y. Angew. Chem. Int. Edit., 2005, 44: 7053
13. Liang, C. D.; Dai, S. J. Am. Chem. Soc., 2006, 128: 5316
14. Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Cheng, L.; Feng, D.; Wu, Z. X.; Chen, Z. X.;Wan, Y.; Stein, A.; Zhao, D. Y. Chem. Mater., 2006, 18: 4447
15. Liu, R. L.; Shi, Y. F.;Wan, Y.; Meng, Y.; Zhang, F. Q.; Gu, D.; Chen, Z. X.; Tu, B.; Zhao, D. Y. J. Am. Chem. Soc., 2006, 128: 11652
16. Wan, Y.; Shi, Y. F.; Zhao, D. Y. Chem. Commun., 2007: 897
17. Wan, Y.; Shi, Y. F.; Zhao, D. Y. Chem. Mater., 2008, 20: 932
18. Wan, Y.; Qian, X.; Jia, N. Q.;Wang, Z. Y.; Li, H. X.; Zhao, D. Y. Chem. Mater., 2007, 20: 1012
19. Zhou, J. H.; He, J. P.;Wang, T.; Sun, D.; Zhao, G.W.; Chen, X.; Wang, D. J.; Di, Z. Y. J. Mater. Chem., 2008, 18: 5776
20. Wang, T.; He, J. P.; Zhang, C. X.; Zhou, J. H.; Guo, Y. X.; Chen, X.; Di, Z. Y.; Sun, D.;Wang, D. J. Acta Phys. Chim. Sin., 2008, 24: 2314. [王涛, 何建平, 张传香, 周建华, 郭云霞, 陈秀, 狄志勇, 孙盾, 王道军. 物理化学学报, 2008, 24: 2314]
21. Wang, T.; Zhou, J. H.;Wang, D. J.; Sun, D.; Di, Z. Y.; He, J. P. Acta Phys. Chim. Sin., 2009, 25: 2155. [王涛, 周建华, 王道军, 孙盾, 狄志勇, 何建平. 物理化学学报, 2009, 25: 2155]
22. Sun, D.; He, J. P.; Zhou, J. H.;Wang, T.; Di, Z. Y.;Wang, D. J.; Ding, X. C. Acta Phys. Chim. Sin., 2010, 26: 385. [孙盾, 何建平, 周建华, 王涛, 狄志勇, 王道军, 丁晓春. 物理化学学报, 2010, 26: 385]
23. Yang, J. P.; Zhai, Y. P.; Deng, Y. H.; Gu, D.; Li, Q.;Wu, Q. L.; Huang, Y.; Tu, B.; Zhao, D. Y. J. Colloid Interface Sci., 2010, 342: 579
24. Wu, Z. X.;Webley, P. A.; Zhao, D. Y. Langmuir, 2010, 26: 10277
25. Zhu, J. Z.; Yang, J.; Deng, B. L. New Carbon Materials, 2008, 23: 622. [祝建中, 杨嘉, Deng Baolin. 新型炭材料, 2008, 23: 622]
26. Peng, H. Q.; Alemany, L. B.; Margrave, J. L.; Khabashesku, V. N. J. Am. Chem. Soc., 2003, 125: 15174
27. Knocke,W. R.; Hemphill, L. H. Water Research, 1981, 15: 275

1. WU Hong-Bin, ZHANG Ying, YUAN Cong-Li, WEI Xiao-Pei, YIN Jin-Ling, WANG Gui-Ling, CAO Dian-Xue, ZHANG Yi-Ming, YANG Bao-Feng, SHE Pei-liang.Synthesis and Electrochemical Performance of Li4Ti5O12/CMK-3 Nanocomposite Negative Electrode Materials for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1247-1252
2. ZHAO Ling-Xi, SONG Shu-E, DU Na, HOU Wan-Guo.A Sorbent Concentration-Dependent Langmuir Isotherm[J]. Acta Phys. -Chim. Sin., 2012,28(12): 2905-2910
3. CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia.Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2012,28(04): 837-842
4. LI Yong-Chao, LI Tie-Long, WANG Xue, JIN Zhao-Hui.One-Step Synthesis of Fe@SiO2 and Its Application in Cr(VI) Removal[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2711-2718
5. LI Jian-Sheng, GU Juan, LING Xiao-Feng, SUN Xiu-Yun, SHEN Jin-You, HAN Wei-Qing, WANG Lian-Jun.Synthesis of Ordered Mesoporous Carbon Loaded Fe, Co, Ni Nanocrystals by the Soft Templating Route and Their Characterization[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1772-1776
6. SUN Dun, HE Jian-Ping, ZHOU Jian-Hua, WANG Tao, DI Zhi-Yong, WANG Dao-Jun, DING Xiao-Chun.MClx(M=Pd, Fe, Cr) Assisted Synthesis of Ordered Mesoporous Carbon and Their Electrocatalytic Performance after Loading with Pt Nanoparticles[J]. Acta Phys. -Chim. Sin., 2010,26(02): 385-391
7. SUN Xiao-Li, ZENG Qing-Xuan, FENG Chang-Gen.Adsorption Kinetics of Chromium (VI) onto an Anion Exchange Fiber Containing Polyamine[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1951-1957
8. WANG Li-Juan, LIU Gou-Sheng, SONG Xing-Fu, YU Jian-Guo.Molecular Modeling for Selective Adsorption of Halite with Dodecylmorpholine[J]. Acta Phys. -Chim. Sin., 2009,25(05): 963-969
9. WANG Hong-Guo; JIANG Heng; XU Jing; SUN Zhao-Lin; ZHANG Xiao-Tong; ZHU He-Li; SONG Li-Juan.Effects of Benzene and 1-Octene on Desulfurization by Selective Adsorption with Ce(IV)Y[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1714-1718
10. MALIK Maqsood Ahmad; KHAN Zaheer.Effect ofMn(II) and Ce(IV) Ions on the Oxidation of Lactic Acid by Chromic Acid[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1013-1017
11. HU Bing-wen; ZHAO Xue-zhou; ZONG Xiao-hong; ZHOU Ping.EPR Spectral Simulation for Silk Fibroin-Cu(II) Complexes with Multiple Components[J]. Acta Phys. -Chim. Sin., 2006,22(02): 167-171
12. Zhu Jian-Hua;Xu Yang;Wang Ying;Zhou Shi-Lu;Zhou Chun-Fang.Adsorption and Catalytic Degradation of Nitrosamines by Zeolites and Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 946-952
13. Song Ji-Guo;Song Hua-Can;Yang Qi-Qin;Xu Zun-Le.Electoreduction of Cu(II) in Cu (p-CH3C6H4SO3)2+DMSO[J]. Acta Phys. -Chim. Sin., 2003,19(03): 283-285
14. Zhu Jian-Hua;Xu Yang;Zhou Chun-Fang;Zhou Shi-Lu;Ma Li-Li.Investigation on the Insertion-adsorption of N-nitrosamines on the Zeolite with Small Pore[J]. Acta Phys. -Chim. Sin., 2003,19(03): 221-225
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top