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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2010,Vol.26>> Issue(12)>> 3278-3284     doi: 10.3866/PKU.WHXB20101210         中文摘要
CATALYSIS AND SURFACE STRUCTURE
Effect of Preparation Method on the Activity of CuO/CeO2-ZrO2 Catalysts for Low Temperature CO Oxidation
YANG Zhi-Qiang, MAO Dong-Sen, GUO Qiang-Sheng, GU Lei
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, P. R. China
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CuO/CeO2-ZrO2 catalysts were prepared by microwave heating decomposition (one-step approach) and by microwave heating treatment of co-precipitation followed by impregnation (two-step approach). The catalysts were characterized by X-ray diffraction (XRD), low temperature N2 adsorption/ desorption, and H2-temperature-programmed reduction (H2-TPR). The catalytic activities of the catalysts for low temperature CO oxidation were investigated using a microreactor-gas chromatograph. The results showed that the one-step approach was more beneficial to CuO dispersion on the catalyst surface because of a strong interaction between CuO and CeO2-ZrO2 and to the improved reducibility of CuO, which resulted in higher catalytic activity. We conclude that finely dispersed and small CuO particles strongly interact with CeO2-ZrO2 are responsible for the high catalytic activity toward CO oxidation and that large CuO particles that do not interact with CeO2-ZrO2 inhibit the catalytic activity.



Keywords: Catalytic activity   CuO/CeO2-ZrO2   CO oxidation   Microwave heating  
Received: 2010-08-01 Accepted: 2010-10-08 Publication Date (Web): 2010-10-29
Corresponding Authors: MAO Dong-Sen Email: dsmao@sit.edu.cn, dsmao1106@yahoo.com.cn

Fund: The project was supported by the Leading Academic Discipline Project of Shanghai Education Committee, China (J51503) and Research Foundation of Shanghai Institute of Technology, China (KJ2008-01).

Cite this article: YANG Zhi-Qiang, MAO Dong-Sen, GUO Qiang-Sheng, GU Lei. Effect of Preparation Method on the Activity of CuO/CeO2-ZrO2 Catalysts for Low Temperature CO Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26 (12): 3278-3284.    doi: 10.3866/PKU.WHXB20101210

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