ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2010,Vol.26>> Issue(12)>> 3278-3284     doi: 10.3866/PKU.WHXB20101210         中文摘要
Effect of Preparation Method on the Activity of CuO/CeO2-ZrO2 Catalysts for Low Temperature CO Oxidation
YANG Zhi-Qiang, MAO Dong-Sen, GUO Qiang-Sheng, GU Lei
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, P. R. China
Full text: PDF (2450KB) HTML Export: BibTeX | EndNote (RIS)

CuO/CeO2-ZrO2 catalysts were prepared by microwave heating decomposition (one-step approach) and by microwave heating treatment of co-precipitation followed by impregnation (two-step approach). The catalysts were characterized by X-ray diffraction (XRD), low temperature N2 adsorption/ desorption, and H2-temperature-programmed reduction (H2-TPR). The catalytic activities of the catalysts for low temperature CO oxidation were investigated using a microreactor-gas chromatograph. The results showed that the one-step approach was more beneficial to CuO dispersion on the catalyst surface because of a strong interaction between CuO and CeO2-ZrO2 and to the improved reducibility of CuO, which resulted in higher catalytic activity. We conclude that finely dispersed and small CuO particles strongly interact with CeO2-ZrO2 are responsible for the high catalytic activity toward CO oxidation and that large CuO particles that do not interact with CeO2-ZrO2 inhibit the catalytic activity.

Keywords: Catalytic activity   CuO/CeO2-ZrO2   CO oxidation   Microwave heating  
Received: 2010-08-01 Accepted: 2010-10-08 Publication Date (Web): 2010-10-29
Corresponding Authors: MAO Dong-Sen Email:,

Fund: The project was supported by the Leading Academic Discipline Project of Shanghai Education Committee, China (J51503) and Research Foundation of Shanghai Institute of Technology, China (KJ2008-01).

Cite this article: YANG Zhi-Qiang, MAO Dong-Sen, GUO Qiang-Sheng, GU Lei. Effect of Preparation Method on the Activity of CuO/CeO2-ZrO2 Catalysts for Low Temperature CO Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26 (12): 3278-3284.    doi: 10.3866/PKU.WHXB20101210

1. Liu, Y.; Meng, M.; Yao, J. S.; Zha, Y. Q. Acta Phys. -Chim. Sin., 2007, 23: 641
[刘咏, 孟明, 姚金松, 査宇清. 物理化学学 报, 2007, 23: 641]
2. Yu, J.;Wu, G. S.; Mao, D. S.; Lu, G. Z. Acta Phys. -Chim. Sin., 2008, 24: 1751
[俞俊, 吴贵升, 毛东森, 卢冠忠. 物理化学学 报, 2008, 24: 1751]
3. Zheng, X. C.;Wang, X. Y.; Yu, L. H.;Wang, S. R.;Wu, S. H. Prog. Chem., 2006, 18: 159
[郑修成, 王向宇, 于丽华, 王淑荣, 吴世华. 化学进展, 2006, 18: 159]
4. Liang, F. X.; Zhu, H. Q.; Qin, Z. F.;Wang, G. F.;Wang, J. G. Prog. Chem., 2008, 20: 1453
[梁飞雪, 朱华青, 秦张峰, 王国 富, 王建国. 化学进展, 2008, 20: 1453]
5. Wang, S. P.; Zheng, X. C.;Wang, X. Y.;Wang, S. R.; Zhang, S. M.; Yu, L. H.; Huang,W. P.;Wu, S. H. Catal. Lett., 2005, 105: 163
6. Wang, S. P.;Wang, X. Y.; Huang, J.; Zhang, S. M.;Wang, S. R.; Wu, S. H. Catal. Commun., 2007, 8: 231
7. Wang, S. P.; Zhang, T. Y.; Su, Y.;Wang, S. R.; Zhang, S. M.; Zhu, B. L.;Wu, S. H. Catal. Lett., 2008, 121: 70
8. Jiang, X. Y.; Zhou, R. X.; Chen, Y.; Lou, L. P.; Zheng, X. M. J. Zhejiang Univ.: Science Edition, 2001, 28: 653
[蒋晓原, 周仁 贤, 陈煜, 楼莉萍, 郑小明. 浙江大学学报: 理学版, 2001, 28: 653]
9. Wang, S. P.;Wang, X. Y.; Zheng, X. C.;Wang, S. R.; Zhang, S. M.; Huang,W. P.;Wu, S. H. React. Kinet. Catal. Lett., 2006, 89: 37
10. Luo, M. F.; Zheng, X. M. Acta Chem. Scand., 1998, 52: 1183
11. Yang, Z. Q.; Mao, D. S.; Zhu, H. L.; Lu, G. Z. Chin. J. Catal., 2009, 30: 997
[杨志强, 毛东森, 朱慧琳, 卢冠忠. 催化学报
, 2009, 30: 997]
12. Martinez-Arias, A.; Fernandez-Garcia, M.; Galvez, O.; Coronado, J. M.; Anderson, J. A.; Conesa, J. C.; Soria, J.; Munuera, G. J. Catal., 2000, 195: 207
13. Chen, H. L.; Zhu, H. Y.;Wu, Y.; Gao, F.; Dong, L.; Zhu, J. J. J. Mol. Catal. A, 2006, 255: 254
14. Zhu, J.; Zhang, L. L.; Deng, Y.; Liu, B.; Dong, L. H.; Gao, F.; Sun, K. Q.; Dong, L.; Chen, Y. Appl. Catal. B, 2010, 96: 449
15. Hong, Q. H.; Song, Y. P.; Jia, A. P.; Pu, Z. Y.; Luo, M. F. J. Mol. Catal. (China), 2008, 22: 429
[洪庆红, 宋宇鹏, 贾爱平, 普志 英, 罗孟飞. 分子催化, 2008, 22: 429]
16. Wang, E. G.; Chen, S. Y. J. Chin. Rare Earth Soc., 2001, 19: 17
[王恩过, 陈诵英. 中国稀土学报, 2001, 19: 17]
17. Wang, E. G.; Chen, S. Y. J. Rare Earths, 2002, 20: 533
18. Wang, J. P.;Wang, E. G.; Chen, S. Y. Coal Conv., 2000, 23: 88
[王建平, 王恩过, 陈诵英. 煤炭转化, 2000, 23: 88]
19. Cao, J. L.;Wang, Y.; Zhang, T. Y.;Wu, S. H.; Yuan, Z. Y. Appl. Catal. B, 2008, 78: 120
20. Yang, Z. Q.; Mao, D. S.; Zhu, H. L.; Lu, G. Z. Chin. J. Inorg. Chem., 2009, 25: 812
[杨志强, 毛东森, 朱慧琳, 卢冠忠. 无机 化学学报, 2009, 25: 812]
21. Cai, C.; Xue, P. J. Ningxia Univ.: Natural Science Edition, 2005, 26: 345
[蔡超, 薛屏. 宁夏大学学报: 自然科学版, 2005, 26: 345]
22. Wang, J. Q.; Shen, M. Q.;Wang, J.;Wang,W. L.; Jia, L.W. Acta Phys. -Chim. Sin., 2010, 26: 2249
[王建强, 沈美庆, 王军, 王务林, 贾莉伟. 物理化学学报, 2010, 26: 2249]
23. Ma, L.; Luo, M. F.; Chen, S. Y. Appl. Catal. A, 2003, 242: 151

1. GU Yong-Bing, CAI Qiu-Xia, CHEN Xian-Lang, ZHUANG Zhen-Zhan, ZHOU Hu, ZHUANG Gui-Lin, ZHONG Xing, MEI Dong-Hai, WANG Jian-Guo.Theoretical Insights into Role of Interface for CO Oxidation on Inverse Al2O3/Au(111) Catalysts[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1674-1680
2. JIA Yong-Chang, WANG Shu-Yuan, MENG Lian, LU Ji-Qing, LUO Meng-Fei.Effects of Zr Addition on CO and CH4 Catalytic Oxidation over PdO/PdO/Ce1-xPdxO2-δ Catalyst[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1801-1809
3. HUANG Wei-Xin, QIAN Kun, WU Zong-Fang, CHEN Shi-Long.Structure-Sensitivity of Au Catalysis[J]. Acta Phys. -Chim. Sin., 2016,32(1): 48-60
4. LIU Na, ZHANG Hui, XUE Nian-Hua, DING Wei-Ping.Influence of Tungsten Loadings on the 1-Butene Metathesis Reaction over W/SiO2/Al2O3 Catalysts[J]. Acta Phys. -Chim. Sin., 2015,31(5): 933-940
5. ZHANG Xiao-Qing, XU Yan YAN, YANG Chun-Hui, ZHANG Yan-Ping, YIN Yong-Xiang, SHANG Shu-Yong.In-situ Co-Precipitation of Ni-Mg-Al-LDH Catalytic Precursor on γ-Al2O3 for Dry Reforming of Methane: Synthesis and Evaluation[J]. Acta Phys. -Chim. Sin., 2015,31(5): 948-954
6. PAN Jian-Ming, YANG Wei, SUN Hai-Biao, ZHENG Xiang, LI Guo-Hua.Preparation and Electrocatalytic Activity of Tungsten Carbide-Montmorillonite Composite[J]. Acta Phys. -Chim. Sin., 2015,31(5): 998-1006
7. WANG Yu-Qiao, WANG Pan-Pan, LU Jing, BAI Yi-Chao, GU Yun-Liang, SUN Yue-Ming.Dye-Sensitized Solar Cells Based on MWCNT/TiO2 Counter Electrode and Thiolate/Disulfide Non-Iodine Redox Couple[J]. Acta Phys. -Chim. Sin., 2015,31(3): 448-456
8. YU Wei-Ling, ZUO Hui-Wen, LU Chun-Hai, LI Yi, ZHANG Yong-Fan, CHEN Wen-Kai.Nitrous Oxide Decomposition Catalyzed by Au19Pd and Au19Pt Clusters[J]. Acta Phys. -Chim. Sin., 2015,31(3): 425-434
9. QI Qi, WANG Yu-Qiao, WANG Sha-Sha, QI Hao-Nan, WEI Tao, SUN Yue-Ming.Preparation of Reduced Graphene Oxide/TiO2 Nanocomposites and Their Photocatalytic Properties[J]. Acta Phys. -Chim. Sin., 2015,31(12): 2332-2340
10. YU Chang-Lin, WEI Long-Fu, LI Jia-De, HE Hong-Bo, FANG Wen, ZHOU Wan-Qin.Preparation and Characterization of GO/Ag3PO4 Composite Photocatalyst and Its Visible Light Photocatalytic Performance[J]. Acta Phys. -Chim. Sin., 2015,31(10): 1932-1938
11. LIN Cai-Fang, CHEN Xiao-Ping, CHEN Shu, SHANGGUAN Wen-Feng.Preparation of NiS-Modified Cd1-xZnxS by a Hydrothermal Method and Its Use for the Efficient Photocatalytic H2 Evolution[J]. Acta Phys. -Chim. Sin., 2015,31(1): 153-158
12. SU Jia, LU Shan, WANG Sha-Sha, ZHANG Xue-Hua, FU Yu-Bin, HE Tao.Influence of pH Values on the Structure and Performance of a Polypyrrole Counter Electrode for Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1487-1494
13. ZHANG Jing-Bo, LI Pan, YANG Hui, ZHAO Fei-Yan, TANG Guang-Shi, SUN Li-Na, LIN Yuan.Preparation of a Highly Efficient PbS Electrode and Its Application in Quantum Dots-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1495-1500
14. ZHAO Wei-Rong, SHI Qiao-Meng, LIU Ying.Performance, Deactivation and Regeneration of SnO2/TiO2 Nanotube Composite Photocatalysts[J]. Acta Phys. -Chim. Sin., 2014,30(7): 1318-1324
15. FU Ping-Feng, ZHANG Peng-Yi.Low-Temperature Electrostatic Self-Assembly of Noble Metals on TiO2 Nanostructured Films with Enhanced Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2014,30(5): 965-972
16. CHEN Hui, CHEN Dan, XIE Wei-Miao, ZHENG Xiang, LI Guo-Hua.Preparation and Electrocatalytic Activity of Tungsten Carbide and Tungsten-Iron Carbide Composite with Core-Shell Structure[J]. Acta Phys. -Chim. Sin., 2014,30(5): 891-898
17. GUO Zhang-Long, HUANG Li-Qiong, CHU Wei, LUO Shi-Zhong.Effects of Promoter on NiMgAl Catalyst Structure and Performance for Carbon Dioxide Reforming of Methane[J]. Acta Phys. -Chim. Sin., 2014,30(4): 723-728
18. WANG Jing-Sheng, WANG En-Jun, YU Yan-Long, GUO Li-Mei, CAO Ya-An.Visible Light Photocatalytic Activity of an In-Doped TiO2 Thin Film with a Three-Dimensional Ordered Structure[J]. Acta Phys. -Chim. Sin., 2014,30(3): 513-519
19. LÜ Yong-Ge, LI Yong, TA Na, SHEN Wen-Jie.Morphology-Controlled Synthesis of Co3O4 Nanocubes and Their Catalytic Performance in CO Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30(2): 382-388
20. WANG Jia-Sheng, HAN Shu-Min, LI Yuan, SHEN Na, ZHANG Wei.Hydriding/Dehydriding Properties of an MgH2+20%(w) MgTiO3 Composite[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2323-2327
21. LIN Xue, GUO Xiao-Yu, WANG Qing-Wei, CHANG Li-Min, ZHAI Hong-Ju.Hydrothermal Synthesis and Efficient Visible Light Photocatalytic Activity of Bi2MoO6/BiVO4 Heterojunction[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2113-2120
22. LIANG Qian, ZHAO Zhen, LIU Jian, WEI Yue-Chang, JIANG Gui-Yuan, DUAN Ai-Jun.Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al):an Active Catalyst for CO Oxidation[J]. Acta Phys. -Chim. Sin., 2014,30(1): 129-134
23. SUN Jing-Fang, GE Cheng-Yan, YAO Xiao-Jiang, CAO Yuan, ZHANG Lei, TANG Chang-Jin, DONG Lin.Preparation of NiO/CeO2 Catalysts by Solid State Impregnation and Their Application in CO Oxidation[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2451-2458
24. GUO Li-Mei KUANG Yuan-Jiang YANG Xiao-Dan YU Yan-Long YAO Jiang-Hong CAO Ya-An.Investigation on Photocatalytic Reduction of CO2into CH4 Using SrB2O4/SrCO3Composite Catalyst[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1558-1565
25. YAN Wei-Ping, WANG De-Jun, CHEN Li-Ping, LU Yong-Chun, XIE Teng-Feng, LIN Yan-Hong.Properties and Photoelectrocatalytic Activity of In2O3-Sensitized ZnO Nanorod Array[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1021-1027
26. WANG Sha-Sha, LU Shan, SU Jia, GUO Zheng-Kai, LI Xue-Min, ZHANG Xue-Hua, HE Sheng-Tai, HE Tao.Influences of Polymerization Time on Structure and Properties of Polyaniline Counter Electrodes in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2013,29(03): 516-524
27. GUO Li-Mei, KUANG Yuan-Jiang, YANG Xiao-Dan, YU Yan-Long, YAO Jiang-Hong, CAO Ya-An.Photocatalytic Reduction of CO2 into CH4 Using SrB2O4 Catalyst[J]. Acta Phys. -Chim. Sin., 2013,29(02): 397-402
28. LI Guo-Hua, CHEN Dan, ZHENG Xiang, XIE Wei-Miao, CHENG Yuan.Preparation and Electrocatalytic Activity of WC/W2C Nanocomposite with Core-Shell Structure[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2077-2083
29. SUN Yi-Fei, LI Guang-Chao, PAN Xin-Di, HUANG Chuan-Jing, WENG Wei-Zheng, WAN Hui-Lin.Oxidative Dehydrogenation of Propane to Propylene over Mesoporous Alumina Supported Ni-Co Oxide Catalysts[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2135-2140
30. WANG Fang, WANG Cai-Hong, LI Da-Zhi.Novel Method of Controlling Formation of Hot-Spot over Gold Catalysts for CO Oxidation[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1455-1460
31. YANG Wei-Hua, YANG Wu-Tao, LIN Xiao-Yan.Preparation and Characterization of a Novel Bi-Doped PbO2 Electrode[J]. Acta Phys. -Chim. Sin., 2012,28(04): 831-836
32. WU Xiao-Qin, ZONG Rui-Long, ZHU Yong-Fa.Enhanced MnO2 Nanorods to CO and Volatile Organic Compounds Oxidative Activity by Platinum Nanoparticles[J]. Acta Phys. -Chim. Sin., 2012,28(02): 437-444
33. YIN Shi-Bin, LUO Lin, JING Sheng-Yu, ZHU Qiang-Qiang, QIANG Ying-Huai.Effect of Intermittent Microwave Heating on the Performance of Catalysts for Oxygen Reduction Reaction[J]. Acta Phys. -Chim. Sin., 2012,28(01): 85-89
34. HU Xian-Chao, CHEN Dan, SHI Bin-Bin, LI Guo-Hua.Preparation of Tungsten Carbide and Titania Nanocomposite and Its Electrocatalytic Activity for Methanol[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2863-2871
35. YE Qing, HUO Fei-Fei, YAN Li-Na, WANG Juan, CHENG Shui-Yuan, KANG Tian-Fang.Highly Active Au/α-MnO2 Catalysts for the Low-Temperature Oxidation of Carbon Monoxide and Benzene[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2872-2880
36. WANG Xi-Zhao, FU Rong, ZHENG Jun-Sheng, Ma Jian-Xin.Platinum Nanoparticles Supported on Carbon Nanofibers as Anode Electrocatalysts for Proton Exchange Membrane Fuel Cells[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1875-1880
37. YANG Zhi-Qiang, MAO Dong-Sen, WU Ren-Chun, YU Jun, WANG Qian.Preparation of CuO-Ce0.6Zr0.4O2 by Microwave Heating Decomposition and Its Catalytic Property for CO Oxidation[J]. Acta Phys. -Chim. Sin., 2011,27(05): 1163-1168
38. CHEN Jin-Yi, LI Nian, LI Jing, ZHU Liang, PENG Chang-Jun.Synthesis and Visible Light Photocatalytic Activity of Cross-Linked Sodium Rectorite/Cu2O Nanocomposites[J]. Acta Phys. -Chim. Sin., 2011,27(04): 932-938
39. SU Ya-Ling, LI Yi, DU Ying-Xun, LEI Le-Cheng.Visible-Light-Driven Catalytic Properties and First-Principles Study of Fluorine-Doped TiO2 Nanotubes[J]. Acta Phys. -Chim. Sin., 2011,27(04): 939-945
40. HU Jian-Ping, WANG Jun, TANG Dian-Yong, FU Qin-Chao, ZHANG Yuan-Qin.Reaction Mechanisms of CO Oxidation Catalyzed by Binary Copper Group Cluster Anions[J]. Acta Phys. -Chim. Sin., 2011,27(02): 329-336
41. CHEN Hua-Rong, CHANG Ran-Ran, LI Li, YUAN Wen-Hui.High Performance NaA Zeolite Membrane for Hydrogen Separation Synthesized on an Organic-Functionalized α-Al2O3 Ceramic Hollow Fiber Surface[J]. Acta Phys. -Chim. Sin., 2011,27(01): 241-247
42. HAO Ping, GAO Yun-Yan, OU Zhi-Ze, LI Yi, WANG Zhong-Li, WANG Xue-Song.Preparation of Aminopyridine Grafted Carbon Nanotube and Its Interaction with Horseradish Peroxidase[J]. Acta Phys. -Chim. Sin., 2011,27(01): 233-240
43. ZHANG Xiao-Ru, LIN Yan-Hong, ZHANG Jian-Fu, HE Dong-Qing, WANG De-Jun.Photoinduced Charge Carrier Properties and Photocatalytic Activity of N-Doped TiO2 Nanocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2733-2738
44. SONG Li-Jun, MENG Hui-Min.Electrodeposition of Nanocrystalline Nickel Alloys and Their Hydrogen Evolution in Seawater[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2375-2380
45. LIU Yu-Liang, YOU Cui-Rong, LI Yang, HE Tao, ZHANG Xiang-Qin, SUO Zhang-Huai.Preparation of Au@TiO2 Catalyst Using Escherichia Coil as the Template and Its Oxidation Reaction Activity toward CO[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2455-2460
46. WEN Zhu-Liang, YANG Su-Dong, SONG Qi-Jun, HAO Liang, ZHANG Xiao-Gang.High Activity of Pd/Graphene Catalysts for Ethanol Electrocatalytic Oxidation[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1570-1574
47. YAO Guo-Xin, SHI Bin-Bin, LI Guo-Hua, ZHENG Yi-Fan.Preparation and Electrocatalytic Activity of Tungsten Carbide and Zeolite Nanocomposite[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1317-1322
48. WANG Meng-Ye, WANG Cheng-Lin, XIE Kun-Peng, SUN Lan, LIN Chang-Jian.Fabrication of a Spongelike Nanostructured TiO2 Filmand Its Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2475-2480
49. LI Chang-Yu, LIU Shou-Xin, MA Yue.Preparation of Visible-Light Response Cu-Cu2+1O Composites by a One-Step Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1555-1560
50. CAO Yong-Qiang, LONG Hui-Jin, CHEN Yong-Mei, CAO Ya-An.Photocatalytic Activity of TiO2 Films with Rutile/Anatase Mixed Crystal Structures[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1088-1092
51. CAI Li, WANG Kang-Cai, ZHAO Ming, GONG Mao-Chu, CHEN Yao-Qiang.Application of Ultrasonic Vibrations in the Preparation of Ce-Zr-La/Al2O3 and Supported Pd Three-Way-Catalyst[J]. Acta Phys. -Chim. Sin., 2009,25(05): 859-863
52. XIAO Xiao-Yan, LU Ji-Qing, SU Xiao-Wen, GUO Ming, LUO Meng-Fei.PdO-CeO2 Composite Catalysts for Low Temperature CO Oxidation[J]. Acta Phys. -Chim. Sin., 2009,25(03): 561-566
53. YU Jun-Jie; ZHU Ling; ZHOU Bo; SHAO Li-Nan; ZHANG Yu-Ting; HE Xu-Wen.N2O Catalytic Decomposition over Mixed Oxides Derived from Zn-substituted Hydrotalcite-like Compounds[J]. Acta Phys. -Chim. Sin., 2009,25(02): 353-359
54. SHI Yan-Hua; MENG Hui-Min; SUN Dong-Bai; YU Hong-Ying; FU Hua-Rong.Manganese Oxide Coating Electrodes Prepared by Pulse Anodic Electrodeposition[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1199-1206
55. LUO Da-Chao; ZHANG Lan-Lan; LONG Hui-Jin; CHEN Yong-Mei; CAO Ya-An.Effect of Surface Modification by Ni2+ on Photocatalysis Activity of TiO2[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1095-1099
56. ZHOU Jian-Hua; HE Jian-Ping; JI Ya-Jun; ZHAO Gui-Wang; ZHANG Chuan-Xiang; CHEN Xiu; WANG Tao.Influence of Hierarchical Porosity in Carbon Material on Electrocatalytic Property of Supported Pt Nanoparticles[J]. Acta Phys. -Chim. Sin., 2008,24(05): 839-843
57. WEN Li; LIN Zhong-Yu; ZHOU Jian-Zhang; GU Ping-Ying; FU Jin-Kun; LIN Zhong-Hua.Au/γ-Al2O3 Catalyst Prepared from Octanethiolate Monolayer Protected Au Nanoparticles for CO Oxidation[J]. Acta Phys. -Chim. Sin., 2008,24(04): 581-586
58. LIU Shou-Xin; CHEN Xiao-Yun.Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO2/AC Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(03): 533-538
59. LIANG Ying; LIAO Dai-Wei.Effects of pH on the PtRu/C Catalyst Prepared by Microwave-assisted Ethylene Glycol Process[J]. Acta Phys. -Chim. Sin., 2008,24(02): 317-322
60. ZHAN Ying-Ying; CAI Guo-Hui; ZHENG Yong; SHEN Xiao-Nv; ZHENG Ying; WEI Ke-Mei.Synthesis of High Surface Area Silicon Carbide and Its Application in CO Oxidation Reaction[J]. Acta Phys. -Chim. Sin., 2008,24(01): 171-175
61. CHEN Qi-Yuan; TONG Hai-Xia; YIN Zhou-Lan; HU Hui-Ping; LI Jie; LIU Liang-Liang.Preparation, Characterization and Photo-catalytic Behavior of TiO2 Catalysts with Oxygen Vacancies[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1917-1921
62. TIAN Bao-Zhu; TONG Tian-Zhong; CHEN Feng; ZHANG Jin-Long.Effect of Water Washing Treatment on the Photocatalytic Activity of Au/TiO2 Catalysts[J]. Acta Phys. -Chim. Sin., 2007,23(07): 978-982
63. YAN Zhi-Ying; WU Li-Yan; SUN Gui-Xiang; ZHANG Ning; ZHENG Wen-Jun.Structural Characterization of Nanocrystalline TiO2 fromIonic Liquid-Water Solvent Mixture and Its Photocatalytic Activity[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1032-1036
64. WU Yan; YAO Wen-Qing; ZHU Yong-Fa.Interfacial Structure of Ta2O5/Si Filmand Photoactivity[J]. Acta Phys. -Chim. Sin., 2007,23(05): 625-629
65. YAN Shan-Shan;WU Lian-Di;CHEN Feng;ZHANG Jin-Long.Low-temperature Preparation and Characterization of TiO2 Thin Films with a Bicrystalline Framework[J]. Acta Phys. -Chim. Sin., 2007,23(03): 414-418
66. YANG Xi-Kun;LI Yang;HENG Gen-Hua.Structure and Catalytic Properties of PtRu Alloy Thin-film[J]. Acta Phys. -Chim. Sin., 2007,23(03): 389-393
67. TAO Yan-Xin;YU Jun-Jie;LIU Chang-Chun;HAO Zheng-Ping;ZHANG Ze-Peng .Study on N2O Catalytic Decomposition over Mixed Oxides Derived from Co-Mg/Al Hydrotalcite-like Compounds[J]. Acta Phys. -Chim. Sin., 2007,23(02): 162-168
68. HU Ji-Ming;HOU Yan-Yuan;WANG Xiao-Mei;ZHANG Jian-Qing;CAO Chun-Nan .Effect of Calcination Procedure on the Electrocatalytic Activities of Ti/IrO2 Electrodes in Acidic Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(08): 1010-1014
69. WANG Zhen-bo; YIN Ge-ping; SHI Peng-fei.The Influence of Three Groups of Pt-Ru/C Catalyst’s Precursors on Its Performance for Direct Methanol Fuel Cell[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1156-1160
70. CAO Jie-ming; WANG Jun; FANG Bao-qing; ZHENG Ming-bo; LU Hong-xia; CHANG Xin; WANG Hai-yan.Synthesis and Characterization of ZnO Nanomaterials with Different Morphologies in Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2005,21(06): 668-672
71. TIAN Na;CHEN Wei;SUN Shi-Gang.Spectroscopic Characterization and Electrocatalytic Properties of Core-Shell Au-Pt Nanoparticles[J]. Acta Phys. -Chim. Sin., 2005,21(01): 74-78
72. Peng Cheng;Cheng Xuan;Zhang Ying;Chen Ling;Fan Qing-Bai.Comparison of Methanol Electrooxidation on Carbon Supported Pt and PtRu Catalysts[J]. Acta Phys. -Chim. Sin., 2004,20(04): 436-439
73. Wang Shu-Rong;Wu Shi-Hua;Shi Juan;Zheng Xiu-Cheng;Huang Wei-Ping.Preparation and Catalytic Activity of Au/SnO2 for Low-temperature CO Oxidation[J]. Acta Phys. -Chim. Sin., 2004,20(04): 428-431
74. Zhang Min;Jin Zhen-Sheng;Wang Shou-Bin;Zhang Shun-Li;Zhang Zhi-Jun.The Photocatalytic Enhancement Effect of CO on Pd/TiO2[J]. Acta Phys. -Chim. Sin., 2003,19(02): 100-104
75. An Zeng-Jian;Zhou Peng;Jian Xi-Gao;Cai Tian-Xi.Catalytic Activity of Sulfonated Poly (phthalazinone ether sulfone ketone) Resin[J]. Acta Phys. -Chim. Sin., 2003,19(01): 1-3
76. Jing Li-Qiang;Sun Xiao-Jun;Cai Wei-Min;Zheng Da-Fang;Xu Yue;Xu Zhao-Peng;Xu Zi-Li;Du Yao-Guo.Study of SPS and XPS of Pd/ZnO and Ag/ZnO Composite Nanoparticles[J]. Acta Phys. -Chim. Sin., 2002,18(08): 754-758
77. Yu Jia-Guo;Zhao Xiu-Jian;Chen Wen-Mei;Lin Li;Zhang Ai-Li.Photocatalytic Activity and Hydrophilic Property of TiO2/SiO2 Composite Nanometer Thin Films[J]. Acta Phys. -Chim. Sin., 2001,17(03): 261-264
78. Liu Han-Xing, Zhao Shi-Xi, Liu Zhi-Jian, Ouyang Shi-Xi.Study on the Influence of Microwave Field on Heating in SrTiO3 Synthesis[J]. Acta Phys. -Chim. Sin., 2000,16(12): 1067-1072
79. Zhao Zhen-Bo, Sun Wen-Dong, Yang Xiang-Guang, Ye Xing-Kai, Wu Yue.Active Components and Mechanism of Isobutane Alkylation with Butenes in the Catalytic System of HPAs+AcOH[J]. Acta Phys. -Chim. Sin., 2000,16(07): 613-620
80. Wen Bin, He Ming-Yuan, Song Jia-Qing, Zong Bao-Ning, Shu Xing-Tian, Lu Yong.Study on the Reduction of NO by CO in the Presence of Oxygen[J]. Acta Phys. -Chim. Sin., 1999,15(10): 868-871
81. Zeng Jian-Qing, Zhang Jing-Cheng, Zhong Bing.Monte Carlo Simulation of CO Oxidation Reaction on Fractal Surface[J]. Acta Phys. -Chim. Sin., 1999,15(06): 555-559
82. Liu Ying-Jun, Zhang Ji-Jun, Li Neng, Lin Bing-Xiong.The Effect of CO2 on Catalytic Activity of Cu-Ce-O Complex Oxides for CO Oxidation[J]. Acta Phys. -Chim. Sin., 1999,15(02): 97-100
83. Zhang Ji-Jun, Liu Ying-Jun, Li Neng, Lin Bing-Xiong.Synergistic Effect between CuO and CeO2 for CO Oxidation[J]. Acta Phys. -Chim. Sin., 1999,15(01): 15-21
84. Fu Jin-Kun, Liu Yue-Ying, Hu Rong-Zong, Zeng Jin-Long, Xu Pian-Pian, Lin Zhong-Yu, Yao Bing-Xin, Weng Cheng-Zhou.Preparation of Highly Dispersive Supported Gold Catalyst by Microbial Reduction Method[J]. Acta Phys. -Chim. Sin., 1998,14(09): 769-771
85. Ma Zhi, Qin Yong-Ning, Qi Xiao-Zhou, Liang Zhen-Cheng, He Fei.Studies on Prepartion and CO Oxidation Activity of LaSrBO4 Compound[J]. Acta Phys. -Chim. Sin., 1998,14(05): 453-457
86. Zhou Ren-Xian, Chen Fang, Jiang Xiao-Yuan, Zheng Xiao-Ming.The Dispersed States of Manganese Species on Mn-O/ZrO2 Catalysts and its Influents on the Catalytic Performance[J]. Acta Phys. -Chim. Sin., 1998,14(02): 178-180
87. Zeng Jian-Qing,Zhang Jing-Cheng,Guo Xiang-Yun,Zhong Bing.The Influence of Diffusion on the First Order Phase Transition Point of CO Oxidation:Monte Carlo Simulation[J]. Acta Phys. -Chim. Sin., 1997,13(02): 183-187
88. Zhou Ren-Xian,Jiang Xiao-Yuan,Lv Guang-Lie,Zheng Xiao-Ming.Desorption of Surface Oxygen on Cu/ZrO2-γ-Al2O3 and its Influence on the Catalytic Performance[J]. Acta Phys. -Chim. Sin., 1997,13(02): 128-133
89. Fu Xiang-Kai,Ma Xue-Bing,Wen Shu-Ying,Liu Chang-Hua.Study on the Crystallinity of ZGDMP and the Catalytic Activities of ZGDMP-Pd Catalysts for Hydrogenation[J]. Acta Phys. -Chim. Sin., 1996,12(12): 1079-1083
90. Li Xu-Yuan,Zhang Zi-Ping,Ma Jian-Tai,Zhu Zong-Zhen,Meng Yi-Min.The Catalytic Activity for CO Oxidation and Characterization of Perovskite-type Oxides Catalysts La1+X/2Sr1-x/2Co1-xCuxO3[J]. Acta Phys. -Chim. Sin., 1996,12(06): 502-507
91. ZHOU Ren-Xian, WEI Jian-Gen, ZHENG Xiao-Ming, WU Hong-Li, LV Guang-Lie.Study on Phase Structure, Pore Structure and catalytic Property of Out-layer ZrO2 on Alumina Base[J]. Acta Phys. -Chim. Sin., 1995,11(12): 1097-1100
92. Ren Yan-Zhi, Yu Jian-Feng, Wu Tong-Hao, Wang De-Jun, Cui Yi.The Effect of Modulated Surface Band Bending on Photovoltage Spectra[J]. Acta Phys. -Chim. Sin., 1995,11(03): 274-278
93. Zheng Guo-Dong, Yan Yan, Gao Sai, Tong Shan-Ling, Gao De.Ellectrocarboxylation of Organic Compounds with Carbon Dioxide Catalyzed by Metalloporphyrins III.Effects of Axial Ligands on Catalytic Activity of CoTPP[J]. Acta Phys. -Chim. Sin., 1994,10(11): 1035-1039
94. Kan Jin-Qing; Mu Shao-Lin.The Study of Properties for the Polyaniline Uricase Electrode[J]. Acta Phys. -Chim. Sin., 1993,9(03): 345-350
95. Wang Qiu-Ying; Jian Pan-Ming; Zhu Chao; Zhai Ying-Li.Studies on Silicon-Rich PrHY Zeolites of Ultrastability by IR AND 29Si MAS NMR[J]. Acta Phys. -Chim. Sin., 1993,9(01): 50-55
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top