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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2011,Vol.27>> Issue(02)>> 479-485     doi: 10.3866/PKU.WHXB20110221         中文摘要
ELECTROCHEMISTRY AND NEW ENERGY
Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon
TIAN Ying1,2, YAN Jing-Wang1, XUE Rong1, YI Bao-Lian1
1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China;
2. College of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian 116028, Liaoning Province, P. R. China
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The influences of electrolyte concentration and temperature on the capacitive behavior of activated carbon (AC) were investigated by cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge/discharge measurements. The performance of a symmetric capacitor was characterized in 0.1, 0.5, 1.0, and 6.0 mol·L-1 KOH solution. We found that the high electrolyte concentration led to high capacitance, low internal resistance, and a narrow voltage window. The capacitance and internal resistance were found to be linearly dependent on the logarithm of KOH concentration. AC supercapacitor performance was investigated at 20, 40 and 80 °C, respectively. We found that elevated temperatures are favorable for an increase in capacitance and for a decrease in internal resistance. However, elevated temperatures increase the capacitance fading rate during long charge/discharge cycling tests.



Keywords: Supercapacitor   Activated carbon   Electrolyte concentration   Temperature  
Received: 2010-08-24 Accepted: 2010-11-17 Publication Date (Web): 2011-01-04
Corresponding Authors: YAN Jing-Wang Email: yanjw@dicp.ac.cn

Fund: The project was supported by the Important Directional Project of ‘The Research and Exploration of Supercapacitor Storage System for Electric Vehicle’ from Dalian Institute of Chemical Physics, Chinese Academy of Sciences, China.

Cite this article: TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian. Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27 (02): 479-485.    doi: 10.3866/PKU.WHXB20110221

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73. LI Zhao, XU Ju-Liang, LI Xu-Yan, GUO Li-Fang, LI Jin, JIANG Yi-Ming.Preparation of Manganese Dioxide for Electrodes of Supercapacitors Based on Duplex Stainless Steel[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1424-1430
74. LIU Yun, HE You-Zhou, YUAN Li-Hua, FENG Wen.Synthesis and Self-Assembly of an Oligoaramide Containing Multiple Hydrogen Bonds[J]. Acta Phys. -Chim. Sin., 2011,27(04): 918-924
75. MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui.Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2011,27(04): 893-899
76. ZHAN Wang-Cheng, ZHOU Guo-Jun, CHU Guo-Hai, SHEN Kai, YU Jun, WANG Ai-Yong, SU Na, LU Guan-Zhong, GUO Yang-Long.Effect of Supports on the Catalytic Performance of Pd-Cu/Activated Carbon Catalyst for Eliminating CO in Cigarette Smoke[J]. Acta Phys. -Chim. Sin., 2011,27(03): 705-710
77. YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
78. LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min.Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Phys. -Chim. Sin., 2011,27(03): 620-626
79. LI Jin-Hua, LIU Bao-Zhong, HAN Shu-Min, HU Lin, ZHU Xi-Lin, WANG Ming-Zhi.Phase Structure and Hydrogen Storage Properties of LaMg8.40Ni2.34 Alloy[J]. Acta Phys. -Chim. Sin., 2011,27(02): 403-407
80. ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun.Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2011,27(02): 455-460
81. ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke.5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3175-3180
82. ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen.Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3169-3174
83. WANG Wen-Qing, SHEN Xin-Chun, GONG Yan.Cryogenic Magnetic Transition of D- and L-Alanine: Magnetic Field Dependence of Specific Heat and DC Magnetic Susceptibility[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2597-2603
84. HU Ren-Zhi, ZHANG Qun, CHEN Yang.Temperature Dependence of Reactions of C2(a3Πu) Radical with Several Unsaturated Hydrocarbons[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2619-2624
85. TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
86. YUAN Peng, LIU Zhong-Yi, SUN Hai-Jie, LIU Shou-Chang.Influence of Calcination Temperature on the Performance of Cu-Al-Ba Catalyst for Hydrogenation of Esters to Alcohols[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2235-2241
87. YANG Wei-Ben, REN Li.Adsorption Mechanism of Nonylphenol Polyethoxylate onto Hypercrosslinked Resins[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2182-2188
88. ZHANG Sa, LIU Shou-Xin, HAN Xiao-Yu, DANG Li, QI Xiao-Jun, YANG Xi.Synthesis of P(DEAM-co-NAS) and the Environmental Effects of Its Temperature Sensitivity[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2189-2194
89. LI Li-Min, LIU En-Hui, LI Jian, YANG Yan-Jing, SHEN Hai-Jie, HUANG Zheng-Zheng, XIANG Xiao-Xia.Polyaniline-Based Carbon for a Supercapacitor Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1521-1526
90. JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song.Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1254-1258
91. DING Liang-Xin, WANG Shi-Rui, ZHENG Xiao-Long, CHEN Yu, LU Tian-Hong, CAO Dian-Xue, TANG Ya-Wen.Effect of Carbon Modification on Electrocatalytic Performance of Carbon Supported Pd Catalysts[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1311-1316
92. ZHANG Tian-Yong, YANG Qiu-Sheng, SHI Hui-Xian, HAN Cong, LIU Xu.Adsorption of Naphthalene on a Viscose-Based Activated Carbon Fiber[J]. Acta Phys. -Chim. Sin., 2010,26(02): 367-372
93. ZANG Yang, HAO Xiao-Gang, WANG Zhong-De, ZHANG Zhong-Lin, LIU Shi-Bin.Copolymerization and Capacitive Performance of Composite Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Films[J]. Acta Phys. -Chim. Sin., 2010,26(02): 291-298
94. XU Xin, WANG Xiao-Jing, HU Zhong-Hua, LIU Ya-Fei, WANG Chen-Chen, ZHAO Guo-Hua.Influence of Sol-Gel and Dip-Hydrothermal Preparation Methods on Structure and Performance of TiO2/AC Photocatalysts[J]. Acta Phys. -Chim. Sin., 2010,26(01): 79-86
95. LI Juan, MO Xiao-Liang, SUN Da-Lin, CHEN Guo-Rong.Preparation of CuInS2 Thin Films by One-Step Electrodeposition[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2445-2449
96. PANG Xu, MA Zheng-Qing, ZUO Lie.Sn Doped MnO2 Electrode Material for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2433-2437
97. FU Qing-Bin, GAO Bo, SU Ling-Hao, YUAN Chang-Zhou, LU Xiang-Jun, ZHANG Xiao-Gang.Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi-Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2199-2204
98. SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
99. WANG Yan-Kun, ZHANG Jian-Min, LAN Meng.Temperature Effects on ZnO Film Electrodeposition[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1998-2004
100. XU Cong, LI Wei, PAN Gang.Particle Concentration Effect on Zn(II) Adsorption at Water-Goethite Interfaces[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1737-1742
101. WANG Huan-Xia, LIU Shou-Xin, FANG Yu, HAN Xiao-Yu, ZHANG Sa.Synthesis of Poly(N,N-diethylacrylamide) and the Effect of Salts on the Thermosensitivity of Its Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1911-1915
102. XING Li-Qiong, QIAN Lin, BI Qing-Yuan, HE Jun, WANG Yue-Juan, ZHOU Li-Yang, CHEN Ke-Feng, LU Ji-Qing, LUO Meng-Fei.Effect of Cr Species in CrOx-Y2O3 Catalyst on Chlorine/Fluorine Exchange Reactions[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1928-1932
103. JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
104. DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
105. CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
106. GAO Qiang; LIU Ya-Fei; HU Zhong-Hua; ZHENG Xiang-Wei; WEN Zu-Biao.Electrochemical Properties of Manganese Oxide Surface-Modified Activated Carbon Electrode Materials[J]. Acta Phys. -Chim. Sin., 2009,25(02): 229-236
107. CUI Hu-Xiong, CHENG Tian-Tao, CHEN Jian-Min, XU Yong-Fu, FANG Wen.A Simulated Heterogeneous Reaction of SO2 on the Surface of Hematite at Different Temperatures[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2331-2336
108. JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
109. CHEN Yu-Juan; HU Zhong-Hua; WANG Xiao-Jing; ZHAO Guo-Hua; LIU Ya-Fei; LIU Wei.Influence of Pore Size and Surface Area of Activated Carbon on the Performance of TiO2/AC Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1589-1596
110. LIU Ya-Fei; HU Zhong-Hua; XU Kun; ZHENG Xiang-Wei; GAO Qiang.Surface Modification and Performance of Activated Carbon Electrode Material[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1143-1148
111. LI Jin-Wei; ZHAN Ying-Ying; LIN Xing-Yi; ZHENG Qi.Influence of Calcination Temperature on Properties of Au/Fe2O3 Catalysts for Low Temperature Water Gas Shift Reaction[J]. Acta Phys. -Chim. Sin., 2008,24(06): 932-938
112. GUO Liang; WU Zhan-Song.Mechanism of Methane’s Adsorption on Nanometer Active Carbon at Supercritical State[J]. Acta Phys. -Chim. Sin., 2008,24(05): 737-742
113. XIE Wei-Jie; LI Long-Hai; ZHOU Bao-Xue; CAI Wei-Min.Emission Spectroscopy and Energy Transfer Process in Atmospheric Dielectric Barrier Discharge in Oxygen[J]. Acta Phys. -Chim. Sin., 2008,24(05): 827-832
114. WEN Li; LIN Zhong-Yu; ZHOU Jian-Zhang; GU Ping-Ying; FU Jin-Kun; LIN Zhong-Hua.Au/γ-Al2O3 Catalyst Prepared from Octanethiolate Monolayer Protected Au Nanoparticles for CO Oxidation[J]. Acta Phys. -Chim. Sin., 2008,24(04): 581-586
115. LIU Shou-Xin; CHEN Xiao-Yun.Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO2/AC Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(03): 533-538
116. ZENG Wen-Wen; HUANG Ke-Long; YANG You-Ping; LIU Su-Qin; LIU Ren-Sheng.Solvothermal Synthesis and Capacitance Performance of Co3O4 with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2008,24(02): 263-268
117. YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
118. CHEN Cong; LI Wei-Zhong.Determination of Homogeneous Nucleation Temperature of Intracellular Solution during Cooling[J]. Acta Phys. -Chim. Sin., 2008,24(01): 74-78
119. YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu.Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1365-1369
120. WAN Hai-Jun; WU Bao-Shan; AN Xia; TAO Zhi-Chao; LI Ting-Zhen; XIANG Hong-Wei; LI Yong-Wang.Structural Properties, Reduction and Carburization Behaviors of Fe/Cu/K/Al2O3 Catalyst for Fischer-Tropsch Synthesis[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1151-1156
121. LIU Su-Qin; GONG Ben-Li; HUANG Ke-Long; ZHANG Ge; LI Shi-Cai.Effect of Calcination Temperature on the Compositions and Electrochemical Performance of Products in the Synthesis of LiFePO4[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1117-1122
122. GE Li; HUI Xi-Dong; CHEN Guo-Liang; LIU Zi-Kui.Prediction of the Glass-Forming Ability of Cu-Zr Binary Alloys[J]. Acta Phys. -Chim. Sin., 2007,23(06): 895-899
123. WANG Jie; XU You-Long; SUN Xiao-Fei; XIAO Fang; MAO Sheng-Chun.Capacitance Properties of Porous Polypyrrole Thick Films Prepared Electrochemically by Multi-step Polymerization[J]. Acta Phys. -Chim. Sin., 2007,23(06): 877-882
124. LI Wei; PAN Gang; CHEN Hao; ZHANG Mei-Yi; HE Guang-Zhi; LI Jin; YANG Yu-Huan.Temperature Effects on Adsorption-Desorption Irreversibility of Zn(II) onto Anatase[J]. Acta Phys. -Chim. Sin., 2007,23(06): 807-812
125. WANG Jie;XU You-Long;CHEN Xi;DU Xian-Feng;LI Xi-Fei.Effect of Doping Ions on Electrochemical Capacitance Properties of Polypyrrole Films[J]. Acta Phys. -Chim. Sin., 2007,23(03): 299-304
126. QIU Kai-Dong;LI Wei-Bin.Adsorption of Hexavalent Chromium Ions on Multi-wall Carbon Nanotubes in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1542-1546
127. YE Xiu-Dong;ZHOU Guo-Yan;HUA Ze-Zhao .A new Method for Measuring the Glass Transition Temperature of the Maximally Freeze-concentrated Glucose Solution by DSC[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1347-1352
128. ZOU Yu-Man;WANG Shi-Zhong .Preparation of Sm0.5Sr0.5CoO3-La0.8Sr0.2Ga0.8Mg0.15Co0.05O3 composite cathodes using wet-chemistry method and characterization of their properties[J]. Acta Phys. -Chim. Sin., 2006,22(08): 958-961
129. LIU Yi-An;XUE Cheng-Shan;ZHUANG Hui-Zhao;ZHANG Xiao-Kai;TIAN De-Heng;WU Yu-Xin;SUN Li-Li;AI Yu-Jie;WANG Fu-Xue.Structure and Synthesis of GaN Powder by Sol-Gel Method[J]. Acta Phys. -Chim. Sin., 2006,22(06): 657-660
130. SUN Yuan-Hua;ZHANG Tong-Lai;ZHANG Jian-Guo;YANG Li;QIAO Xiao-Jing.Kinetics of Flash Pyrolysis of [Co(CHZ3](ClO42 and [Ni(CHZ)3](ClO4)2[J]. Acta Phys. -Chim. Sin., 2006,22(06): 649-652
131. CHEN Xiao-Yun;LIU Shou-Xin;CHEN Xi;SUN Cheng-Lin.Characterization and Activity of TiO2 /wAC Composite Photocatalyst Prepared by Acid Catalyzed Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 2006,22(05): 517-522
132. YU Juan-Li;LIU Shou-Xin;FANG Yu;GAO Gai-Ling;WANG Ming-Zhen.The Phase Behaviors of Temperature- and pH-sensitive Poly(methacrylic acid-g-N, N-diethylacrylamide) Dilute Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2006,22(05): 579-583
133. PENG Chun-Yu;ZHOU Hai-Hui;ZENG Wei;JIAO Shu-Qiang;LUO Sheng-Lian;KUANG Ya-Fei.Studies on the Conductivity of Reverse Microemulsion[J]. Acta Phys. -Chim. Sin., 2006,22(04): 409-413
134. MEI Yan;HAN Ye-Bin;NIE Zuo-Ren.The Influence of Reaction Temperature on the Morphology and Formation Mechanism of Ce2(C2O4)3•10H2O Powders[J]. Acta Phys. -Chim. Sin., 2006,22(04): 492-495
135. YIN Hai-qing; HUANG Jian-bin.Progress in the Temperature-controlled Transition of Self Assemblies in Surfactant Solutions[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1324-1330
136. DONG Yan-ming; RUAN Yong-hong; ZHAO Ya-qing; BI Dan-xia; YANG Liu-lin; GE Qiang.Studies on Glass Transition Temperature ofNl Chitosan[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1307-1310
137. YAN Chang-ling; LU Yan; ZHOU Jian-guo.Study on the Composition and Mechanism of Precipitated Solid Phases from MgO•3B2O3-18%MgSO4-H2O Supersaturated Solution[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1161-1163
138. WANG Wen-qing; MIN Wei; GONG Yan.Temperature- induced Phase Transitions in Chiral Amino Acids——Search of Spontaneous Parity- Breaking and Restoration[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1186-1194
139. LIU Chun-ling; WEN Yue-hua; CHENG Jie; GUO Quan-gui; CAO Gao-ping; LIU Lang; YANG Yu-sheng.Influence of Pore Structure of Phenolic Resin Based Activated Carbon Fibers on the Electrochemical Performance of Electrical Double-layer Capacitors[J]. Acta Phys. -Chim. Sin., 2005,21(07): 786-791
140. WANG Wen-qing; GONG Yan; YAO Nan.Temperature Effect on Molecular Chirality:X-ray Diffraction and Neutron Diffraction Studies of D-alanine[J]. Acta Phys. -Chim. Sin., 2005,21(07): 774-781
141. LIU Wan-qiang; WANG Xue-ye; LI Xin-fang; LONG Qing-ping; WEN Xiao-hong; LI Jianjun.Quantum Chemistry-ANN Methods Study on Tg of Polyacrylates[J]. Acta Phys. -Chim. Sin., 2005,21(06): 596-601
142. YANG Hong-Sheng; ZHOU Xiao; ZHANG Qing-Wu.Electrochemical Performances of Supercapacitor with Polyaniline Particles with Hierarchy as Active Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(04): 414-418
143. WANG Xiao-Feng; WANG Da-Zhi; LIANG Ji.Pseudo-capacitance of Ultrafine Nickel Hydroxide Prepared by Sol-gel Method[J]. Acta Phys. -Chim. Sin., 2005,21(02): 117-122
144. Yu Xue-Chun;Peng Hai-Lin;Zhang Ran;Zhang Ying-Ying;Liu Zhong-Fan.Influence of Decomposition Temperature on the Threshold Voltage for a Series of Charge Transfer Complexes[J]. Acta Phys. -Chim. Sin., 2004,20(06): 565-568
145. Jiang Qi;Lu Xiao-Ying;Zhao Yong;Yu Zuo-Long.Effect of Microstructure’s Change on Electrochemical Capacitance of Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2004,20(05): 546-549
146. Liu Xian-Ming;Zhang Yi-He;Zhang Xiao-Gang;Fu Shao-Yun.The Supercapacitive Properties of Ni-Ru Oxide Composites[J]. Acta Phys. -Chim. Sin., 2004,20(04): 417-420
147. Wang Shi-Zhong;Liu Xuan.Preparation and Characterization of High Performance Sm0.5Sr0.5CoO3 Cathodes[J]. Acta Phys. -Chim. Sin., 2004,20(04): 391-395
148. Deng Mei-Gen;Zhang Zhi-An;Hu Yong-Da;Wang Bin-Hua;Yang Bang-Chao.Effect of Activation and Surface Modification on the Properties of Carbon Nanotubes Supercapacitors[J]. Acta Phys. -Chim. Sin., 2004,20(04): 432-435
149. Bian Feng-Ling;Liu Ming-Zhu;Sheng Fen-Ling.A Study of Solution Properties of Poly(N-isopropylacrylamide) and Poly(N,N-diethylacrylamide) in Mixed Solvent of Water-Methanol[J]. Acta Phys. -Chim. Sin., 2004,20(04): 337-343
150. Lu Dong-Yun;Wen Hao;Liu Hui-Zhou;Xu Zhi-Hong.Temperature Effects on Block Copolymer Micelle Based on the Scaling Model[J]. Acta Phys. -Chim. Sin., 2004,20(01): 38-42
151. Li Jian-Gang;Wan Chun-Rong;Yang Dong-Ping;Yang Zhang-Ping.Effect of Cell Temperature on the Electrochemical Reaction of LiNi3/8Co2/8Mn3/8O2[J]. Acta Phys. -Chim. Sin., 2003,19(11): 1030-1034
152. Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
153. Wang Xiao-Feng;Wang Da-Zhi;Liang Ji.Carbon Nanotube Capacitor Materials Loaded with Different Amounts of Ruthenium Oxide[J]. Acta Phys. -Chim. Sin., 2003,19(06): 509-513
154. Zhang Bao-Hong;Zhang Na.Research on Nanophase MnO2 for Electrochemical Supercapacitor[J]. Acta Phys. -Chim. Sin., 2003,19(03): 286-288
155. Zhang Jian-He.Stimuli-response of Hydrophilic-hydrophobic Semi-IPN Hydrogels on Temperature[J]. Acta Phys. -Chim. Sin., 2003,19(01): 90-93
156. Bian Feng-Ling;Liu Ming-Zhu.The Temperature Dependence of the Viscosity of Poly (N,N-diethylacrylamide) Solutions[J]. Acta Phys. -Chim. Sin., 2002,18(09): 776-780
157. Chen Fu-Liang;Wang Yi;Zheng Fei-Neng;Liang Wen-Ping.Stability of Agrochemical Microemulsions at Low Temperature[J]. Acta Phys. -Chim. Sin., 2002,18(07): 661-664
158. Xing Wei;Zhang Ming-Jie;Yan Zi-Feng.Synthesis and Activation Mechanism of Coke Based Super Activated Carbons[J]. Acta Phys. -Chim. Sin., 2002,18(04): 340-345
159. Liang Kui;Chen Ai;Feng Zhe-Sheng;Ye Zhi-Xiang.AC Impedance Analysis of Supercapacitors Utilizing Carbon Nanotube Electrodes[J]. Acta Phys. -Chim. Sin., 2002,18(04): 381-384
160. Gong Yu-Jun;Zhu Bu-Yao;Zhao Guo-Xi.Study on the Aguous Surfactant TwoPhase of Dodecyltrimethylammonium Bromide(DTAB)Sodium Laurate(SL) Mixed System[J]. Acta Phys. -Chim. Sin., 2001,17(11): 1027-1030
161. Kong Yong;Mu Shao-Lin.Electrochemical Evidence of Semiconductor Properties of Polythionine[J]. Acta Phys. -Chim. Sin., 2001,17(09): 806-810
162. Liu Zhen-Yu;Zheng Jing-Tang;Wang Mao-Zhang;Zhang Bi-Jiang.Study for Nitrogen Adsorption of PAN-based Activated Carbon Fibers[J]. Acta Phys. -Chim. Sin., 2001,17(07): 594-599
163. Lu An-Hui;Li Wen-Cui;Zheng Jing-Tang.Preparation of PANbased Molecular Sieve ACF and Study of Surface Structure by XPS[J]. Acta Phys. -Chim. Sin., 2001,17(03): 216-221
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165. Dai Le-Rong, Dong Xiang-Qun.The Temperature Coefficient of Interfacial Tension[J]. Acta Phys. -Chim. Sin., 1999,15(01): 64-68
166. Li Hua-Ping, Wang Peng-Fei, Wu Shi-Kang.Temperature Dependence of Excimer Formation of a New Kind of Fluorescence Chemosensor[J]. Acta Phys. -Chim. Sin., 1998,14(11): 995-1000
167. He Xu, Zhu Bu-Yao, Zhao Guo-Xi.Influence of pH on the Properties of the Vesicles and Foams in the Aqueous Dispersion of 2RNC2[J]. Acta Phys. -Chim. Sin., 1998,14(10): 932-935
168. Wang Xiao-Yong, Wang Min, Zhao Bi-Ying, Xie You-Chang.Spontaneous Monolayer Dispersion of Some Organic Compounds on Oxide-supports[J]. Acta Phys. -Chim. Sin., 1998,14(10): 869-873
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170. Lu Hui-Zhe,Qiu Yong-Qing,Zhao Cheng-Da.Magnetism and Ferromagnetic Transition Temperature of a Series of PYNN Molecules[J]. Acta Phys. -Chim. Sin., 1996,12(11): 1015-1017
171. Bian Guo-Zhu,Ma Yun-Sheng,Fu Yi-Lu,Xie Ya-Ning,Hu Tian-Dou.Catalytic Properties for Mixed Alcohols Synthesis and Structure of Co-K-Mo/γ-Al2O3[J]. Acta Phys. -Chim. Sin., 1996,12(05): 406-412
172. Miao Rui-Ping,Dai Min-Ping.Study of Activatied Carbon on the Adsorption of Titan Yellow from Aqueous Solution[J]. Acta Phys. -Chim. Sin., 1996,12(02): 173-176
173. Wang Xin-Ping,Ye Xing-Kai,Wu Yue.Chemical Bonding between Heteropoly Acid and Oxygen-containing Groups on the Surface of Activated Carbon[J]. Acta Phys. -Chim. Sin., 1995,11(12): 1105-1109
174. Xiong Xing-Min,Yang Ju-Hua,Ye Mei-Ling,Zhang Ying-Jiu,Shi Liang-He.Study of Temperature Effect of Micellar Solutions of PSDMS Block Copolymer in n-Heptane by Positron Annihilation[J]. Acta Phys. -Chim. Sin., 1995,11(06): 541-546
175. Mu Guan-Nan, Yang Chun-Fen.Adsorption of Zinc(II) Ion and its Complexes from Solution by Activatied Charcoal[J]. Acta Phys. -Chim. Sin., 1995,11(02): 157-161
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