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Acta Physico-Chimica Sinica  2011, Vol. 27 Issue (03): 743-748    DOI: 10.3866/PKU.WHXB20110318
PHYSICAL CHEMISTRY OF MATERIALS     
Controlled Synthesis of Mesoporous MnO2 Nanospindles
HAN Ling, NI Ji-Peng, ZHANG Liang-Miao, YUE Bao-Hua, SHEN Shan-Shan, ZHANG Hao, LU Wen-Cong
Department of Chemistry, Shanghai University, Shanghai 200444, P. R. China
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Abstract  

We synthesized mesoporous MnO2 nanospindles by a one-step hydrothermal process in an aqueous solution of KMnO4 and glucose. The structure, morphology, purity, and size of the products were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), and nitrogen adsorption/desorption (BET) measurements. The reaction time and concentrations of glucose influenced the final structures and shapes of the MnO2 nanospindles. The length to diameter ratio of the MnCO3 precursor nanospindles can be easily tuned from 1.35:1 to 2.89:1. A possible formation mechanism for the mesoporous MnO2 nanospindles is proposed and discussed.



Key wordsHydrothermal method      Spindle      MnO2      Mesoporous     
Received: 27 September 2010      Published: 28 January 2011
MSC2000:  O641  
Fund:  

The project was supported by the Shanghai Special Nanotechnology Project, China (0852nm00700) and Innovation Fund of Shanghai University, China (A.10-0101-09-023).

Corresponding Authors: LU Wen-Cong     E-mail: wclu@shu.edu.cn
Cite this article:

HAN Ling, NI Ji-Peng, ZHANG Liang-Miao, YUE Bao-Hua, SHEN Shan-Shan, ZHANG Hao, LU Wen-Cong. Controlled Synthesis of Mesoporous MnO2 Nanospindles. Acta Physico-Chimica Sinica, 2011, 27(03): 743-748.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20110318     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2011/V27/I03/743

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