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Acta Phys. -Chim. Sin.  2011, Vol. 27 Issue (03): 711-716    DOI: 10.3866/PKU.WHXB20110327
CATALYSIS AND SURFACE SCIENCE     
Pt-Ni Catalyst Supported on CMK-5 for the Electrochemical Oxidation of Methanol
DING Xiao-Chun, CHEN Xiu, ZHOU Jian-Hua, WANG Tao, SUN Dun, HE Jian-Ping
College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China
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Abstract  

Pt-Ni alloy catalysts with different atomic ratios were deposited on CMK-5 (carbon replicated from SBA-15 silica) by NaBH4 reduction. X-ray diffraction (XRD) suggests alloy formation between Pt and Ni. X-ray photoelectron spectroscopy (XPS) shows that Pt-Ni/CMK-5 (5:1) has more detectable oxidized Ni. More metallic Pt is present on Pt-Ni/CMK-5 (5:1) (atomic ratio) than on Pt/CMK-5. Oxidized Ni species, such as NiO, Ni(OH)2, and NiOOH, favor the adsorption of methanol and the dissociation of methanol from the surface of Pt. Cyclic voltammetry shows that Pt-Ni/CMK-5 (5:1) has the highest specific activity among the as-made catalysts and its electrochemical active area is 63.9 m2·g-1. It has more resistance to CO poisoning than Pt/CMK-5.



Key wordsCMK-5      Pt/CMK-5 catalyst      Pt-Ni/CMK-5 catalyst      Methanol      Electrooxidation     
Received: 27 October 2010      Published: 16 February 2011
MSC2000:  O646  
Fund:  

The project was supported by the National Natural Science Foundation of China (50871053).

Corresponding Authors: HE Jian-Ping     E-mail: jianph@nuaa.edu.cn
Cite this article:

DING Xiao-Chun, CHEN Xiu, ZHOU Jian-Hua, WANG Tao, SUN Dun, HE Jian-Ping. Pt-Ni Catalyst Supported on CMK-5 for the Electrochemical Oxidation of Methanol. Acta Phys. -Chim. Sin., 2011, 27(03): 711-716.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB20110327     OR     http://www.whxb.pku.edu.cn/Y2011/V27/I03/711

(1) Liu, X.; Chen, J.; Liu, G.; Zhang, L.; Zhang, H. M.; Yia, B. L. J. Power Sources 2010, 195, 4098.
(2) Li, W. Z.; Zhou, W. J.; Li, H. Q.; Zhou, Z. H.; Zhou, B.; Sun, G. Q.; Xin, Q. Electrochim. Acta 2004, 49, 1045.
(3) Yang, C. W.; Wang, D. L.; Hu, X. G.; Dai, C. S.; Liang, Z. J. Alloy. Compd. 2008, 448, 109.
(4) Wang, X. M.; Li, N.; Pfefferle, L. D.; Haller, G. L. J. Phys. Chem., C 2010, 114, 16996.
(5) Tang, H.; Chen, J. H.; Nie, L. H.; Liu, D. Y.; Deng, W.; Kuang, Y. F.; Yao, S. Z. J. Colloid Interface Sci. 2004, 269, 26.
(6) Steigerwalt, E. S.; Deluga, G. A.; Lukehart, C. M. J. Nanosci. Nanotechnol. 2003, 3, 247.
(7) Yen, C. H.; Shimizu, K.; Lin, Y. Y.; Bailey, F.; Cheng, I. F.; Wai, C. M. Energy Fuels 2007, 21, 2268.
(8) Shimazaki, Y.; Hayasaka, S.; Koyama, T,; Nagao, D.; Kobayashi, Y.; Konno, M. J. Colloid Interface Sci. 2010, 350, 580.
(9) Zhao, Y.; Yifeng, E.; Fan, L. Z.; Qiu, Y. F.; Yang, S. H. Electrochim. Acta 2007, 52, 5873.
(10) Do, J. S.; Chen, Y. T.; Lee, M. H. J. Power Sources 2007, 172, 623.
(11) Choi, J. H.; Park, K. W.; Kwon, B. K.; Sung, Y. E. J. Electrochem. Soc. 2003, 150, 773.
(12) Liu, F.; Lee, J. Y.; Zhou, W. J. J. Phys. Chem. B 2004, 108, 17959.
(13) Jeon, T. Y.; Yoo, S. J.; Cho, Y. H.; Lee, K. S.; Kang, S. H.; Sung, Y. E. J. Phys. Chem. C 2009, 113, 19732.
(14) Jiang, S. J.; Ma, Y. W.; Tao, H. S.; Jian, G. Q.; Wang, X. Z.; Fan, Y. N.; Zhu, J. M.; Hu, Z. J. Nanosci. Nanotechnol. 2010, 10, 3895.
(15) Yano, H.; Kataoka, M.; Yamashita, H.; Uchida, H.; Watanabe, M. Langmuir 2007, 23, 6438.
(16) He, C. Z.; Kunz, H. R.; Fenton, J. M. J. Electrochem. Soc. 2003, 150, A1071.
(17) Mathiyarasu, J.; Remona, A. M.; Mani, A.; Phani, K. L. N.; Yegnaraman, V. J. Solid State Electrochem. 2004, 8, 968.
(18) Liu, Z. L.; Ling, X. Y.; Su, X. D.; Lee, J. Y. J. Phys. Chem. B 2004, 108, 8234.
(19) Wang, Z. B.; Yin, G. P.; Shi, P. F. J. Electrochem. Soc. 2005, 153, A2406.
(20) Park, K. W.; Choi, J. H.; Ahn, K. S.; Sung, Y. E. J. Phys. Chem. B 2004, 108, 5989.
(21) Sun, D.; He, J. P.; Zhou, J. H.; Wang, T.; Di, Z. Y.; Ding, X. C. Acta Phys.-Chim. Sin. 2010, 26, 1219.
[孙 盾, 何建平, 周建华, 王 涛, 狄志勇, 丁晓春.. 物理化学学报, 2010, 26, 1219.]
(22) Lu, A. H.; Li, W. C.; Schmidt, W. G.; Schuth, F. Microporous Mesoporous Mat. 2005, 80, 117.
(23) Antolini, E.; Salgado, J. R. C.; Gonzalez, E. R. J. Electroanal. Chem. 2005, 580, 145.
(24) Zhou, J. H.; He, J. P.; Dang, W. J.; Zhao, G. W.; Zhang, C. X.; Mei, T. Q. Electrochem. Solid-State Lett. 2007, 10, B191.
(25) Pozio, A.; Francesco, D. M.; Cemmi, A. J. Power Sources 2002, 105, 13.
(26) Yang, R. Z.; Iiu X. P.; Zhang, H. R. Carbon 2005, 43, 11.
(27) Zhou, J. H.; He, J. P.; Dang, W. J.; Zhao, G. W.; Zhang, C. X. Electrochem. Solid-State Lett. 2007, 10, B191.
(28) Park, K. W.; Choi, J. H.; Kwon, B. K.; Lee, S. A.; Sung, Y. E. J. Phys. Chem. B 2002, 106, 1869.
(29) Gojkovic, S. L.; Vidakovic, T. R.; Durovic, D. R. Electrochim. Acta 2003, 48, 3607.
(30) Radmilovic, V.; Gasteiger, H. A.; Ross, P. N. J. Catal. 1995, 154, 98.
(31) Geng, D. S.; Lu, G. X. J. Phys. Chem. C 2007, 111, 11897.
(32) Liu, F.; Lee, J. Y.; Zhou, W. J. Small 2006, 2, 121.
(33) Watanabe, M.; Uchida, M.; Motoo, S. J. Electroanal. Chem. 1987, 229, 395.
(34) Park, K. W.; Choi, J. H.; Sung, Y. E. J. Phys. Chem. B 2003, 107, 5851.
(35) Lin, Y.; Cui, X.; Yen, C.; Wai, C. M. J. Phys. Chem. B 2005, 109, 14410.

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