ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2011,Vol.27>> Issue(04)>> 881-886     doi: 10.3866/PKU.WHXB20110413         中文摘要
TiO2 Thin-Film Electrode Modified by Co-Adsorbents
LI Jie, KONG Fan-Tai, WU Guo-Hua, ZHANG Chang-Neng, DAI Song-Yuan
Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, P. R. China
Full text: PDF (706KB) HTML Export: BibTeX | EndNote (RIS)

A co-adsorbents modified nanocrystalline TiO2 thin-film electrode was studied for application in dye-sensitized solar cells. The effects of di(3,3-dimethylbutyl) phosphoric acid and chenodeoxycholic acid modification on the flat band potential and the passivation of the TiO2 thin-film electrode were investigated by determining the flat-band potential and undertaking electrochemical impedance spectroscopy (EIS). The results suggest that di(3,3-dimethylbutyl) phosphoric acid is more effective in passivating the TiO2 film surface and in shifting the flat-band potential negatively. For the dye-sensitized solar cells, EIS measurements indicate that the use of di(3,3-dimethylbutyl) phosphoric acid as a co-adsorbent may be more effective in increasing the electronic lifetime and the open-circuit voltage of the device than chenodeoxycholic acid.

Keywords: Dye-sensitized solar cell   Coadsorbent   Dark current   Flat-band potential   Electrochemical impedance spectroscopy  
Received: 2010-12-03 Accepted: 2011-02-15 Publication Date (Web): 2011-03-03
Corresponding Authors: KONG Fan-Tai,DAI Song-Yuan Email:;

Fund: The project was supported by the National Key Basic Research Program of China (2011CBA00700), National Natural Science Foundation of China (21003130) and Natural Science Foundation of Anhui Province, China (090414174).

Cite this article: LI Jie, KONG Fan-Tai, WU Guo-Hua, ZHANG Chang-Neng, DAI Song-Yuan. TiO2 Thin-Film Electrode Modified by Co-Adsorbents[J]. Acta Phys. -Chim. Sin., 2011,27 (04): 881-886.    doi: 10.3866/PKU.WHXB20110413

(1) Hagberg, D. P.; Yum, J. H.; Lee, H.; Grätzel, M.; Nazeeruddin, M. K. J. Am. Chem. Soc. 2008, 130, 6259.
(2) Wang, Z. S.; Zhou, G. J. Phys. Chem. C 2009, 113, 15417.
(3) Horiuchi, T.; Miura, H.; Sumioka, K.; Uchida, S. J. Am. Chem. Soc. 2004, 126, 12218.
(4) Yum, J. H.; Jang, S. R.; Walter, P.; Geiger, T.; Nuesch, F.; Kim, S.; Ko, J.; Grätzel, M.; Nazeeruddin, M. K. Chem. Commun. 2007, 4680.
(5) Hara, K.; Dan-Oh, Y.; Kasada, C.; Ohga, Y.; Shinpo, A.; Suga, S.; Sayama, K.; Arakawa, H. Langmuir 2004, 20, 4205.
(6) Wang, Z. S.; Cui, Y.; Dan-Oh, Y.; Kasada, C.; Shinpo, A.; Hara, K. J. Phys. Chem. C 2007, 111, 7224.
(7) Zhan, W. S.; Pan, S.; Li, Y. Z.; Chen, M. D. Acta Phys. -Chim. Sin. 2009, 25, 2087.
[詹卫伸, 潘 石, 李源作, 陈茂笃. 物学学报, 2009, 25, 2087.]
(8) Zhang, J. J.; Wu, M.; Qin, Y. T.; Chen, R.; Jiang, Y. H.; Sun, Y. M.; Yang, C. H. Acta Phys. -Chim. Sin. 2008, 24, 79.
[张俊颉, 吴 敏, 秦艳涛, 陈 蕊, 蒋银花, 孙岳明, 杨朝晖. 物理化学, 2008, 24, 79.]
(9) Shi, C. W.; Ge, Q.; Li, B.; Tao, L.; Liu, Q. A. Acta Phys. -Chim. Sin. 2008, 24, 2327.
[史成武, 葛 茜, 李 兵, 桃 李, 刘清安. 物理化学学报, 2008, 24, 2327.]
(10) Nazeeruddin, M. K.; Péchy, P.; Renouard, T.; Zakeeruddin S. M.; Humphry-Baker, R.; Comte, P.; Liska, P.; Cevey, L.; Costa, E.; Shklover, V.; Spiccia, L.; Deacon, G. B.; Bignozzi, C. A.; Grätzel, M. J. Am. Chem. Soc. 2001, 123, 1613.
(11) Li, J.; Kong, F. T.; Zhang, C. N.; Liu, W. Q.; Dai, S. Y. Acta Chim. Sin. 2010, 68, 1357.
[李 洁, 孔凡太, 张昌能, 刘伟庆, 戴松元. 化学学报, 2010, 68, 1357.]
(12) Li, J.; Kong, F. T.; Dai, S. Y.; Wang, K. J. Chem. Online 2010, 73, 205.
[李 洁, 孔凡太, 戴松元, 王孔嘉. 化学通报, 2010, 73, 205.]
(13) Yang, S. M.; Kou, H. Z.; Wang, L.; Wang, H. J.; Fu, W. H. Acta Phys. -Chim. Sin. 2009, 25, 1219.
[杨术明, 寇慧芝, 汪 玲, 王红军, 付文红. 物理化学学报, 2009, 25, 1219.]
(14) Wang, Z. S.; Koumura, N.; Cui, Y.; Takahashi, M.; Sekiguchi, H.; Mori, A.; Kubo, T.; Furube, A.; Hara, K. Chem. Mater. 2008, 20, 3993.
(15) Chen, R.; Yang, X.; Tian, H.; Wang, X.; Hagfeldt, A.; Sun, L. Chem. Mater. 2007, 19, 4007.
(16) Yum, J. H.; Jang, S. R.; Humphry-Baker, R.; Grätzel, M.; Cid, J. J.; Torres, T, Nazeeruddin, M. K. Langmuir 2008, 24, 5636.
(17) Jiang, X.; Marinado, T.; Gabrielsson, E.; Hagberg, D. P.; Sun, L.; Hagfeldt, A. J. Phys. Chem. C 2010, 114, 2799
(18) Wang, P.; Zakeeruddin, S. M.; Comte, P.; Charvet, R.; Humphry-Baker, R.; Grätzel, M. J. Phys. Chem. B 2003, 107, 14336.
(19) Wang, P.; Zakeeruddin, S. M.; Moser, J. E.; Grätzel, A. K. M.; Humphry-Baker, R. Adv. Mater. 2003, 15, 2101.
(20) Wang, P.; Klein, C.; Humphry-Baker, R.; Zakeeruddin, S. M.; Grätzel, M. Appl. Phys. Lett. 2005, 86, 123508.
(21) Wang, P.; Klein, C.; Humphry-Baker, R.; Zakeeruddin, S. M.; Grätzel, M. J. Am. Chem. Soc. 2005, 127, 808.
(22) Wang, M.; Li, X.; Lin, H.; Péchy, P.; Zakeeruddin, S. M.; Grätzel, M. Dalton Trans. 2009, 10015.
(23) Dai, J.; Hu, L. H.; Liu, W. Q.; Dai, S. Y. Chin. J. Phys. 2008, 57, 5310.
[戴 俊, 胡林华, 刘伟庆, 戴松元. 物理学报, 2008, 57, 5310.]
(24) Neale, N. R.; Kopidakis, N.; Lagemaat, J.; Grätzel, M.; Frank, A. J. J. Phys. Chem. B 2005, 109, 23183.
(25) Dai, S. Y. Study on Dye-sensitized Nanocrystalline TiO2 Solar Cells, Ph.D. Dissertation, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, 2001.
[戴松元. 染料敏化纳米太阳电池的研究
[D]. 合肥: 中国科学院等离子体物理研, 2001.]
(26) Wenger, B.; Grätzel, M.; Moser, J. E. J. Am. Chem. Soc. 2005, 127, 12150.

1. CHENG Qing-Li, ZHANG Wei-Hua, TAO Bin.Investigation of the Electrochemical Corrosion of Copper under a Micrometric Electrolyte Droplet Using a Three-Electrode System[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1345-1350
2. TAO Li, HUO Zhi-Peng, WANG Lu, DAI Song-Yuan.Quasi-Solid-State Dye-Sensitized Solar Cell Fabricated fromIonic Gel Electrolyte with High Gel-to-Solution Transition Temperature[J]. Acta Phys. -Chim. Sin., 2015,31(1): 121-127
3. SU Jia, LU Shan, WANG Sha-Sha, ZHANG Xue-Hua, FU Yu-Bin, HE Tao.Influence of pH Values on the Structure and Performance of a Polypyrrole Counter Electrode for Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1487-1494
4. LI Jing-Zhe, KONG Fan-Tai, WU Guo-Hua, CHEN Wang-Chao, HUANG Yang, FANG Xia-Qin, DAI Song-Yuan.Di-n-alkylphosphinic Acid with a Long Alkyl Chain as a Coadsorbent for Modifying TiO2 Photoanodes[J]. Acta Phys. -Chim. Sin., 2014,30(4): 662-668
5. SUN Xian-Zhong, HUANG Bo, ZHANG Xiong, ZHANG Da-Cheng, ZHANG Hai-Tao, MA Yan-Wei.Experimental Investigation of Electrochemical Impedance Spectroscopy of Electrical Double Layer Capacitor[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2071-2076
6. LUO Bing, XIA Da-Hai.Characterization of pH Effect on Corrosion Resistance of Nuclear Steam Generator Tubing Alloy by In-situ Scanning Electrochemical Microscopy[J]. Acta Phys. -Chim. Sin., 2014,30(1): 59-66
7. LI Jing-Zhe, KONG Fan-Tai, WU Guo-Hua, HUANG Yang, CHEN Wang-Chao, DAI Song-Yuan.TiO2/Dye/Electrolyte Interface Modification for Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1851-1864
8. SHANGGUAN Peng-Peng, TONG Shao-Ping, LI Hai-Li, LENG Wen-Hua.Influence of the Potential on the Charge-Transfer Rate Constant of Photooxidation of Water over α-Fe2O3 and Ti-Doped α-Fe2O3[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1954-1960
9. CAO Jian-Yu, TANG Jia-Li, SONG Ling-Zheng, XU Juan, WANG Wen-Chang, Chen Zhi-Dong.Functionalization of Activated Carbon with EDTA and Its Effect on Electrocatalytic Performance of Carbon Supported Pd Catalysts[J]. Acta Phys. -Chim. Sin., 2013,29(01): 144-150
10. DAI Yu-Hua, LI Xiao-Jie, FANG Yan-Yan, SHI Qiu-Fei, LIN Yuan, YANG Ming-Shan.Influence of Polymer Gel Electrolyte on the Performance of Dye-Sensitized Solar Cells Analyzed by Electrochemical Impedance Spectroscopy[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2669-2675
11. SUN Cheng, LI Xi-Ming, XU Jin, YAN Mao-Cheng, WANG Fu-Hui, WANG Zhen-Yao.Effect of Urea on Microbiologically Induced Corrosion of Carbon Steel in Soil[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2659-2668
12. PANG Ran, ZUO Yu, TANG Yu-Ming, XIONG Jin-Ping.Electrochemical Impedance Spectroscopy Study of Failure Process of an Epoxy/Fluorocarbon Coating System[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1146-1152
13. YUAN Zheng, CUI Yong-Li, SHEN Ming-Fang, QIANG Ying-Huai, ZHUANG Quan-Chao.Preparation and Electrochemical Performance of LiTi2(PO4)3/C Composite Cathode for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2012,28(05): 1169-1176
14. YANG Wei-Hua, YANG Wu-Tao, LIN Xiao-Yan.Preparation and Characterization of a Novel Bi-Doped PbO2 Electrode[J]. Acta Phys. -Chim. Sin., 2012,28(04): 831-836
15. XU Zi-Jie, JI Tao, ZHAO Lei, WANG Wei-Yan, YANG Chun-Yan, GAN Li-Hua.Restructured Carbon Aerogels and Their Electrochemical Performances[J]. Acta Phys. -Chim. Sin., 2012,28(02): 361-366
16. ZHU Yan-Feng, ZHANG Juan, ZHANG Yi-Yong, DING Min, QI Hai-Qing, DU Rong-Gui, LIN Chang-Jian.Anticorrosion Properties of Modified Nano-TiO2 Films Prepared by Sol-Gel Method[J]. Acta Phys. -Chim. Sin., 2012,28(02): 393-398
17. XIA Da-Hai, SONG Shi-Zhe, WANG Ji-Hui, BI Hui-Chao, HAN Zhe-Wen.Corrosion Behavior of Tinplates in a Functional Beverage[J]. Acta Phys. -Chim. Sin., 2012,28(01): 121-126
18. CHANG Lin-Rong, CAO Fa-He, CAI Jing-Shun, LIU Wen-Juan, ZHENG Jun-Jun, ZHANG Jian-Qing, CAO Chu-Nan.Polarization Behavior of Magnesium Alloy AZ91D with Micro-Arc Oxidation Coating in NaCl Solution[J]. Acta Phys. -Chim. Sin., 2012,28(01): 127-136
19. XU Shou-Dong, ZHUANG Quan-Chao, SHI Yue-Li, ZHU Ya-Bo, QIU Xiang-Yun, SUN Zhi.Electrochemical Impedance Spectra of Intercalation Compound Electrodes: Models and Theoretical Simulations[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2353-2359
20. LI Wen-Xin, HU Lin-Hua, DAI Song-Yuan.Core-Shell Structure of Y2O3/TiO2 for Use in Dye Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2367-2372
21. TU Xiao-Hua, CHU You-Qun, MA Chun-An.Electrochemical Behavior of Nitroaromatics on Pt Microelectrode in an Aprotic Medium[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2148-2152
22. XU Jia, ZHANG Ming, XU Jian-Hong, MA Gui-Lin.Synthesis and Electrical Properties of La2(Mo1-xVx)2O9-α[J]. Acta Phys. -Chim. Sin., 2011,27(04): 863-868
23. ZHANG Qi-Bo, HUA Yi-Xin.Effect of Alkylimidazolium Ionic Liquids on the Corrosion Inhibition of Copper in Sulfuric Acid Solution[J]. Acta Phys. -Chim. Sin., 2011,27(03): 655-663
24. CHEN Dong-Po, ZHANG Xiao-Dan, WEI Chang-Chun, LIU Cai-Chi, ZHAO Ying.Effect of Blocking Layers Prepared by the Hydrolysis of TiCl4 Solution on the Photovoltaic Performance of a Dye-Sensitized Solar Cell[J]. Acta Phys. -Chim. Sin., 2011,27(02): 425-431
25. ZHANG Qi-Bo, HUA Yi-Xin.Effect of the Ionic Liquid Additive-[BMIM]HSO4 on the Kinetics of Oxygen Evolution during Zinc Electrowinning[J]. Acta Phys. -Chim. Sin., 2011,27(01): 149-155
26. DUAN Ye, LI Song-Mei, DU Juan, LIU Jian-Hua.Corrosion Behavior of Q235 Steel in the Presence of Pseudomonas and Iron Bacteria[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3203-3211
27. ZHANG Wei, WANG Jia, LI Yu-Nan, WANG Wei.Evaluation of Metal Corrosion under Defective Coatings by WBE and EIS Technique[J]. Acta Phys. -Chim. Sin., 2010,26(11): 2941-2950
28. GE Fang, CAO Rui-Guo, ZHU Bin, LI Jing-Jian, XU Dong-Sheng.DNA Electrochemical Biosensor for Trace Hg2+ Detection[J]. Acta Phys. -Chim. Sin., 2010,26(07): 1779-1783
29. QU Xiao-Hua, LIU Jie, WANG Zhao-Xiang, CAO Dian-Liang, FANG Xiang-Peng, ZHANG Ling, DUAN Jing-Lai, YAO Hui-Jun, CHEN Yan-Feng, SUN You-Mei, HOU Ming-Dong.Preparation of Microporous Membranes by Swift Heavy Ion Irradiation and Impedance Characterization[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1722-1726
30. ZHAO Di, HUANG Qing, JIN Xian-Bo, WEI Xian-Jun, CHEN George Z..Capacitance at the Electrode/Ionic Liquid Interface[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1239-1248
31. WANG Wen-Li, LIN Hong, ZHANG Luo-Zheng, LI Xin, CUI Bai, LI Jian-Bao.Electrochemical Impedance Spectroscopy Analysis of an Electrophoretic Titania Nanotube/Nanoparticle Composite Film[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1249-1253
32. TAO Li, YANG Yan-Zhen, SHI Cheng-Wu, WU Yu-Cheng, WU Xiao-Yan.Improved Preparation of Benzothiazolium Iodides and Their Application in Dye Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2010,26(03): 578-582
33. DENG Jun-Ying, JIANG Xiao-Hui, LI Wei-Hua, ZHAO Xia, YU Liang-Min, HOU Bao-Rong.Dithioamide Derivative as an Efficient Inhibitor for Mild Steel in Hydrochloric Acid[J]. Acta Phys. -Chim. Sin., 2010,26(01): 34-38
34. LI Song-Mei, ZHANG Yuan-Yuan, BAI Ru-Bing, LIU Jian-Hua, YU Mei.Corrosion Behavior of Steel A3 under the Combined Effect of Streptomyces and Nocardia sp[J]. Acta Phys. -Chim. Sin., 2009,25(05): 921-927
35. FAN Xiao-Yong, ZHUANG Quan-Chao, WEI Guo-Zhen, KE Fu-Sheng, HUANG Ling, DONG Quan-Feng, SUN Shi-Gang.Fabrication and Performance of Cu6Sn5 Alloy Anode Using Porous Cu as Current Collector[J]. Acta Phys. -Chim. Sin., 2009,25(04): 611-616
36. ZHUANG Quan-Tiao, WEI Guo-Zhen, DONG Quan-Feng, SUN Shi-Gang.Influence of Temperature on the Performance of a Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(03): 406-410
37. ZHANG Jing, DU Min, YU Hui-Hua, WANG Ning.Effect of Molecular Structure of Imidazoline Inhibitors on Growth and Decay Laws of Films Formed on Q235 Steel[J]. Acta Phys. -Chim. Sin., 2009,25(03): 525-531
38. XU Jie; YAO Wan-Hao; YAO Yi-Wen; WANG Zhou-Cheng; YANG Yong.Effect of Fluoroethylene Carbonate Additive on the Performance of Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2009,25(02): 201-206
39. SHI Cheng-Wu, GE Qian, LI Bing, TAO Li, LIU Qing-An.Influence of Additives on the Performance of Electrolytes in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2008,24(12): 2327-2330
40. ZHANG Li-Jun; ZHANG Zhao; ZHANG Jian-Qing.Corrosion Behavior of Anodized AZ91D Magnesium Alloy in NaCl Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2008,24(10): 1831-1838
41. LUO Hai-He; CAI Qi-Zhou; WEI Bo-Kang; YU Bo; HE Jian; LI Ding-Jun.Effect of (NaPO3)6 on Electrochemical Corrosion Characteristic of Micro-arc Oxidation Ceramic Coatings Formed on AZ91DMg Alloy[J]. Acta Phys. -Chim. Sin., 2008,24(03): 481-486
42. SHI Yan-Hua; MENG Hui-Min; SUN Dong-Bai; NI Yong-Le; CHEN Dong.Effect of SbOx+SnO2 Intermediate Layer on the Properties of Ti-based MnO2 Anode[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1553-1559
43. HE Wei-Chun; SHAO Hai-Bo; CHEN Quan-Qi; WANG Jian-Ming; ZHANG Jian-Qing.Polarization Characteristic of Iron Anode in the Concentrated NaOH Solution[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1525-1530
44. ZHAO Yan; LIN Chang-Jian; LI Yan; DU Rong-Gui; WANG Jing-Run.Electrochemical Corrosion Behavior of Copper Clad Laminate in NaCl Solution[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1342-1346
45. SHI Cheng-Wu; GE Qian; QIU Zhi-Guo; LI Bing; HAN Shi-Kui.Synthesis of 3-hexyl-1-methylimidazolium Iodide and Its Application in Dye-Sensitized Solar Cells[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1473-1477
46. ZHUANG Quan-chao; FAN Xiao-yong; XU Jin-mei; CHEN Zuo-feng; DONG Quan-feng; JIANG Yan-xia; HUANG Ling; SUN Shi-gang.Electrochemical Impedance Spectroscopic Study of the First Delithiation of Spinel Lithium Manganese Oxide[J]. Acta Phys. -Chim. Sin., 2006,22(02): 234-238
47. CHEN Can-hui; LI Hong; ZHU Wei; ZHANG Quan-xin.The Electrochemical Behavior of Ferrocene and Its Complex with DNA[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1067-1072
48. ZHANG Sen; DENG Chao.A Novel Method of Surface Modification on AB5 Hydrogen Storage Alloy and Its Mechanism Analysis[J]. Acta Phys. -Chim. Sin., 2005,21(10): 1146-1150
49. SHI Jing-ying; LENG Wen-hua; CHENG Xiao-fang; ZHANG Jian-qing; CAO Chu-nan.Photocatalytic Oxidation of Methyl Red by TiO2 in a Photoelectrochemical Cell[J]. Acta Phys. -Chim. Sin., 2005,21(09): 971-976
50. LIN Yu-hua; DU Rong-gui; HU Rong-gang; LIN Chang-jian.A Correlation Study of Corrosion Resistance and Semiconductor Properties for the Electrochemically Modified Passive Film of Stainless Steel[J]. Acta Phys. -Chim. Sin., 2005,21(07): 740-745
51. Shen Chang-Bin;Wang Sheng-Gang;Yang Huai-Yu;Long Kang;Wang Fu-Hui.Corrosion Inhibition of Bulk Nanocrystallized Industrial Pure Iron by Thiourea in HCl[J]. Acta Phys. -Chim. Sin., 2004,20(06): 664-667
52. Sun Qiu-Xia;Zhang Jian-Qing;Lin Chang-Jian.Interpretation of Electrochemical Impedance Spectroscopy in Coating/Metal System by CR Transmission Line Model[J]. Acta Phys. -Chim. Sin., 2004,20(01): 70-75
53. Tang Zhi-Yuan;Song Shi-Dong;Liu Jian-Hua;Pan Li-Zhu;Nan Jun-Min.Electrochemical Properties of La1-xSrxNi1-yCoyO3 Bifunctional Oxygen Electrodes[J]. Acta Phys. -Chim. Sin., 2003,19(09): 785-790
54. Ge Hong-Hua;Zhou Guo-Ding;Wu Wen-Quan.The Spontaneous Passivation of Stainless Steel in Simulated Cooling Water and the Influence of Sulfide[J]. Acta Phys. -Chim. Sin., 2003,19(05): 403-407
55. Shao Hai-Bo;Zhang Jian-Qing;Wang Jian-Ming;Cao Chu-Nan.EIS Analysis on the Anodic Dissolution Process of Pure Aluminum in an Alkaline Solution[J]. Acta Phys. -Chim. Sin., 2003,19(04): 372-375
56. Hu Ji-Ming;Zhang Jian-Qing;Xie De-Ming;Cao Chu-Nan.Impedance Models of Epoxy Coated LY12 Aluminum Alloys in NaCl Solution[J]. Acta Phys. -Chim. Sin., 2003,19(02): 144-149
57. Lei Jing-Lei;Li Ling-Jie;Cai Sheng-Min;Zhang Sheng-Tao;Li Di;Yang Mai-Zhi.Effect of Cl- on the Corrosion Behavior of Copper Electrode in Weak-alkaline Medium[J]. Acta Phys. -Chim. Sin., 2001,17(12): 1107-1111
58. Zhang Fen-Fen;Wu Xia-Qin;Meng Xiao-Yun;Guo Xiao-Ming;Zhang Zong-Rang.Electrochemical Impedance Spectra of Prussian Blue Film Modified Platinum Electrode[J]. Acta Phys. -Chim. Sin., 2001,17(09): 788-791
59. Liu Hong;Wu Ming;Wu He-Jin;Sun Fu-Xia;Zheng Yun;Li Wen-Zhao.Photocatalytic Activity and Electrochemical Impedance Spectroscopy of TiO2 Thermally Treated by Hydrogen[J]. Acta Phys. -Chim. Sin., 2001,17(03): 286-288
60. Liu Bin;Li Ying;Lin Hai-Chao;Cao Chu-Nan.Effect of PVC on the Diffusing Behavior of Water through Alkyd Coatings[J]. Acta Phys. -Chim. Sin., 2001,17(03): 241-244
61. Ma Hou-Yi, Li Gui-Qiu, Chen Shen-Hao.Relations between the ElS and Mechanism for the Consecutive Charge-Transfer Reaction[J]. Acta Phys. -Chim. Sin., 1998,14(09): 833-840
62. Yuan An-Bao, Cheng Shao-An, Zhang Jian-Qing, Cao Chu-Nan.Electrochemical lmpedance Spectroscopy of Porous Nickel Electrode and its Mathematical Model[J]. Acta Phys. -Chim. Sin., 1998,14(09): 804-810
63. Leng Yong-Jun,Cheng Saho-An,Zhang Jian-Qing,Cao Chu-Nan,Wang Chun-Sheng.Electrochemical Impedance Spectroscopy(EIS) of Metal Hydride Electrode and its Mathematical Model[J]. Acta Phys. -Chim. Sin., 1997,13(10): 890-897
64. Zhang Shu-Yong,Luo Xiao-Wen,Li Shan-Jun,Zhou Wei-Fang.Study on the Water Sorption of an Epoxy Coating Using Electrochemical Impedance Spectroscopy[J]. Acta Phys. -Chim. Sin., 1997,13(03): 207-211
65. Jiang Xiong.An Investigation on the Cathodic Reduction of Co2+ Ions[J]. Acta Phys. -Chim. Sin., 1993,9(01): 129-133
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top