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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2011,Vol.27>> Issue(04)>> 759-763     doi: 10.3866/PKU.WHXB20110415         中文摘要
Electrodeposition and Electrochemical Property of Porous Li-Si Film Anodes for Lithium-Ion Batteries
Lü Rong-Guan, YANG Jun, WANG Jiu-Lin, NULI Yan-Na
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China
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Porous Li-Si thin films (LSFs) were prepared by a multi-step constant current electrodeposition onto Cu foil. The structure and morphology of the electrodeposited films were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). As anodes for Li-ion batteries, Li-Si films give high cycling stability, adjustable Li-storage capacity and initial coulombic efficiency under different electrodeposition conditions. For instance, LSF-3 was electrodeposited in an electrolyte of 0.5 mol·L-1 SiCl4+0.7 mol·L-1 LiClO4+propylene caronate (PC) under certain conditions (i1=-3.82 mA·cm-2, t1=600 s; i2=-1.27 mA·cm-2, t2=7200 s). LSF-3 showed the first coulombic efficiency of 97.1% at a current density of 12.7 μA·cm-2. After the two initial pre-cycles, it delivered gravimetric and geometric charge capacities of 1410 mAh·g-1 and 240.6 μAh·cm-2 at 25.5 μA·cm-2. After 50 cycles, its charge capacity was 179.0 μAh·cm-2 (1049 mAh·g-1), retaining 74.4% of its initial capacity. The porous structure in LSFs can accommodate a part of the volume change during Li insertion/extraction and this favors the structural stability.



Keywords: Porous Li-Si film   Electrodeposition   Coulombic efficiency   Anode material   Lithium-ion battery  
Received: 2010-12-13 Accepted: 2011-02-17 Publication Date (Web): 2011-03-07
Corresponding Authors: YANG Jun Email: yangj723@sjtu.edu.cn

Fund: The project was supported by the National Natural Science Foundation of China (20873085).

Cite this article: Lü Rong-Guan, YANG Jun, WANG Jiu-Lin, NULI Yan-Na. Electrodeposition and Electrochemical Property of Porous Li-Si Film Anodes for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27 (04): 759-763.    doi: 10.3866/PKU.WHXB20110415

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69. ZHAO Hao-Chuan, SONG Yang, GUO Xiao-Dong, ZHONG Ben-He, DONG Jing, LIU Heng.Effect of Precursor Ingredient Temperature on the Performance of LiFePO4 by Hydrothermal Method[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2347-2352
70. XU Shou-Dong, ZHUANG Quan-Chao, SHI Yue-Li, ZHU Ya-Bo, QIU Xiang-Yun, SUN Zhi.Electrochemical Impedance Spectra of Intercalation Compound Electrodes: Models and Theoretical Simulations[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2353-2359
71. NIE Ping, SHEN Lai-Fa, CHEN Lin, SU Xiao-Fei, ZHANG Xiao-Gang, LI Hong-Sen.Sol-Gel Synthesis and Electrochemical Performance of Porous LiMnPO4/MWCNT Composites[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2123-2128
72. GAO Wen-Chao, HUANG Tao, SHEN Yu-Dong, YU Ai-Shui.Phenolic Resin Coated Natural Graphite Oxide as an Anode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2129-2134
73. YANG Fang-Zu, WU Wei-Gang, TIAN Zhong-Qun, ZHOU Shao-Min.Application of Copper Electrochemical Deposition for the Metallization of Micropores[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2135-2140
74. CHU Dao-Bao, LI Yan, SONG Qi, ZHOU Ying.Synthesis and Properties of LiFePO4/C Cathode Material with a New Carbon Source[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1863-1867
75. MAI Li-Qiang, YANG Shuang, HAN Chun-Hua, XU Lin, XU Xu, PI Yu-Qiang.Chemical Lithiation and Electroactivity of Nanomaterials[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1551-1559
76. CHEN Lang, RAO Mu-Min, LI Wei-Shan, XU Meng-Qing, LIAO You-Hao, TAN Chun-Lin, YI Jin.Performance Improvement of Polyethylene-Supported PAMS Electrolyte Using Urea as Foaming Agent[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1689-1694
77. ZHAO Xing, ZHUANG Quan-Chao, QIU Xiang-Yun, XU Shou-Dong, SHI Yue-Li, CUI Yong-Li.Electrochemical Performance of Cr2O3/TiO2 Composite Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(07): 1666-1672
78. WANG Sen-Lin, ZHANG Yi.Preparation and Electrocatalytic Performance of Ni-Mo/LaNi5 Porous Composite Electrode toward Hydrogen Evolution Reaction[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1417-1423
79. CHENG Feng, HUANG Ke-Long, LIU Su-Qin, FANG Xue-Song, ZHANG Xin.Surfactant Carbonization to Synthesize a Fe3O4/C Composite and Its Electrochemical Performance[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1439-1445
80. LI Zhao, XU Ju-Liang, LI Xu-Yan, GUO Li-Fang, LI Jin, JIANG Yi-Ming.Preparation of Manganese Dioxide for Electrodes of Supercapacitors Based on Duplex Stainless Steel[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1424-1430
81. TANG Yan, ZHONG Ben-He, GUO Xiao-Dong, LIU Heng, ZHONG Yan-Jun, NIE Xiang, TANG Hong.Effects of Mixed Solvents on the High-Rate Performance of Li3V2(PO4)3/C Prepared by Sol-Gel Method[J]. Acta Phys. -Chim. Sin., 2011,27(04): 869-874
82. KONG De-Shuai, WANG Jian-Ming, PI Ou-Yang, SHAO Hai-Bo, ZHANG Jian-Qing.Electrochemical Fabrication and Pseudocapacitive Performance of a Porous Nanostructured Nickel-Based Complex Film Electrode[J]. Acta Phys. -Chim. Sin., 2011,27(04): 764-768
83. SU Chang, LU Guo-Qiang, XU Li-Huan, ZHANG Cheng, MA Chun-An.Synthesis and Properties of Spindle-Shaped LiFePO4 for the Cathode Material of Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2011,27(03): 609-614
84. TANG Jing, TIAN Xiao-Chun, ZHOU Fu-Qing, LIU Yue-Qiang, LIN Jian-Hang.Mechanism of Au Electrodeposition onto Indium Tin Oxide[J]. Acta Phys. -Chim. Sin., 2011,27(03): 641-646
85. HAN Nan-Nan, WANG Hui, LI Na, ZHOU Jian-Zhang, LIN Zhong-Hua, WU Di, WAN Guo-Jiang.Electrochemical Behavior of Redox Proteins on ZnO Nanorod-Modified Electrodes Prepared by Electrodeposition[J]. Acta Phys. -Chim. Sin., 2011,27(02): 468-472
86. SHI Yan-Hua, MENG Hui-Min.Electrochemical Behavior of IrO2 Electrodes in the Anodic Electrodeposition of MnO2[J]. Acta Phys. -Chim. Sin., 2011,27(02): 461-467
87. ZHANG Qiu-Mei, SHI Zhi-Cong, LI Yi-Xiao, GAO Dan, CHEN Guo-Hua, YANG Yong.Recent Advances in Fluorophosphate and Orthosilicate Cathode Materials for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(02): 267-274
88. WANG Xiao-Ya, CHENG Qian, HUANG Tao, YU Ai-Shui.Effect of Calcination Atmosphere on Li/Ni Disorder and Electrochemical Performance of Layered LiNi0.5Mn0.5O2[J]. Acta Phys. -Chim. Sin., 2011,27(02): 437-442
89. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia, ZHANG Jin-Qiu.Cathodic and Thermal Stabilities of the P(VdF-HFP)-Based Ionic Liquid Composite Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2011,27(01): 78-84
90. ZHENG Jing-Wu, LU Guo-Ying, QIAO Liang, JIANG Li-Qiang, JIANG Mei-Yan.Copper Electrodeposition from Non-Cyanide Alkaline Baths Containing Methylene Diphosphonic Acid as a Complexing Agent[J]. Acta Phys. -Chim. Sin., 2011,27(01): 143-148
91. CHEN Shi-Yu, WANG Zhao-Xiang, FANG Xiang-Peng, ZHAO Hai-Lei, LIU Xiao-Jiang, CHEN Li-Quan.Characterization of TiS2 as an Anode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2011,27(01): 97-102
92. WANG Ming-Yong, WANG Zhi, GUO Zhan-Cheng.NiW Alloys Electrodeposited under Super Gravity Field and Their Anti-Corrosion Properties in Alkaline Solutions[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3163-3168
93. WANG Dan-Li, RUAN Yong-Feng, ZHANG Ling-Cui, YANG Hong-Bo.Preparation by Electrodeposition and Characterization of ZnO Nanowire Arrays[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3369-3372
94. ZHOU Xiao-Ling, HUANG Rui-An, WU Zhao-Cong, YANG Bin, DAI Yong-Nian.Synthesis and Electrochemical Properties of High-Rate Spinel Li4Ti5Ol2/TiN Anode Material for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3187-3192
95. WU Wei-Gang, YANG Fang-Zu, LUO Ming-Hui, TIAN Zhong-Qun, ZHOU Shao-Min.Electrodeposition of Copper in a Citrate Bath and Its Application to a Micro-Electro-Mechanical System[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2625-2632
96. CHANG Zhao-Rong, DAI Dong-Mei, LI Bao, TANG Hong-Wei.Effect of Hydrazine on the Performance of LiNi0.5Mn1.5O4Cathode Materials[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2633-2637
97. LI Ya-Juan, ZHAN Hui, LIU Su-Qin, HUANG Ke-Long, ZHOU Yun-Hong.Nanosized Flame Retarded HydroxideMagnesium/Poly(ethylene-oxide) Composite Polymer Electrolyte[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2387-2391
98. SONG Li-Jun, MENG Hui-Min.Electrodeposition of Nanocrystalline Nickel Alloys and Their Hydrogen Evolution in Seawater[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2375-2380
99. DAI Ke-Hua, MAO Jing, ZHAI Yu-Chun.High Rate Capability of 5 V LiNi0.5Mn1.5O4 Cathode Materials Synthesized via a Gel-Combustion Method[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2130-2134
100. GUO Yuan-Yuan, WANG Ming, MAO Xiao-Bo, JIANG Yue-Xiu, WANG Chen, YANG Yan-Lian.Growth Mechanism for Controlled Synthesis of Metal Nanotube and Nanowire Arrays Using Anodic Aluminum Oxide Templates[J]. Acta Phys. -Chim. Sin., 2010,26(07): 2037-2043
101. QIU Xiang-Yun, ZHUANG Quan-Chao, WANG Hong-Ming, CUI Yong-Li, FANG Liang, SUN Shi-Gang.Influence of Electrolyte Composition on the Intercalation-Deintercalation Process of Lithium Ion in Spinel LiMn2O4[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1499-1506
102. QU Xiao-Hua, LIU Jie, WANG Zhao-Xiang, CAO Dian-Liang, FANG Xiang-Peng, ZHANG Ling, DUAN Jing-Lai, YAO Hui-Jun, CHEN Yan-Feng, SUN You-Mei, HOU Ming-Dong.Preparation of Microporous Membranes by Swift Heavy Ion Irradiation and Impedance Characterization[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1722-1726
103. ZHANG Xiao-Yu, JIANG Wei-Jun, ZHU Xiao-Pei, QI Lu.Characterization of LiNi1/3Mn1/3Co1/3O2 Synthesized by Wet-Chemical Method[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1507-1514
104. ZHANG Hui-Juan, SONG Huai-He, ZHOU Ji-Sheng, ZHANG Hong-Kun, CHEN Xiao-Hong.Preparation and Electrochemical Properties of SnO2/Onion-Like Hollow Carbon Nanoparticle Composites as Anode Materials for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1259-1263
105. CUI Wen-Yu, AN Mao-Zhong, YANG Pei-Xia.Preparation of an Ionic Liquid Gel Polymer Electrolyte and Its Compatibility with a LiFePO4 Cathode[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1233-1238
106. CHANG Yu-Qing, HUANG Ling, SUN Shi-Gang.Electrodeposition and Electrochemical Properties of Ternary Sn-Co-Zn Alloy Electrodes as Anodes for Lithium-Ion Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(03): 561-566
107. XIONG Li-Zhi, HE Ze-Qiang.A New Rheological Phase Route to Synthesize Nano-LiVOPO4 Cathode Material for LithiumIon Batteries[J]. Acta Phys. -Chim. Sin., 2010,26(03): 573-577
108. CHANG Zhao-Rong, YU Xu, TANG Hong-Wei, WEI Wen-Qiang, DAI Dong-Mei.Influence of Al Doping Content on the Structure and Electrochemical Properties of LiNi1/3Co2/3-xAlxO2[J]. Acta Phys. -Chim. Sin., 2010,26(03): 567-572
109. LIANG Shan, XUE Qun-Ji, CUI Yu-Hong, ZHAO Zhan-Fen.Patterning of TiO2 Thin Films Prepared from Aqueous Solutions[J]. Acta Phys. -Chim. Sin., 2010,26(02): 502-506
110. ZHOU Bao-Ping, YU Gang, OUYANG Yue-Jun, SI Wei-Wei, QIAO Li-Jie.Electrodeposition of Pd-Ag Alloy Nanoparticle Chains on Carbon Fibers and Their Hydrogen Sensing Properties[J]. Acta Phys. -Chim. Sin., 2010,26(01): 237-243
111. LU Hua-Quan, WU Feng, SU Yue-Feng, LI Ning, CHEN Shi, BAO Li-Ying.Electrochemical Performance of LiNi0.5Mn0.5O2 as Cathode Material for Lithium-Ion Batteries Prepared by Oxalate Co-Precipitation Method[J]. Acta Phys. -Chim. Sin., 2010,26(01): 51-56
112. LI Juan, MO Xiao-Liang, SUN Da-Lin, CHEN Guo-Rong.Preparation of CuInS2 Thin Films by One-Step Electrodeposition[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2445-2449
113. TAN Xiao-Lan, CHENG Xin-Qun, MA Yu-Lin, ZUO Peng-Jian, YIN Ge-Ping.Film Formation and Cycleability of LiBOB-Based Electrolyte[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1967-1971
114. CAO Yin-Liang, WANG Feng, LIU Jing-Jun, WANG Jian-Jun, ZHANG Liang-Hu, QIN Shi-Yong.Electrochemical Preparation and Electrocatalytic Mechanisms of Ni-S Active Cathode for Hydrogen Evolution[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1979-1984
115. WANG Yan-Kun, ZHANG Jian-Min, LAN Meng.Temperature Effects on ZnO Film Electrodeposition[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1998-2004
116. ZHENG Jun-Chao, LI Xin-Hai, WANG Zhi-Xing, LI Jin-Hui, WU Ling, LI Ling-Jun, GUO Hua-Jun.A Coalescence Mechanism for the Composite Cathode Material xLiFePO4·yLi3V2(PO4)3[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1916-1920
117. ZHONG Mei-E, ZHOU Zhi-Hui, ZHOU Zhen-Tao.Electrochemical Performance of High-Density LiFePO4/C Composites Synthesized by Solid State-Carbothermal Reduction Method[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1504-1510
118. JIANG Dong-Dong, FU Yan-Bao, MA Xiao-Hua.Fabrication and Characterization of Tin Nanorod Electrodes for Lithium Ion Rechargeable Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1481-1484
119. FENG Ji-Jun, LIU Xiang-Zhe, LIU Xiao-Zhen, JIANG Jian-Zhuang, ZHAO Jing.Hydrothermal Syntheses and Properties of LiV3-xMnxO8 as Cathode Materials for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(08): 1490-1494
120. HU Guo-Rong, CAO Yan-Bing, PENG Zhong-Dong, DU Ke, JIANG Qing-Lai.Preparation of Li2FeSiO4 Cathode Material for Lithium-Ion Batteries by Microwave Synthesis[J]. Acta Phys. -Chim. Sin., 2009,25(05): 1004-1008
121. GAO Hong-Quan, LAI Yan-Qing, ZHANG Zhi-An, LIU Ye-Xiang.Electrochemical Behaviors of New Lithium Salt LiBC2O4F2 in EC+DMC Solvents[J]. Acta Phys. -Chim. Sin., 2009,25(05): 905-910
122. WANG Ming-Yong, WANG Zhi, GUO Zhan-Cheng.Regularity and Mechanism of Pb Electrodeposition Intensified by Super Gravity Field[J]. Acta Phys. -Chim. Sin., 2009,25(05): 883-889
123. YANG Fang-Zu, HUANG Ling, XU Shu-Kai, ZHOU Shao-Min.Preparation, Heat Treatment and Corrosion Behavior of Amorphous Ni-W/ZrO2 Composite Coating[J]. Acta Phys. -Chim. Sin., 2009,25(05): 864-868
124. YANG Hong-Yan, GUO Pan-Pan, LI Wei-Shan.Electrodeposition Preparation and Activity of CO-Resistant Catalyst Pt-HxWO3 for Methanol Oxidation[J]. Acta Phys. -Chim. Sin., 2009,25(04): 719-723
125. FAN Xiao-Yong, ZHUANG Quan-Chao, WEI Guo-Zhen, KE Fu-Sheng, HUANG Ling, DONG Quan-Feng, SUN Shi-Gang.Fabrication and Performance of Cu6Sn5 Alloy Anode Using Porous Cu as Current Collector[J]. Acta Phys. -Chim. Sin., 2009,25(04): 611-616
126. WU Feng, WANG Meng, SU Yue-Feng, CHEN Shi.Surface Modification of LiCo1/3Ni1/3Mn1/3O2 by TiO2-Coating[J]. Acta Phys. -Chim. Sin., 2009,25(04): 629-634
127. LI Ning, GAO Cheng-Hui, YANG Su-Zhen.Crystallization Kinetics of Electrodeposited Amorphous/Nanocrystalline Ni81.32Mo18.68 Alloy Coating[J]. Acta Phys. -Chim. Sin., 2009,25(04): 735-740
128. ZHUANG Quan-Tiao, WEI Guo-Zhen, DONG Quan-Feng, SUN Shi-Gang.Influence of Temperature on the Performance of a Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2009,25(03): 406-410
129. ZHANG Guo-Qiang, MA Li, WU Zhong-Jie, ZHANG Hai-Yan, NI Pei.Electrochemical Behaviour of the Composite Polymer Electrolyte P(VDF-HFP)-PMMA/CaCO3(SiO2)[J]. Acta Phys. -Chim. Sin., 2009,25(03): 555-560
130. MA Ruo-Biao, FU Yan-Bao, MA Xiao-Hua.Preparation and Electrochemical Performance of Tin-Dioxide Filled Multi-Walled Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2009,25(03): 441-445
131. XU Jie; YAO Wan-Hao; YAO Yi-Wen; WANG Zhou-Cheng; YANG Yong.Effect of Fluoroethylene Carbonate Additive on the Performance of Lithium Ion Battery[J]. Acta Phys. -Chim. Sin., 2009,25(02): 201-206
132. LI Yang; XIE Hua-Qing; TU Jiang-Ping.SnS with Various Morphologies and Sizes as Anode Material for Lithium Ion Batteries[J]. Acta Phys. -Chim. Sin., 2009,25(02): 365-370
133. YANG Pei-Xia; AN Mao-Zhong; SU Cai-Na; WANG Fu-Ping.Electrodeposition Behaviors of Pure Cobalt in Ionic Liquid[J]. Acta Phys. -Chim. Sin., 2008,24(11): 2032-2036
134. YANG Shun-Yi; WANG Xian-You; WEI Jian-Liang; LI Xiu-Qin; TANG An-Ping.Preparation and Electrochemical Performance of Na-Mn-O Cathode Materials[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1669-1674
135. HUANG Jun-Jie; JIANG Zhi-Yu.Electrochemical Performance of LiMn2O4 Thin Film Electrode Fabricated by Ink-Jet Printing Technique[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1563-1567
136. ZHANG Hua; ZHOU Yong-Ning; WU Xiao-Jing; FU Zheng-Wen.Electrochemical Properties of CuF2 Films Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1287-1291
137. LI Fan-Qun; LAI Yan-Qing; ZHANG Zhi-An; GAO Hong-Quan; YANG Juan.Electrochemical Behaviors of Et4NBF4+LiPF6/EC+PC+DMC Electrolyte on Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1302-1306
138. WANG Meng; WU Feng; SU Yue-Feng; CHEN Shi.Electrochemical Characteristics of Y2O3-Coated LiCo1/3Ni1/3Mn1/3O2[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1175-1179
139. SHI Yan-Hua; MENG Hui-Min; SUN Dong-Bai; YU Hong-Ying; FU Hua-Rong.Manganese Oxide Coating Electrodes Prepared by Pulse Anodic Electrodeposition[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1199-1206
140. GAO Li-Xia; WANG Li-Na; QI Tao; LI Yu-Ping; CHU Jing-Long; QU Jing-Kui.Electrodeposition of Aluminium from AlCl3/Et3NHCl Ionic Liquids[J]. Acta Phys. -Chim. Sin., 2008,24(06): 939-944
141. AO Jian-Ping; SUN Guo-Zhong; YAN Li; KANG Feng; YANG Liang; HE Qing; ZHOU Zhi-Qiang; LI Feng-Yan; SUN Yun.Properties of One-Step Electrodeposited Cu(In1-x, Gax)Se2 Thin Films[J]. Acta Phys. -Chim. Sin., 2008,24(06): 1073-1079
142. WANG Jian-Hua; LI Bin; WU Hai-Yan; GUO Yu-Zhong.Synthesis of Mesoporous SnO2 and Its Application in Lithium-Ion Battery[J]. Acta Phys. -Chim. Sin., 2008,24(04): 681-685
143. GUO Ying-Jun; LI Qi-Qi-Ge; NING Ying-Kun; QI Lu; TANG Hong-Wu.Performance of Liquid Electrolyte for Lithium-ion Battery at Elevated-temperature[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 1-4
144. WANG Ya-Dan; WANG Jian; MU Qi-Yong; LI Yong-Wei; QI Lu.Electrochemical Performances of LiMn2O4-based Electrode with Water-soluble Binder[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 14-17
145. QI Lu; SONG Zhao-Shuang; XU Hua; MAO Yong-Zhi; WU Ning-Ning; LIU Zheng-Yao.Electrochemical Performance of LithiumIon Battery Power Syetemfor Electric Vehicles[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 21-25
146. ZHANG Chun-Ling; JIANG Wei-Jun; ZHANG Jing; QI Lu.Performance of LiMn1.5Ni0.5-xCuxO4 as 5V Cathode Material for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 31-35
147. TANG Ding-Guo.Application of Polymer LithiumIon Batteries Based on IPN[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 18-20
148. HOU Xian-Quan; JIANG Wei-Jun; QI Lu; HAN Li-Juan.Synthesis and Properties of Layered LiNi0.8Co0.2-xMgxO2 Cathode Material[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 40-45
149. FAN Mao-Song; LEI Xiang-Li; WU Ning-Ning; QI Lu.Electrochemical Performance of LiMn2O4 Power Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 36-39
150. WANG Hai-Yan; LIU Xin-Hou; WU Da-Yong.Electrospinning and Electrospun Membranes[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 67-74
151. AN Hong-Li; WU Ning-Ning; LEI Xiang-Li; XU Jin-Long; QI Lu.Electrochemical Performance of LithiumIon Battery for Plug-in Hybrid Electric Vehicle Applications[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 60-66
152. GUO Ying-Jun; CHEN Hui; QI Lu.Progress in Electrolyte Solutions for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 80-89
153. LEE Meng-Lung; LEE Yi-Da; CHANG Chie-Tai; GAO Tong-Han; LEE Torng-Jinn.Application and Technology of Aluminum Bag Lithium-Ion Polymer Battery[J]. Acta Phys. -Chim. Sin., 2007,23(Supp): 100-106
154. FENG Hua-Jun; CHEN Yuan;DAI Ke-Hua; SONG Zhao-Shuang; MA Jian-Wei; QI Lu.Preparation and Characterization of a Novel Kind of Polymer Electrolyte Composite Membrane for Lithium-Ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1922-1926
155. CHEN Yong-Chong; XU Xing-Jun; CUI Hong-Zhi; DAI Ke-Hua; SONG Zhao-Shuang; JIANG Wei-Jun; QI Lu.Preferred Orientation of Crystals and the Intensity Ratios of XRD Peaks of Cathode Material LiCoO2[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1948-1953
156. HOU Chun-Ping; YUE Min.A Novel Cathode Material Lithium Vanadium Phosphate Synthesized by Liquid-phase Sphericizing Granulation[J]. Acta Phys. -Chim. Sin., 2007,23(12): 1954-1957
157. MA Xu; YAO Su-Wei; ZHANG Wei-Guo; WANG Hong-Zhi.Structure and Corrosion Behavior of Electrodeposited Fe-W-ZrO2 Nano-composite Coatings[J]. Acta Phys. -Chim. Sin., 2007,23(10): 1617-1621
158. TANG Hong-Wei; ZHU Zhi-Hong; CHANG Zhao-Rong; CHEN Zhong-Jun.Drawing and Application of Phase Diagram Related to Eutectic Mixed Lithium Salts[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1265-1268
159. WEI Ying-Jin; LI Xu; WANG Chun-Zhong; ZHAN Shi-Ying; CHEN Gang.Preparation and Electrochemical Properties of Cu Doped V2O5[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1090-1094
160. ZHANG Hong-Fang; FU Ping-Ping; SONG Ying-Jie; DU Chen-Shu; YANG Hua-Bin; ZHOU Zuo-Xiang; WU Meng-Tao; HUANG Lai-He.Preparation and Properties of Sandwich-type Si/Fe/Si Film Anode for Lithium-ion Battery[J]. Acta Phys. -Chim. Sin., 2007,23(07): 1065-1070
161. ZENG Wei; ZHOU Hai-Hui; YING Xiao-Fang; ZENG Qing-Liang; HU Wei-Ya; KUANG Ya-Fei.Electrodeposition of Gold Nanoparticles Coatings from Electrode/ReverseMicroemulsion System[J]. Acta Phys. -Chim. Sin., 2007,23(05): 769-773
162. LIU Su-Qin; LI Shi-Cai; HUANG Ke-Long; CHEN Zhao-Hui.Effect of Doping Ti4+ on the Structure and Performances of Li3V2(PO4)3[J]. Acta Phys. -Chim. Sin., 2007,23(04): 537-542
163. LIU Yong; WEI Zi-Dong; CHEN Si-Guo; FENG Yong-Chao; YIN Guang-Zhi; SUN Cai-Xin.PEMFC Electrodes Platinized by Modulated Pulse Current Electrodeposition[J]. Acta Phys. -Chim. Sin., 2007,23(04): 521-525
164. YAO Su-Wei; JIANG Ying; ZHANG Wei-Guo.Electrochemical Preparation and Giant Magnetoresistance Effect of Spin-valve Multilayers[J]. Acta Phys. -Chim. Sin., 2007,23(04): 493-498
165. MA Liang; MA Jie; LIU Hui.Composite Electrodeposition of CoNiP-BaFe12O19Magnetic Thin Film[J]. Acta Phys. -Chim. Sin., 2007,23(04): 590-594
166. HUANG Ke-Long;YANG Sai;LIU Su-Qin;WANG Hai-Bo.Kinetics of Electrode Processes of LiFePO4 in Saturated Lithium Nitrate Solution[J]. Acta Phys. -Chim. Sin., 2007,23(01): 129-133
167. QIN Hai-Ying;XIE Jian;MI Jian-Li;TU Jian;ZHAO Xin-Bing.Solvothermal Synthesis and Electrochemical Lithiation/Delithiation Performance of FeSb2 Nanorods[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1555-1559
168. HUANG Ling;JIANG Hong-Hong;KE Fu-Sheng;FAN Xiao-Yong;ZHUANG Quan-Chao;YANG Fang-Zu;SUN Shi-Gang.Structure and Properties of Three-dimensional Reticular Sn-Co Alloy Electrodes as Anode Material for Lithium Batteries[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1537-1541
169. XU Yu-Hong;ZHANG Bao-Hong;GONG GUI-Ying;MA Ping .Electrochemical Properties Study of Sb2O3 doped Li4Ti5O12[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1336-1341
170. PENG Xie-Lan;XIE Qing-Ji;KANG Qing;YAO Shou-Zhuo .EQCM Study on the Electrodeposition of Hydroxides in Hydrated Perchlorate + Organic Solvent Systems[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1361-1366
171. XIE Jian;ZHAO Xin-Bing;YU Hong-Ming;QI Hao;CAO Gao-Shao;TU Jiang-Ping .Preparation, Characterization and Electrochemical Li-absorption/extraction Behaviors of Nanosized Co-Sn Intermetallic Compounds[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1409-1412
172. BAI Shuo;YANG Ling-Lu;ZHANG Mao-Feng;YANG Zhao-Hui;ZHANG Zhi-Feng;CAO Wei-Xiao.Patterned Ag Film with Superhydrophobic Properties[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1296-1299
173. ZHANG Wei-guo;LI Wei-Xiang;ZHANG Lu;YAO Su-Wei .Electrodeposition of Cu/Ni Multilayered Nanowires Ordered Arrays by Dual Bath Technique[J]. Acta Phys. -Chim. Sin., 2006,22(08): 977-980
174. ZHUANG Da-Gao;ZHAO Xin-Bing;XIE Jian;TU Jian;ZHU Tie-Jun;CAO Gao-Shao.One-step Solid-state Synthesis and Electrochemical Performance of Nb-doped LiFePO4/C[J]. Acta Phys. -Chim. Sin., 2006,22(07): 840-844
175. WANG Zhong;TIAN Wen-Huai;LI Xing-Guo.Synthesis and Electrochemical Properties of Sn-Sb Alloy Prepared by Hydrogen Plasma-metal Reaction[J]. Acta Phys. -Chim. Sin., 2006,22(06): 752-755
176. GU Min; XIAN Xiao-Hong.The Preparation of Copper Electrodeposits with (110) Lattice Plane Fully Preferred Orientation[J]. Acta Phys. -Chim. Sin., 2006,22(03): 378-382
177. XUE Ming-Zhe; CHENG Sun-Chao; YAO Jia; FU Zheng-Wen.Electrochemical Properties of SnSe Thin Film Electrode Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2006,22(03): 383-387
178. XU Meng-Qing; ZUO Xiao-Xi; LI Wei-Shan; ZHOU Hao-Jie; LIU Jian-Sheng; YUAN Zhong-Zhi.Effect of Butyl Sultone on the Li-ion Battery Performance and Interface of Graphite Electrode[J]. Acta Phys. -Chim. Sin., 2006,22(03): 335-340
179. ZHUANG Quan-chao; FAN Xiao-yong; XU Jin-mei; CHEN Zuo-feng; DONG Quan-feng; JIANG Yan-xia; HUANG Ling; SUN Shi-gang.Electrochemical Impedance Spectroscopic Study of the First Delithiation of Spinel Lithium Manganese Oxide[J]. Acta Phys. -Chim. Sin., 2006,22(02): 234-238
180. YANG Xiao; NI Jiang-feng; HUANG You-yuan; CHEN Ji-tao; ZHOU Heng-hui; ZHANG Xinxiang.Effect of Ti-Doping on Different Morphologic LiCoO2[J]. Acta Phys. -Chim. Sin., 2006,22(02): 183-188
181. WANG Ying; LIU Wen-yuan; FU Zheng-wen.Electrochemistry of Mn4N with Lithium[J]. Acta Phys. -Chim. Sin., 2006,22(01): 65-70
182. WANG Guo-guang WANG Jian-ming MAO Wen-qu LIU Li-qing ZHANG Jian-qing CAO Chu-nan.Structure and Electrochemical Performance of LiNiyCo0.1-yMn1.9O4 Cathode Materials Prepared by a Precipitation Method[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1285-1290
183. TANG Xin-cun; HUANG Bo-yun; HE Yue-hui.Dependence of Li+ Diffusion Coefficients in LiMn2O4 on Charge/Discharge Cycles[J]. Acta Phys. -Chim. Sin., 2005,21(09): 957-960
184. YAO Su-wei; WU Hai-xia; WANG Hong-zhi; ZHANG Wei-guo.Electrodeposition of Cu-Co Granular Films on Semiconductor Si Substrate and Their GMR Effect[J]. Acta Phys. -Chim. Sin., 2005,21(08): 915-919
185. TANG Zhi-yuan; LU Xing-he; ZHANG Na.The Anion-cation Multiple Doping Effect of Spinel Cathode Materials on Electrochemical Speciality[J]. Acta Phys. -Chim. Sin., 2005,21(08): 934-938
186. HUANG You-yuan; ZHOU Heng-hui; CHEN Ji-tao; GAO De-shu; SU Guang-yao.The Effect of Ti4+, Mg2+ Co-doping on Performance of LiNi0.4Co0.2Mn0.4O2[J]. Acta Phys. -Chim. Sin., 2005,21(07): 725-729
187. XUE Ming-zhe; FU Zheng-wen.Electrochemical Properties of LiFePO4 Cathode Thin Film Fabricated by Pulsed Laser Deposition[J]. Acta Phys. -Chim. Sin., 2005,21(07): 707-710
188. LI Hua; XU Cai-ling; ZHAO Guang-yu; LI Hu-lin.Preparation and Magnetic Properties of Amorphous Co-Pt Alloy Nanowire Arrays[J]. Acta Phys. -Chim. Sin., 2005,21(06): 641-645
189. CHEN Zhi-gang; TANG Yi-wen; ZHANG Li-sha; CHEN Zheng-hua; JIA Zhi-jie.Electrochemical Deposition and Characterization of Zinc Oxide Thin Films[J]. Acta Phys. -Chim. Sin., 2005,21(06): 612-615
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