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Acta Physico-Chimica Sinica  2011, Vol. 27 Issue (04): 959-964    DOI: 10.3866/PKU.WHXB20110417
CATALYSIS AND SURFACE SCIENCE     
High-Temperature Synthesis of Zeolite Y
SHAN Zhi-Chao1, LIU Si-Yu1, LI Cai-Jin1, ZHU Long-Feng1, MENG Xiang-Ju2, XIAO Feng-Shou2
1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Institute of Catalysis, Zhejiang University, Hangzhou, 310028, P. R. China
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Abstract  

We hydrothermally synthesized sheet-like crystals of zeolite Y at high temperature (140 °C) using methyltriethoxysilane (MTS) as an additivity. Compared with the zeolite Y synthesized at 100 °C, the zeolite Y synthesized at high temperature has a high Si/Al ratio, a large crystalline width/thickness ratio and has good adsorption for organic volatile compounds. Characterization by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), 29Si nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR) spectroscopy, elemental analysis and water contact angle measurements suggests that the zeolite Y synthesized at high temperature contains methyl groups, which can be responsible for the improvement in sample hydrophobicity and adsorption capacity.



Key wordsZeolite Y      High-temperature      Sheet-like morphology      Adsorption      Organosilane     
Received: 25 October 2010      Published: 08 March 2011
MSC2000:  O643  
Fund:  

The project was supported by the National Natural Science Foundation of China (20973079).

Corresponding Authors: MENG Xiang-Ju, XIAO Feng-Shou     E-mail: fsxiao@mail.jlu.edu.cn; mengxj@zju.edu.cn
Cite this article:

SHAN Zhi-Chao, LIU Si-Yu, LI Cai-Jin, ZHU Long-Feng, MENG Xiang-Ju, XIAO Feng-Shou. High-Temperature Synthesis of Zeolite Y. Acta Physico-Chimica Sinica, 2011, 27(04): 959-964.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20110417     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2011/V27/I04/959

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