金在氨基硅烷修饰SBA-15上的巴豆醛选择加氢性能

doi:10.3866/PKU.WHXB20110434

Abstract

Abstract:

Three kinds of aminosilane (APTS: 3-aminopropyltrimethoxysilane, TPED: N-[3-(trimethoxysilyl)-propylethylene]diamine, TPDT: trimethoxysilyl propyl diethylenetriamine) functionalized mesoporous SBA- 15 molecular sieves (denoted APTS-SBA-15, TPED-SBA-15 and TPDT-SBA-15) were synthesized by post-grafting. Using the static interaction between the amino group and chloroauric acid followed by chemical reduction, the gold nanoparticles were immobilized into the channels of SBA-15. The Au/aminosilane-SBA-15 catalysts were systematically characterized by N₂ physisorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The liquid phase hydrogenation of crotonaldehyde to crotyl alcohol (CROL) was used to investigate the effect of aminosilanes on the catalytic performance of the Au/amine-SBA-15 catalysts. The results revealed that the electron-donating ability of the aminosilane determines the selectivity towards the hydrogenation of the C＝O bond on the gold catalyst. A stronger aminosilane electron-donating ability results in higher electron density on the gold active sites, which leads to the higher selectivity and yield of CROL.

Key words: Au, SBA-15, Aminosilane, Crotonaldehyde, Selective hydrogenation, Crotyl alcohol

MSC2000:

O643

TIAN Li, ZHOU Gong-Bing, LI Zhen-Hua, PEI Yan, QIAO Ming-Hua, FAN Kang-Nian. Gold Supported on Aminosilane-Functionalized SBA-15 for Chemoselective Hydrogenation of Crotonaldehyde[J].Acta Phys. -Chim. Sin., 2011, 27(04): 946-952.

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Gold Supported on Aminosilane-Functionalized SBA-15 for Chemoselective Hydrogenation of Crotonaldehyde

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