Please wait a minute...
Acta Phys. -Chim. Sin.  2011, Vol. 27 Issue (05): 1181-1187    DOI: 10.3866/PKU.WHXB20110519
CATALYSIS AND SURFACE SCIENCE     
Adsorption Performance of Hg(II) Ions on Amine-Modified Nanoporous Carbon Materials
YUAN Xiao-Ling1, LU Chun-Mei2, ZHU Wan-Chun1, JIA Ming-Jun1, LIU Gang1, WANG Zhen-Lü1, ZHANG Wen-Xiang1
1. Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin Uinversity, Changchun 130012, P. R. China;
2. Jilin Entry-Exit Inspection and Quarantine Bureau, Changchun 130062, P. R. China
Download:   PDF(792KB) Export: BibTeX | EndNote (RIS)      

Abstract  

The adsorption performance of nanoporous carbon (NC) and ethylenediamine-modified nanoporous carbon (NC-EDA) toward Hg2+ ions was investigated in an aqueous solution. The NC material exhibited a relatively high adsorption capacity for Hg2+ ions, and the adsorption capacity was improved significantly by ethylenediamine modification. After thermal-treatment at 873 K, the adsorption capacity of the NC-EDA material was still relatively high. Based on various characterization results, we propose that the presence of abundant functional groups (i.e., -COOH, -OH) on the surface of the NC materials is beneficial for the introduction of a large number of amino functional groups resulting in the presence of abundant basic N-containing species on the surface of the NC materials. These basic species can interact with mercury ions and thus significantly improve the adsorption capacity of the carbon material.



Key wordsNanoporous carbon      Adsorption      Ethylenediamine      Mercury ion      Alkalinity     
Received: 19 January 2011      Published: 07 April 2011
MSC2000:  O647  
Fund:  

The project was supported by the National Natural Science Foundation of China (20773050, 21003059) and Ph.D. Programs Foundation of Ministry of Education of China (20090061120024).

Corresponding Authors: LIU Gang, ZHANG Wen-Xiang     E-mail: zhwenx@jlu.edu.cn; lgang@jlu.edu.cn
Cite this article:

YUAN Xiao-Ling, LU Chun-Mei, ZHU Wan-Chun, JIA Ming-Jun, LIU Gang, WANG Zhen-Lü, ZHANG Wen-Xiang. Adsorption Performance of Hg(II) Ions on Amine-Modified Nanoporous Carbon Materials. Acta Phys. -Chim. Sin., 2011, 27(05): 1181-1187.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB20110519     OR     http://www.whxb.pku.edu.cn/Y2011/V27/I05/1181

(1) Matlock, M. M.; Howerton, B. S.; Atwood, D. A. J. Hazard. Mater. 2001, 84, 73.
(2) Oehmen, A.; Fradinho, J.; Serra, S.; Carvalho, G.; Capelo, J. L.; Velizarov, S.; Crespo, J. G.; Reis, M. A. M. J. Hazard. Mater. 2009, 165, 1040.
(3) Miretzky, P.; Fernandez Cirelli, A. J. Hazard. Mater. 2009, 167, 10.
(4) Kennedy Oubagaranadin, J. U.; Sathyamurthy, N.; Murthy, Z. V. P. E. J. Hazard. Mater. 2007, 142, 165.
(5) Kadirvelu, K.; Kavipriya, M.; Karthika, C.; Vennilamani, N.; Pattabhi, S. Carbon 2004, 42, 745.
(6) Choi, M.; Jang, J. J. Colloid Interface Sci. 2008, 325, 287.
(7) Ramadan, H.; Ghanem, A.; El-Rassy, H. Chem. Eng. J. 2010, 159, 107.
(8) Gao, R.; Zheng, H.; Chang, X. J.; He, Q.; Zhang, L. J.; Tu, Z. F.; Shi, J. P. J. Hazard. Mater. 2009, 172, 324.
(9) Vassileva, P.; Tzvetkova, P.; Lakov, L.; Ognyan, P. J. Porous Mater. 2008, 15, 593.
(10) Li, Z. H.; Chang, X. J.; Zou, X. J.; Zhu, X. B.; Nie, R.; Hu, Z.; Li, R. J. Anal. Chim. Acta 2009, 632, 272.
(11) Ranganathan, K. Carbon 2003, 41, 1087.
(12) Kyotani, T. Carbon 2000, 38, 269.
(13) Joo, S. H.; Choi, S. J.; Oh, I.; Kwak, J.; Liu, Z.; Terasaki, O.; Ryoo, R. Nature 2001, 412, 169.
(14) Wang, D. W.; Li, F.; Liu, M.; Lu, G. Q.; Cheng, H. M. Angew. Chem. Int. Edit. 2008, 47, 373.
(15) Lee, J.; Yoon, S.; Hyeon, T.; Oh, S. M.; Kim, K. B. Chem. Commun. 1999, 2177.
(16) Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Yang, H. F.; Li, Z.; Yu, C. Z.; Tu, B.; Zhao, D. Y. Angew. Chem. Int. Edit. 2005, 44, 7053.
(17) Zhu, J. Z.; Yang, J. New Carbon Mater. 2008, 23, 221.
[祝建中, 杨 嘉, Deng, B. L. 新型炭材料, 2008, 23, 221.]
(18) Zhu, J. Z.; Deng, B. L.; Yang, J. Gang, D. C. Carbon 2009, 47, 2014.
(19) Zhu, J. Z.; Yang, J.; Deng, B. L. J. Hazard. Mater. 2009, 166, 866.
(20) Liu, G.; Liu, Y.; Wang, Z. V.; Liao, X. Z.; Wu, S. J.; Zhang, W. X.; Jia, M. J. Microporous Mesoporous Mat. 2008, 116, 439.
(21) Liu, G.; Liu, Y.; Zhang, X. Y.; Yuan, X. L.; Zhang, M.; Zhang,W. X.; Jia, M. J. J. Colloid Interface Sci. 2010, 342, 467.
(22) Liu, G.; Zhang, X. Y.; Xu, Y.; Zhang, M.; Zhang, W. X.; Jia, M. J .; Wu, T. H. Chin. J. Catal. 2010, 31, 1025.
[刘 钢, 张秀艳, 徐 跃, 张 敏,张文祥, 贾明君, 吴通好. 催化学报, 2010, 31, 1025.]
(23) Zhao, G. M.; Shi, J. H.; Liu, G.; Liu, Y.; Wang, Z. L.; Zhang, W. X.; Jia, M. J. J. Mol. Catal. A-Chem. 2010, 327, 32.
(24) Zu, Y. H.; Liu, G.; Wang, Z. L.; Shi, J. H.; Zhang, M.; Zhang, W. X.; Jia, M. J. Energy Fuels 2010, 24, 3810.
(25) Jurewicz, K.; Babe?, K.; Pietrzak, R.; Delpeux, S.; Wachowska, H. Carbon 2006, 44, 2368.
(26) Subramanian, N. P.; Li, X.; Nallathambi, V.; Kumaraguru, S. P.; Colon-Mercado, H.; Wu, G.; Lee, J. W.; Popov, B. N. J. Power Sources 2009, 188, 38.
(27) Arrigo, R.; H?vecker, M.; Wrabetz, S.; Blume, R.; Lerch, M.; McGregor, J.; Parrott, E. P. J.; Zeitler, A.; Gladden,L. F.; Knop- Gericke, A.; Schl?gl, R.; Su, D. S. J. Am. Chem. Soc. 2010, 132, 9616.
(28) Wen, Y. H.; Cheng, J.; Xu, Y.; Liu, X. H.; Cao, G. P.; Yang, Y. S. Progress in Chemistry 2010, 22, 1550.
[文越华, 程 杰, 徐 艳, 刘学虎, 曹高萍, 杨裕生. 化学进展, 2010, 22, 1550.]
(29) Namasivayam, C.; Periasamy, K. Water Res. 1993, 27, 1663.

[1] Jyotirmoy DEB,Debolina PAUL,David PEGU,Utpal SARKAR. Adsorption of Hydrazoic Acid on Pristine Graphyne Sheet: A Computational Study[J]. Acta Phys. -Chim. Sin., 2018, 34(5): 537-542.
[2] Xuanjun WU,Lei LI,Liang PENG,Yetong WANG,Weiquan CAI. Effect of Coordinatively Unsaturated Metal Sites in Porous Aromatic Frameworks on Hydrogen Storage Capacity[J]. Acta Phys. -Chim. Sin., 2018, 34(3): 286-295.
[3] Yuan DUAN,Mingshu CHEN,Huilin WAN. Adsorption and Activation of O2 and CO on the Ni(111) Surface[J]. Acta Phys. -Chim. Sin., 2018, 34(12): 1358-1365.
[4] Qiang LIU,Yong HAN,Yunjun CAO,Xiaobao LI,Wugen HUANG,Yi YU,Fan YANG,Xinhe BAO,Yimin LI,Zhi LIU. In-situ APXPS and STM Study of the Activation of H2 on ZnO(10${\rm{\bar 1}}$0) Surface[J]. Acta Phys. -Chim. Sin., 2018, 34(12): 1366-1372.
[5] Chen-Hui ZHANG,Xin ZHAO,Jin-Mei LEI,Yue MA,Feng-Pei DU. Wettability of Triton X-100 on Wheat (Triticum aestivum) Leaf Surfaces with Respect to Developmental Changes[J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1846-1854.
[6] Chan YAO,Guo-Yan LI,Yan-Hong XU. Carboxyl-Enriched Conjugated Microporous Polymers: Impact of Building Blocks on Porosity and Gas Adsorption[J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1898-1904.
[7] . Influencing Mechanism of Cyclohexene on Thiophene Adsorption over CuY Zeolites[J]. Acta Phys. -Chim. Sin., 2017, 33(6): 1236-1241.
[8] Wei-Guo DAI,Dan-Nong HE. Selective Photoelectrochemical Oxidation of Chiral Ibuprofen Enantiomers[J]. Acta Phys. -Chim. Sin., 2017, 33(5): 960-967.
[9] Lei HE,Xiang-Qian ZHANG,An-Hui LU. Two-Dimensional Carbon-Based Porous Materials: Synthesis and Applications[J]. Acta Phys. -Chim. Sin., 2017, 33(4): 709-728.
[10] Fang CHENG,Han-Qi WANG,Kuang XU,Wei HE. Preparation and Characterization of Dithiocarbamate Based Carbohydrate Chips[J]. Acta Phys. -Chim. Sin., 2017, 33(2): 426-434.
[11] Tao-Na ZHANG,Xue-Wen XU,Liang DONG,Zhao-Yi TAN,Chun-Li LIU. Molecular Dynamics Simulations of Uranyl Species Adsorption and Diffusion Behavior on Pyrophyllite at Different Temperatures[J]. Acta Phys. -Chim. Sin., 2017, 33(10): 2013-2021.
[12] Jun-Jun CHEN,Cheng-Wu SHI,Zheng-Guo ZHANG,Guan-Nan XIAO,Zhang-Peng SHAO,Nan-Nan LI. 4.81%-Efficiency Solid-State Quantum-Dot Sensitized Solar Cells Based on Compact PbS Quantum-Dot Thin Films and TiO2 Nanorod Arrays[J]. Acta Phys. -Chim. Sin., 2017, 33(10): 2029-2034.
[13] Shao-Zheng ZHANG,Jia LIU,Yan XIE,Yin-Ji LU,Lin LI,Liang LÜ,Jian-Hui YANG,Shi-Hao WEI. First-Principle Study of Hydrogen Evolution Activity for Two-dimensional M2XO2-2x(OH)2x (M=Ti, V; X=C, N)[J]. Acta Phys. -Chim. Sin., 2017, 33(10): 2022-2028.
[14] Yan-Ting LI,Xin-Min LIU,Rui TIAN,Wu-Quan DING,Wei-Ning XIU,Ling-Ling TANG,Jing ZHANG,Hang LI. An Approach to Estimate the Activation Energy of Cation Exchange Adsorption[J]. Acta Phys. -Chim. Sin., 2017, 33(10): 1998-2003.
[15] Kui LI,Yao-Lin ZHAO,Jia DENG,Chao-Hui HE,Shu-Jiang DING,Wei-Qun SHI. Adsorption of Radioiodine on Cu2O Surfaces: a First-Principles Density Functional Study[J]. Acta Phys. -Chim. Sin., 2016, 32(9): 2264-2270.