ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2011,Vol.27>> Issue(06)>> 1543-1550     doi: 10.3866/PKU.WHXB20110619         中文摘要
Synthesis and Raman Property of Porous Jujube-Like Cu2O Hierarchy Structure
SUN Du, YIN Peng-Gang, GUO Lin
School of Chemistry and Environment, Beijing University of Aeronautics & Astronautics, Beijing 100191, P. R. China
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Structural engineering of nanocrystals is of great importance to control the properties of semiconductor oxides. Here, we present a mild wet chemical reduction route to obtain a sub-micron porous jujube-like Cu2O hierarchy structure. Sodium dodecylbenzene sulfonate (SDBS) is crucial in structural regulation and it acts as a soft template and a capping agent. The jujube-like particle consists of crystal grains less than 10 nm in size as verified by transmission electron microscopy (TEM) and X-ray diffraction (XRD). A set of time control experiments were carried out to study the evolution of the jujube-like structure. Interestingly, we found that altering the amount of added HCl resulted in a size-tuning effect of changing the size of the particles from approximately 300 to 900 nm. Based on these results, we propose a possible growth-etching competition mechanism to explain the formation of the hollow interior and its porous nature, which also agrees with the sizing-tuning effect. The optical properties were analyzed using Raman spectroscopy. By comparison with a conventional sub-micron solid polyhedral we found a novel Raman property for the porous jujube-like Cu2O. Our research complements the library of Cu2O Raman spectra, which is meaningful for the nondestructive examination of pigments on the surface of antiques by Raman techniques.

Keywords: Nanomaterial   Sodium dodecylbenzene sulfonate   Cuprous oxide   Hierarchy structure   Raman spectroscopy  
Received: 2011-03-04 Accepted: 2011-04-11 Publication Date (Web): 2011-05-03
Corresponding Authors: GUO Lin Email:

Fund: The project was supported by the National Key Basic Research Program of China (973) (2010CB934700), National Natural Science Foundation of China (50725208, 20973019), and Specialized Research Fund for the Doctoral Program of Higher Education, China (20091102110035).

Cite this article: SUN Du, YIN Peng-Gang, GUO Lin. Synthesis and Raman Property of Porous Jujube-Like Cu2O Hierarchy Structure[J]. Acta Phys. -Chim. Sin., 2011,27 (06): 1543-1550.    doi: 10.3866/PKU.WHXB20110619

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78. Li Di;Li Jing-Hong.Electrochemistry of Monolayer Protected Nanoclusters[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 982-988
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85. Dong Xiang-Ting;He Ying;Yan Jing-Hui;Xue Bo-Fei;Feng Xiu-Li;Hong Guang-Yan.Preparation and Characterization of Nanosized AgBr/PMMA Photochromic Hybrid Material[J]. Acta Phys. -Chim. Sin., 2003,19(12): 1159-1162
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95. Hu Wei;Ye Ru-Qiang;Wu Shu-Sen;Liu Hong-Lai.Influence of Alcohol on the Properties of Colloidal Liquid Aphrons[J]. Acta Phys. -Chim. Sin., 2002,18(02): 122-126
96. Cao Da-Peng;Wang Wen-Chuan;Shen Zhi-Gang;Chen Jian-Feng.Determination of Optimum Pressure for Supercritical Methane Adsorbed in Nano-material[J]. Acta Phys. -Chim. Sin., 2001,17(10): 940-943
97. Yan Wei;Wei Zhi-Xiang;Wang Li-Li;Dai Li-Zong;Tian Zhong-Qun.Electrochemical and insitu Raman Spectroscopic Studies of Poly{(pyrrole-2,5-diyl)[(p-N,N-dimethylamino)benzylidene]}[J]. Acta Phys. -Chim. Sin., 2001,17(10): 908-912
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