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Acta Phys. -Chim. Sin.  2011, Vol. 27 Issue (07): 1763-1771    DOI: 10.3866/PKU.WHXB20110704
CATALYSIS AND SURFACE SCIENCE     
Preparation, Characterization and Adsorption Mechanism for Phenols of CTMAB-ZrP
YAO Wei, WANG Hong-Ning, WANG Jian-Wu, ZHONG Jing, CHEN Ruo-Yu
School of Petrochemical Technology, Changzhou University, Changzhou 213164, Jiangsu Province, P. R. China
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Abstract  

Cetyltrimethyl ammonium bromid (CTMAB)-ZrP complexes that contained different amounts of CTMAB that intercalate into α-zirconium phosphate were successfully prepared while methylamine weakened the interlayer forces in α-zirconium phosphate. The CTMAB-ZrP samples were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and N2 sorption isotherm analysis. We discuss the arrangement of CTMAB in the interlayers of zirconium phosphate according to the characterization results. The results of the adsorption of phenol by CTMAB-ZrP showed that the amount of phenol adsorption depended on the content of CTMAB in the complex, the interlayer steric hindrance, and the pH value of the solution. The adsorption of phenol, 2-chlorophenol, 2,4-dichlorophenol, p-methylphenol, and 3,5- dimethylphenol onto CTMAB-ZrP showed that the amount of adsorption correlated positively with the hydrophobicity of the phenols and it was not related to the acidity of the phenolic compounds. The sorption isotherms of phenol, 2-chlorophenol, and 2,4-dichlorophenol fit the Henry and Freundlich equations well. Therefore, the adsorption mechanism is mainly associated with the partition of different phenols in the organic phase of the intercalated CTMAB-ZrP.



Key wordsα-ZrP      Cetyltrimethyl ammonium bromid      Phenol      Adsorption      Partition     
Received: 27 December 2010      Published: 16 May 2011
MSC2000:  O647  
Fund:  

The project was supported by the Natural Science Foundation of Jiangsu Province, China (BK2008143).

Corresponding Authors: CHEN Ruo-Yu     E-mail: chry@cczu.edu.cn
Cite this article:

YAO Wei, WANG Hong-Ning, WANG Jian-Wu, ZHONG Jing, CHEN Ruo-Yu. Preparation, Characterization and Adsorption Mechanism for Phenols of CTMAB-ZrP. Acta Phys. -Chim. Sin., 2011, 27(07): 1763-1771.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB20110704     OR     http://www.whxb.pku.edu.cn/Y2011/V27/I07/1763

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